Abstract: Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.

Abstract: Provided is a dip molding composition containing at least a nitrile rubber elastomer containing a carboxyl group and an amide group. In this dip molding composition, the elastomer contains 50% by weight or more, 78% by weight or less of a conjugated diene monomer-derived structural unit, 17% by weight or more, 35% by weight or less of an ethylenically unsaturated nitrile monomer-derived structural unit, 2.0% by weight or more, 8.0% by weight or less of an ethylenically unsaturated carboxylic acid monomer-derived structural unit, and 0.5% by weight or more, 5.0% by weight or less of an amide group-containing monomer-derived structural unit, and has an MEK-insoluble content of 50% by weight or more, 80% by weight or less.

Abstract: Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.

Abstract: Provided is a dip molding composition including, at least: an elastomer that contains a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit, and a butadiene-derived structural unit in a polymer main chain; an epoxy crosslinking agent; water; and a pH modifier, in which dip molding composition the elastomer contains the (meth)acrylonitrile-derived structural unit in an amount of 20 to 40% by weight, the unsaturated carboxylic acid-derived structural unit in an amount of 1 to 10% by weight, and the butadiene-derived structural unit in an amount of 50 to 75% by weight, and the epoxy crosslinking agent includes an epoxy crosslinking agent containing an epoxy compound having three or more epoxy groups in one molecule and has a dissolution rate in water of 10 to 70% as determined by a specific measurement method.

Abstract: Provided is a dip molding composition which contains at least: a carboxyl group-containing nitrile rubber elastomer; an epoxy crosslinking agent containing an epoxy compound that contains three or more glycidyl ether groups in one molecule and has a basic skeleton containing an alicyclic, aliphatic or aromatic hydrocarbon; and a pH modifier. In this dip molding composition, the elastomer contains 50% by weight or more, 78% by weight or less of a conjugated diene monomer-derived structural unit, 20% by weight or more, 30% by weight or less of an ethylenically unsaturated nitrile monomer-derived structural unit, and 3.5% by weight or more, 6% by weight or less of an ethylenically unsaturated carboxylic acid monomer-derived structural unit; the elastomer has an MEK-insoluble content of 60% by weight or more, 80% by weight or less; and the epoxy crosslinking agent has an MIBK/water distribution ratio of 50% or higher.

Abstract: Provided is a dip molding emulsion including, at least: an elastomer that contains a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit, and a butadiene-derived structural unit in a polymer main chain; an epoxy crosslinking agent; water; and a pH modifier, in which dip molding composition the elastomer contains the (meth)acrylonitrile-derived structural unit in an amount of 20% by weight to 40% by weight, the unsaturated carboxylic acid-derived structural unit in an amount of 1% by weight to 10% by weight, and the butadiene-derived structural unit in an amount of 50% by weight to 75% by weight, and the epoxy crosslinking agent includes an epoxy crosslinking agent containing an epoxy compound having three or more epoxy groups in one molecule and has a dissolution rate in water of 10% to 70% as determined by a specific measurement method.

Abstract: Disclosed is a dip-formed article comprising a layer derived from a latex composition for dip-forming, wherein the latex composition for dip-forming contains a carboxylic acid-modified nitrile-based copolymer latex, the carboxylic acid-modified nitrile-based copolymer latex contains a carboxylic acid-modified nitrile-based copolymer, and the dip-formed article has an elongation of more than 650% and satisfies the following Expressions 1 and 2, [Expression 1] k1?+k2?+k3??9.3 N/mm??(1) [Expression 2] 0.55?k1?/(k1?+k2?+k3?)??(2) wherein k1? is a value obtained by dividing an equilibrium coefficient k1 by a thickness of a test piece, and k2? and k3? are values obtained by dividing viscous coefficients k2 and k3 by the thickness of the test piece, respectively.

Abstract: A glove including a cured film of an elastomer containing a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain, wherein the elastomer contains 20 to 40% by weight of a (meth)acrylonitrile-derived structural unit, 1 to 10% by weight of an unsaturated carboxylic acid-derived structural unit and 50 to 75% by weight of a butadiene-derived structural unit, and has a crosslinked structure of a carboxyl group in the unsaturated carboxylic acid-derived structural unit with an epoxy crosslinker containing an epoxy compound having three or more epoxy groups in one molecule.

Abstract: A glove including a cured film of an elastomer containing a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain, wherein the elastomer contains 20 to 40% by weight of a (meth)acrylonitrile-derived structural unit, 1 to 10% by weight of an unsaturated carboxylic acid-derived structural unit and 50 to 75% by weight of a butadiene-derived structural unit, and has a crosslinked structure of a carboxyl group in the unsaturated carboxylic acid-derived structural unit with an epoxy crosslinker containing an epoxy compound having three or more epoxy groups in one molecule.

Abstract: A glove including a cured film of an elastomer containing a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain, wherein the elastomer contains 20 to 40% by weight of a (meth)acrylonitrile-derived structural unit, 1 to 10% by weight of an unsaturated carboxylic acid-derived structural unit and 50 to 75% by weight of a butadiene-derived structural unit, and has a crosslinked structure of a carboxyl group in the unsaturated carboxylic acid-derived structural unit with an epoxy crosslinker containing an epoxy compound having three or more epoxy groups in one molecule.

