Patents by Inventor Norifumi Hirota

Norifumi Hirota has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11959197
    Abstract: A first aspect of the present invention is carbon fiber wherein the surface of a monofilament has a center line average roughness Ra of 6.0 nm or more and 13 nm or less, and the monofilament has a long diameter/short diameter ratio of 1.11 or more and 1.245 or less. A second aspect of the present invention is carbon fiber precursor acrylic fiber wherein the surface of a monofilament has a center line average roughness Ra of 18 nm or more and 27 nm or less, and the monofilament has a long diameter/short diameter ratio of 1.11 or more and 1.245 or less. The carbon fiber according to the first aspect is obtained by stabilizing and carbonizing under specific conditions the carbon fiber precursor acrylic fiber according to the second aspect.
    Type: Grant
    Filed: August 15, 2019
    Date of Patent: April 16, 2024
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Naomasa Matsuyama, Yuutarou Nakamura, Norifumi Hirota, Hiroko Matsumura, Katsuhiko Ikeda, Kouki Wakabayashi, Tadashi Ootani, Akihiro Itou, Kenji Hirano, Akito Hatayama, Kenji Kaneta, Atsushi Nakajima
  • Patent number: 11332852
    Abstract: A method of producing a carbon fiber bundle is provided, involving performing a flame-proof treatment to a carbon-fiber-precursor acryl fiber bundle having a single-fiber fineness of 1.5 dtex or more and 5.0 dtex or less, and having a roundness of 0.7 or more and 0.9 or less in a cross-section shape perpendicular to a fiber axis of the single fiber to obtain a flame-proofed fiber bundle; and performing a carbonization treatment to the flame-proofed fiber bundle.
    Type: Grant
    Filed: April 28, 2020
    Date of Patent: May 17, 2022
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yuusuke Shinmen, Norifumi Hirota, Takeshi Nii
  • Publication number: 20200263327
    Abstract: Provided are: a carbon fiber bundle which has a large value of single-fiber fineness and excellent productivity and which, despite this, contains few interlaced single fibers therein and has excellent spreadability; and precursor fibers which are suitable for use in producing the carbon fiber bundle. The precursor fibers are a carbon-fiber-precursor acrylic fiber bundle which comprises a polyacrylonitrile copolymer comprising 95-99 mol % acrylonitrile units and 1-5 mol % hydroxyalkyl (meth)acrylate units and which has a single-fiber fineness of 1.5-5.0 dtex. In the acrylic fiber bundle, the cross-section of each single fiber which is perpendicular to the fiber axis has a shape that has a roundness of 0.9 or less.
    Type: Application
    Filed: April 28, 2020
    Publication date: August 20, 2020
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yuusuke Shinmen, Norifumi Hirota, Takeshi Nii
  • Patent number: 10662556
    Abstract: A carbon fiber bundle, wherein an average single-fiber fineness is from 1.0 to 2.4 dtex and a roundness is from 0.7 to 0.9 in a shape of a cross-section perpendicular to a fiber axis of a single fiber; the roundness being determined with equation (1): roundness=4?S/L2, where S is a cross-sectional area of the single fiber and L is a circumferential length of the single fiber, and S and L are obtained by observing, under an SEM, the cross-section of the single fiber perpendicular to the fiber axis of the single fiber and analyzing the obtained image.
    Type: Grant
    Filed: January 28, 2019
    Date of Patent: May 26, 2020
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yuusuke Shinmen, Norifumi Hirota, Takeshi Nii
  • Publication number: 20200002850
    Abstract: A first aspect of the present invention is carbon fiber wherein the surface of a monofilament has a center line average roughness Ra of 6.0 nm or more and 13 nm or less, and the monofilament has a long diameter/short diameter ratio of 1.11 or more and 1.245 or less. A second aspect of the present invention is carbon fiber precursor acrylic fiber wherein the surface of a monofilament has a center line average roughness Ra of 18 nm or more and 27 nm or less, and the monofilament has a long diameter/short diameter ratio of 1.11 or more and 1.245 or less. The carbon fiber according to the first aspect is obtained by stabilizing and carbonizing under specific conditions the carbon fiber precursor acrylic fiber according to the second aspect.
