Abstract: The present invention relates to a metal collecting material formed of an organic polymer fiber base material into which a functional group having a metal adsorbing function is introduced, in which the metal collecting material has a nonwoven fabric form, an opening diameter of 10 to 300 ?m, an aperture ratio of 10 to 50%, a thickness of 10 to 500 ?m, and a weight per area of 5 to 25 g/m2, and a fiber diameter of the organic polymer fiber is 5 to 50 ?m.

Abstract: A renewable adsorbent enabling to adsorb cesium selectively and efficiently, and to reuse cesium by eluting adsorbed cesium, and its manufacturing method are provided. Polyethylene (PE)/polypropylene (PP) based non-woven fabric may be exposed with electron beam, PE/PP based non-woven fabric to which electron beam was exposed is contacted to the monomer solution containing acrylonitrile (AN), dimethyl sulfoxide (DMSO), Tween80 (polyoxyethylene sorbitan monooleate) as a surfactant, and AMP (ammonium molybdophosphate n-hydrate) as an inorganic ion exchanger, and then the inorganic ion exchanger (AMP) is supported directly by the non-ionic graft chain.

Abstract: A method of forming a zirconium-loaded fibrous adsorbent material having phosphoryl groups, the method including: grafting a reactive monomer having phosphoryl groups onto a polymeric substrate; and loading zirconium such that the zirconium-loaded fibrous adsorbent material has a zirconium content in an amount of 4.0 or 4.2 mmol/g.

Abstract: A renewable adsorbent enabling to adsorb cesium selectively and efficiently, and to reuse cesium by eluting adsorbed cesium, and its manufacturing method are provided. Polyethylene (PE)/polypropylene (PP) based non-woven fabric may be exposed with electron beam, PE/PP based non-woven fabric to which electron beam was exposed is contacted to the monomer solution containing acrylonitrile (AN), dimethyl sulfoxide (DMSO), Tween80 (polyoxyethylene sorbitan monooleate) as a surfactant, and AMP (ammonium molybdophosphate n-hydrate) as an inorganic ion exchanger, and then the inorganic ion exchanger (AMP) is supported directly by the non-ionic graft chain.

Abstract: The present invention is one capable of collecting the metal dissolving in a solution, wherein graft chains of a glycidylalkyl(meth)acrylate represented by the following general formula (1) are formed in the polymer substrate and the graft chain has an amino group or a sulfonic acid group: (In the general formula (1), R1 represents a hydrogen atom or a methyl group; R2 represents a linear or branched alkylene group having from 4 to 10 carbon atoms.

Abstract: Filter media for liquid purification, which can remove metal compounds or metal ions containing in polishing or washing liquids such as alkali, acid solution or ultra-pure water used for silicon wafers of semiconductors. Removal of metals from various kind of liquid such as inorganic chemicals, organic solvent, or industrial waste water are also the subject of the present invention. The Filter media made of melt-blown nonwoven substrate comprising of aethylene/norbornene copolymer represented by the following formula [1] and/or a polycyclic norbornene polymer represented by the following formulae [2](a),(b),(c) as raw material, wherein said ethylene/norbornene copolymer and said polycyclic norbornene polymer have a glass transition temperature (Tg) selected in a range from 80 to 180° C. and melt volume rate (MVR) (ISO 1133, measuring conditions: 260° C., 2.

Abstract: A zirconium-loaded fibrous adsorbent material having phosphoryl groups which is produced by first grafting a reactive monomer having phosphoryl groups onto a polymeric substrate and then loading zirconium. One or more methods of using the zirconium-loaded fibrous adsorbent material to recover arsenic, phosphoric ions, and/or fluoride ions are disclosed.

Abstract: A method of forming a zirconium-loaded fibrous adsorbent material having phosphoryl groups, the method including: grafting a reactive monomer having phosphoryl groups onto a polymeric substrate; and loading zirconium such that the zirconium-loaded fibrous adsorbent material has a zirconium content in an amount of 4.0 or 4.2 mmol/g.

Abstract: The high-frequency substrate is constructed of a base member and a conductor adhered to the base member, and the base member is composed of a polymer which is a fluoropolymer having a conductor-affinitive monomer graftpolymerized at a grafting percentage of 1% or less by weight. After reactive sites necessary for graftpolymerization are formed on a film of a fluoropolymer under an oxygen-free atmosphere by irradiating the film with an electron beam or the like, the fluoropolymer film is introduced into a solution of a conductor-affinitive monomer so as to cause graftpolymerization, and a conductor is adhered thereto to thereby produce a substrate, with a grafting percentage of the monomer to the fluoropolymer being 1% or less by weight in the graftpolymerization. The technique leads to the production of a high-frequency substrate having superior adhesion force with respect to the conductor.