Abstract: Provided is a method of producing a glove, the method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the step of adjusting the pH to be 9 or higher using an ammonium compound or an amine compound and leaving a glove emulsion composition to stand with stirring; (3) the dipping step of immersing the glove forming mold, to which the coagulant has thus adhered in the step (1), in the glove emulsion composition; (4) the gelling step of leaving the glove forming mold, to which the glove emulsion composition has thus adhered, to stand at a temperature for a period that satisfy specific conditions; (5) the leaching step of removing impurities from a cured film precursor thus formed on the glove forming mold; (6) the beading step of, after the leaching step, winding the cuff portion of the resulting glove; (7) the precuring step of heating and drying the cured film precursor that has been subj

Abstract: Provided is a dip molding composition including, at least: an elastomer that contains a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit, and a butadiene-derived structural unit in a polymer main chain; an epoxy crosslinking agent; water; and a pH modifier, in which dip molding composition the elastomer contains the (meth)acrylonitrile-derived structural unit in an amount of 20 to 40% by weight, the unsaturated carboxylic acid-derived structural unit in an amount of 1 to 10% by weight, and the butadiene-derived structural unit in an amount of 50 to 75% by weight, and the epoxy crosslinking agent includes an epoxy crosslinking agent containing an epoxy compound having three or more epoxy groups in one molecule and has a dissolution rate in water of 10 to 70% as determined by a specific measurement method.

Abstract: Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.

Abstract: A glove including a cured film of an elastomer containing a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain, wherein the elastomer contains 20 to 40% by weight of a (meth)acrylonitrile-derived structural unit, 1 to 10% by weight of an unsaturated carboxylic acid-derived structural unit and 50 to 75% by weight of a butadiene-derived structural unit, and has a crosslinked structure of a carboxyl group in the unsaturated carboxylic acid-derived structural unit with an epoxy crosslinker containing an epoxy compound having three or more epoxy groups in one molecule.

Abstract: Provided is: A glove dipping composition including, at least: an elastomer that contains a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain; a polycarbodiimide; zinc oxide and/or an aluminum complex; water; and at least one pH modifier selected from an ammonium compound and an amine compound, in which glove dipping composition the polycarbodiimide includes at least one polycarbodiimide containing a hydrophilic segment in its molecular structure and has an average polymerization degree of 3.8 or higher and a carbodiimide equivalent of 260 to 600; the polycarbodiimide is added in an amount of 0.1 to 4.0% by weight and zinc oxide and/or the aluminum complex is/are added in an amount of 0.1 to 5.6% by weight with respect to the total solid content of the glove dipping composition; and the glove dipping composition has a pH of 9.0 to 11.5.

Abstract: Provided is a method of producing a glove, the method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the step of adjusting the pH to be 9 or higher using an ammonium compound or an amine compound and leaving a glove emulsion composition to stand with stirring; (3) the dipping step of immersing the glove forming mold, to which the coagulant has thus adhered in the step (1), in the glove emulsion composition; (4) the gelling step of leaving the glove forming mold, to which the glove emulsion composition has thus adhered, to stand at a temperature for a period that satisfy specific conditions; (5) the leaching step of removing impurities from a cured film precursor thus formed on the glove forming mold; (6) the beading step of, after the leaching step, winding the cuff portion of the resulting glove; (7) the precuring step of heating and drying the cured film precursor that has been subj

Abstract: Provided is: A glove dipping composition including, at least: an elastomer that contains a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain; a polycarbodiimide; zinc oxide and/or an aluminum complex; water; and at least one pH modifier selected from an ammonium compound and an amine compound, in which glove dipping composition the polycarbodiimide includes at least one polycarbodiimide containing a hydrophilic segment in its molecular structure and has an average polymerization degree of 3.8 or higher and a carbodiimide equivalent of 260 to 600; the polycarbodiimide is added in an amount of 0.1 to 4.0% by weight and zinc oxide and/or the aluminum complex is/are added in an amount of 0.1 to 5.6% by weight with respect to the total solid content of the glove dipping composition; and the glove dipping composition has a pH of 9.0 to 11.5.

Abstract: Provided is a resin composition having weather resistance and low-temperature impact resistance, which are the problems of a poly(1,4-cyclohexylene dimethylene terephthalate) copolyester resin, and sustaining the chemical resistance and room-temperature impact resistance of poly(1,4-cyclohexylene dimethylene terephthalate) copolyester resin. It is a resin composition containing a poly(1,4-cyclohexylene dimethylene terephthalate) copolyester resin and a polycarbonate resin, in which the poly(1,4-cyclohexylene dimethylene terephthalate) copolyester resin is contained at 60 to 95% by weight and the polycarbonate resin is contained at 5 to 40% by weight.

Abstract: An emulsion composition includes (1) a carboxylated acrylonitrile butadiene elastomer containing an acrylonitrile residue in an amount of 23 to 30 wt % and an unsaturated carboxylic acid residue in an amount of 3 to 8 wt %, and (2) a polyacrylonitrile butadiene elastomer containing an acrylonitrile residue in an amount of 20 to 50 wt % and having a weight average molecular weight (in terms of styrene) of 7,000 to 50,000. The weight ratio of the component (1)/the component (2) is from 70/30 to 90/10.

Abstract: The present invention reduces the minimum detectable volume of a piece of a glove in the detection using a metal detector. A glove made of a rubber or resin film which contains magnetic particles, wherein the quantity of the magnetic particles is 0.2 to less than 40 mass % relative to the whole of the film; and the magnetic particles comprise secondary particles formed by the agglomeration of primary particles.