    Type: Application
    Filed: August 15, 2019
    Publication date: January 2, 2020
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Naomasa Matsuyama, Yuutarou Nakamura, Norifumi Hirota, Hiroko Matsumura, Katsuhiko Ikeda, Kouki Wakabayashi, Tadashi Ootani, Akihiro Itou, Kenji Hirano, Akito Hatayama, Kenji Kaneta, Atsushi Nakajima
  • Publication number: 20190153628
    Abstract: A carbon fiber bundle, wherein an average single-fiber fineness is from 1.0 to 2.4 dtex and a roundness is from 0.7 to 0.9 in a shape of a cross-section perpendicular to a fiber axis of a single fiber; the roundness being determined with equation (1): roundness=4?S/L2, where S is a cross-sectional area of the single fiber and L is a circumferential length of the single fiber, and S and L are obtained by observing, under an SEM, the cross-section of the single fiber perpendicular to the fiber axis of the single fiber and analyzing the obtained image.
    Type: Application
    Filed: January 28, 2019
    Publication date: May 23, 2019
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yuusuke SHINMEN, Norifumi HIROTA, Takeshi NII
  • Patent number: 10233569
    Abstract: A carbon fiber bundle, wherein an average single-fiber fineness is from 1.0 to 2.4 dtex and a roundness is from 0.7 to 0.9 in a shape of a cross-section perpendicular to a fiber axis of a single fiber; the roundness being determined with equation (1): roundness=4?S/L2, where S is a cross-sectional area of the single fiber and L is a circumferential length of the single fiber, and S and L are obtained by observing, under an SEM, the cross-section of the single fiber perpendicular to the fiber axis of the single fiber and analyzing the obtained image.
    Type: Grant
    Filed: February 5, 2018
    Date of Patent: March 19, 2019
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yuusuke Shinmen, Norifumi Hirota, Takeshi Nii
  • Patent number: 10017881
    Abstract: Provided are: a polyacrylonitrile-based precursor fiber for the production of a carbon fiber having a large single-fiber fineness, said precursor fiber ensuring high heat stability of a spinning dope and excellent productivity; and a copolymer suitable for the production of said precursor fiber. Also provided are: high-quality carbon fiber bundles which have a large single-fiber fineness and excellent productivity; a process for producing the same; and a process for producing flameproofed fiber bundles suitable for the production of the carbon fiber bundles. A polyacrylonitrile-based copolymer which comprises 93.0 to 99.4 mol % of acrylonitrile units, 0.5 to 4.0 mol % of (meth)acrylamide-based units, and 0.1 to 3.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: July 10, 2018
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke Shinmen, Norifumi Hirota, Naoki Aoyama, Naomasa Matsuyama, Takeshi Nii, Yasuyuki Fujii, Yoshiko Irie, Harumi Matsuda
  • Publication number: 20180155855
    Abstract: A carbon fiber bundle, wherein an average single-fiber fineness is from 1.0 to 2.4 dtex and a roundness is from 0.7 to 0.9 in a shape of a cross-section perpendicular to a fiber axis of a single fiber; the roundness being determined with equation (1): roundness=4?S/L2, where S is a cross-sectional area of the single fiber and L is a circumferential length of the single fiber, and S and L are obtained by observing, under an SEM, the cross-section of the single fiber perpendicular to the fiber axis of the single fiber and analyzing the obtained image.
    Type: Application
    Filed: February 5, 2018
    Publication date: June 7, 2018
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yuusuke SHINMEN, Norifumi HIROTA, Takeshi NII
  • Patent number: 9920456
    Abstract: A carbon-fiber-precursor acryl fiber bundle, including a polyacrylonitrile-based copolymer that contains from 95 to 99 mol % of an acrylonitrile unit and from 1 to 5 mol % of a hydroxyalkyl (meth)acrylate unit, where the fiber bundle has a single-fiber fineness of from 1.5 dtex to 5.0 dtex and a roundness of from 0.75 to 0.9 in a cross-section shape perpendicular to a fiber axis of the single fiber; the roundness being determined with equation (1): roundness=4?S/L2, where S is a cross-sectional area of the single fiber and L is a circumferential length of the single fiber, and S and L are obtained by observing, under an SEM, the cross-section of the single fiber perpendicular to the fiber axis of the single fiber and analyzing the obtained image.
    Type: Grant
    Filed: October 13, 2011
    Date of Patent: March 20, 2018
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yuusuke Shinmen, Norifumi Hirota, Takeshi Nii
  • Publication number: 20140212663
    Abstract: Provided are: a polyacrylonitrile-based precursor fiber for the production of a carbon fiber having a large single-fiber fineness, said precursor fiber ensuring high heat stability of a spinning dope and excellent productivity; and a copolymer suitable for the production of said precursor fiber. Also provided are: high-quality carbon fiber bundles which have a large single-fiber fineness and excellent productivity; a process for producing the same; and a process for producing flameproofed fiber bundles suitable for the production of the carbon fiber bundles. A polyacrylonitrile-based copolymer which comprises 93.0 to 99.4 mol % of acrylonitrile units, 0.5 to 4.0 mol % of (meth)acrylamide-based units, and 0.1 to 3.