Abstract: To provide a technique for producing a high-frequency substrate featuring a superior adhesion force of a conductor. The high-frequency substrate is constructed of a base member and a conductor adhered to the base member, and the base member is composed of a polymer which is a fluoropolymer having a conductor-affinitive monomer graftpolymerized at a grafting percentage of 1% or less by weight. After reactive sites necessary for graftpolymerization are formed on a film of a fluoropolymer under an oxygen-free atmosphere by irradiating the film with an electron beam or the like, the fluoropolymer film is introduced into a solution of a conductor-affinitive monomer so as to cause graftpolymerization, and a conductor is adhered thereto to thereby produce a substrate, with a grafting percentage of the monomer to the fluoropolymer being 1% or less by weight in the graftpolymerization.

Abstract: A zirconium-loaded fibrous adsorbent material having phosphoryl groups which is produced by first grafting a reactive monomer having phosphoryl groups onto a polymeric substrate and then loading zirconium. One or more methods of using the zirconium-loaded fibrous adsorbent material to recover arsenic, phosphoric ions, and/or fluoride ions are disclosed.

Abstract: This invention relates to functional nonwoven filter media provided by radiation-induced graft copolymerization and its production method. Meltblown type of nonwoven (Meltblown) comprised of fine fibers, less than 8 micron in diameter, of polyolefin or polyamide is chosen as the suitable grafting trunk polymer. The production methods are composed of following steps, 1) irradiation less than 30 kGy dose to the Meltblown with electron beam or gamma ray; 2) graft copolymerization of emulsified vinyl monomer onto the Meltblown; and 3) chemical conversion of ion exchange group onto the grafted vinyl monomer. These steps are independently conducted in their suitable operation conditions.

Abstract: A zirconium-loaded fibrous adsorbent material having phosphoryl groups which is produced by first grafting a reactive monomer having phosphoryl groups onto a polymeric substrate and then loading zirconium.

Abstract: To produce a bifunctional adsorbent capable of adsorption in the acidic region, a polymeric substrate is first exposed to a radiation and then a phosphonic acid group suitable for metal adsorption and a sulfonic acid group are introduced into the substrate by graft polymerization.

Abstract: A process for emulsion graft polymerization of a polymeric substrate, which comprises a step of activating a polymeric substrate, and a step of contacting the activated polymeric substrate with an emulsion comprising a surfactant, water, and reactive monomers, thereby graft polymerizing the reactive monomers to the polymeric substrate, and products polymerized by the process, where the surfactant is selected from the group consisting of an anionic surfactant, a cationic surfactant, an amphoric surfactant, a non-ionic surfactant and a mixture thereof, and the polymeric substrate is in the form of woven fabrics, non-woven fabrics, films, hollow filamentary films, flat films or threads, made from polyolefinic fibers such as polyethylene, polypropylene, etc., or natural polymeric fibers such as chitin, chitosan, cellulose, starch, etc.

Abstract: An adsorbent for recovering useful rare metals in solution by adsorption is synthesized by forming reactive sites on a polymeric base material at first, then polymerizing reactive monomers at the reactive sites of the polymeric base material by graft polymerization, thereby forming graft chains, and introducing chelate-forming groups into the graft chains, where the polymeric base material is made of woven fabrics, non-woven fabrics, films, hollow filament films (hollow fibes) or threads of polyolefinic material such as polyethylene, polypropylene or the like, and the reactive monomers are preferably vinyl reactive monomers or vinyl reactive monomers having chelate-forming groups.

Abstract: A collector is disclosed that is made of a polyolefin fiber having amidoxime groups and that is capable of efficient adsorptive recovery of useful metals such as uranium, vanadium, cobalt and titanium which are dissolved in small quantities in seawater. In the presence of a polymerizable monomer having a hydrophilic group, a polymerizable monomer having a cyano group is grafted to a polyolefin fiber by radiation-initiated graft polymerization to form both a hydrophilic group and a cyano group in the same graft side chains, and the cyano groups in the graft side chains are reacted with hydroxylamine to be converted to amidoxime groups, thereby producing a collector capable of recovering dissolved metals from seawater.

Abstract: An object of the present invention is to provide a structure of a metal collecting material for use in seawater or river water or industrial wastewater to give the most excellent adsorption efficiency. Another object of the present invention is to provide a process for efficiently separating and recovering valuable metals or noxious metals from a metal collecting material having collected said valuable metals from seawater or noxious metals from river water or wastewater with the least possible waste generation. A metal collector according to an aspect of the present invention is formed by stacking at least partially alternate layers of a fibrous metal collecting material with a spacer for introducing a liquid to be treated into said collecting material, wherein the area of spacer side faces represents 25-75% of the total area of collecting material side faces and spacer side faces in the side faces of the stack.

Abstract: A zirconium-loaded fibrous adsorbent material having phosphoryl groups which is produced by first grafting a reactive monomer having phosphoryl groups onto a polymeric substrate and then loading zirconium.

Abstract: The present invention aims to provide a graft polymerization method that can be applied to even organic polymer substrates having relatively low strength while overcoming the problem of inhomogeneous grafting.