    Type: Application
    Filed: July 20, 2012
    Publication date: July 31, 2014
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Yusuke Shinmen, Norifumi Hirota, Naoki Aoyama, Naomasa Matsuyama, Takeshi Nii, Yasuyuki Fujii, Yoshiko Irie, Harumi Matsuda
  • Publication number: 20130295811
    Abstract: Provided are: a carbon fiber bundle which has a large value of single-fiber fineness and excellent productivity and which, despite this, contains few interlaced single fibers therein and has excellent spreadability; and precursor fibers which are suitable for use in producing the carbon fiber bundle. The precursor fibers are a carbon-fiber-precursor acrylic fiber bundle which comprises a polyacrylonitrile copolymer comprising 95-99 mol % acrylonitrile units and 1-5 mol % hydroxyalkyl (meth)acrylate units and which has a single-fiber fineness of 1.5-5.0 dtex. In the acrylic fiber bundle, the cross-section of each single fiber which is perpendicular to the fiber axis has a shape that has a roundness of 0.9 or less.
    Type: Application
    Filed: October 13, 2011
    Publication date: November 7, 2013
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Yuusuke Shinmen, Norifumi Hirota, Atsushi Nakajima, Naoki Aoyama, Naomasa Matsuyama, Takeshi Nii, Akiyoshi Kogame, Yasuyuki Fujii, Yoshiko Irie, Harumi Matsuda, Takayuki Kiriyama, Teppei Miura, Takuya Teranishi, Shouhei Mori, Manabu Kaneko, Kiharu Numata, Masahiro Ichino, Shigekazu Takeda, Takayuki Kobayashi, Toshiyuki Itou, Masahiro Hata, Hiroyuki Nakao, Kenichi Watanabe
  • Patent number: 8569408
    Abstract: Disclosed are an acrylonitrile copolymer excellent in thermal stability as a solution (spinning dope) when dissolved in an amide solvent and capable of forming dense polyacrylonitrile fiber suitable for production of carbon fiber, an acrylonitrile copolymer solution in which the acrylonitrile copolymer is dissolved in an amide solvent, and a method for producing polyacrylonitrile precursor fiber for carbon fiber by use of the acrylonitrile copolymer solution. Specifically, an acrylonitrile copolymer contains a sulfonate group derived from a polymerization initiator in an amount of 1.0×10?5 equivalent/g or more, and the value (equivalent ratio) of (the content of a sulfate group derived from the polymerization initiator/the total content of the sulfonate group and the sulfate group) is 0.4 or less; an acrylonitrile copolymer solution contains the aforementioned acrylonitrile copolymer and an amide solvent.
    Type: Grant
    Filed: May 12, 2009
    Date of Patent: October 29, 2013
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Norifumi Hirota, Yusuke Shinmen, Naomasa Matsuyama, Takeshi Nii, Harumi Shibatani
  • Publication number: 20110130503
    Abstract: Disclosed are an acrylonitrile copolymer excellent in thermal stability as a solution (spinning dope) when dissolved in an amide solvent and capable of forming dense polyacrylonitrile fiber suitable for production of carbon fiber, an acrylonitrile copolymer solution in which the acrylonitrile copolymer is dissolved in an amide solvent, and a method for producing polyacrylonitrile precursor fiber for carbon fiber by use of the acrylonitrile copolymer solution. Specifically, an acrylonitrile copolymer contains a sulfonate group derived from a polymerization initiator in an amount of 1.0×10?5 equivalent/g or more, and the value (equivalent ratio) of (the content of a sulfate group derived from the polymerization initiator/the total content of the sulfonate group and the sulfate group) is 0.4 or less; an acrylonitrile copolymer solution contains the aforementioned acrylonitrile copolymer and an amide solvent.
    Type: Application
    Filed: May 12, 2009
    Publication date: June 2, 2011
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Norifumi Hirota, Yusuke Shinmen, Naomasa Matsuyama, Takeshi Nii, Harumi Shibatani
  • Patent number: 7777964
    Abstract: A plastic rod lens having a cylindrical shape with a radius R including a central axis; and an outer peripheral portion, wherein a refractive index nD decreases from the central axis to the outer peripheral portion, and the following requirements (1) to (3) are met: 43??1?60??(1) |{nA×?A/(nA?1)}?{nB×?B/(nB?1)}|<5??(2) n0?n1?0.01??(3) wherein n1, n0, nA, and nB represent refraction index nD in the outer peripheral portion, at the center, and at arbitrary points A and B, respectively, and ?1, ?A, and ?B represent Abbe number ? in the outer peripheral portion, and at the arbitrary points A and B, respectively.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: August 17, 2010
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hiroshi Abe, Takashi Saeki, Tsuyoshi Nakagawa, Norifumi Hirota
  • Publication number: 20090257128
    Abstract: A plastic rod lens having a cylindrical shape with a radius R including a central axis; and an outer peripheral portion, wherein a refractive index nD decreases from the central axis to the outer peripheral portion, and the following requirements (1) to (3) are met: 43??1?60??(1) |{nA×?A/(nA?1)}?{nB×?B/(nB?1)}|<5??(2) n0?n1?0.01??(3) wherein n1, n0, nA, and nB represent refraction index nD in the outer peripheral portion, at the center, and at arbitrary points A and B, respectively, and ?1, ?A, and ?B represent Abbe number ? in the outer peripheral portion, and at the arbitrary points A and B, respectively.
    Type: Application
    Filed: July 21, 2006
    Publication date: October 15, 2009
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Hiroshi Abe, Takashi Saeki, Tsuyoshi Nakagawa, Norifumi Hirota
  • Patent number: 7043113
    Abstract: Disclosed is an optical multi/demultiplexer, which comprises a graded index type light transmission section whose refractive index is continuously reduced in the direction from the center to the periphery thereof, a wavelength-multiplexed-light connecting section disposed at one of the axial ends of the light transmission section, and at least one monochromatic light connecting section disposed at the other axial end of the light transmission section. The wavelength-multiplexed-light connecting section and the monochromatic light connecting section are disposed relative to the light transmission section in such a positional relationship that a monochromatic light included in a wavelength multiplexed light entered from the wavelength-multiplexed-light connecting section into the one end of the light transmission section is emitted from the other end of the light transmission section at a position where the monochromatic light connecting section is disposed.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: May 9, 2006
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Toshiaki Hattori, Norifumi Hirota, Yoshihiro Uozu
  • Publication number: 20050094935
    Abstract: Disclosed is an optical multi/demultiplexer, which comprises a graded index type light transmission section whose refractive index is continuously reduced in the direction from the center to the periphery thereof, a wavelength-multiplexed-light connecting section disposed at one of the axial ends of the light transmission section, and at least one monochromatic light connecting section disposed at the other axial end of the light transmission section. The wavelength-multiplexed-light connecting section and the monochromatic light connecting section are disposed relative to the light transmission section in such a positional relationship that a monochromatic light included in a wavelength multiplexed light entered from the wavelength-multiplexed-light connecting section into the one end of the light transmission section is emitted from the other end of the light transmission section at a position where the monochromatic light connecting section is disposed.
    Type: Application
    Filed: November 24, 2004
    Publication date: May 5, 2005
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Toshiaki Hattori, Norifumi Hirota, Yoshihiro Uozu
  • Publication number: 20040202409
    Abstract: Disclosed is an optical multi/demultiplexer, which comprises a graded index type light transmission section whose refractive index is continuously reduced in the direction from the center to the periphery thereof, a wavelength-multiplexed-light connecting section disposed at one of the axial ends of the light transmission section, and at least one monochromatic light connecting section disposed at the other axial end of the light transmission section. The wavelength-multiplexed-light connecting section and the monochromatic light connecting section are disposed relative to the light transmission section in such a positional relationship that a monochromatic light included in a wavelength multiplexed light entered from the wavelength-multiplexed-light connecting section into the one end of the light transmission section is emitted from the other end of the light transmission section at a position where the monochromatic light connecting section is disposed.
    Type: Application
    Filed: April 30, 2004
    Publication date: October 14, 2004
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Toshiaki Hattori, Norifumi Hirota, Yoshihiro Uozu
  • Patent number: 6654173
    Abstract: An object of this invention is to provide a lens array in which the amount of light reaching the image forming surface is large and the variation in the amount of light is small. In order to achieve this object, the lens array comprises cylindrical graded index lenses of radius r0 wherein the refractive index continuously decreases from the center of the lens toward the periphery, said cylindrical graded index lenses are arranged in one line or plural lines with array pitch 2R, if R is R≧r0≧0.8R and if the refractive index profile of each graded index lens is approximated by n(r)2=n02{1−(g·r)2}, the overlapping degree m defined by m=X0/2R satisfies 1.05≦m≦1.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: November 25, 2003
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yoshihiro Uozu, Norifumi Hirota, Toshinori Sumi, Teruta Ishimaru