Abstract: Provided is a charging member having a rough surface, thereby suppressing adhesion of dirt on the surface. A charging member having a supporting member, an elastic layer and a surface layer, in which the surface layer contains a polymer compound, which has a Si—O-M bond and at least one structural unit selected from structural units represented by the following general formula (1) and the following general formula (2), and has a structural unit represented by the following general formula (3); the charging member has cracks developing from the surface thereof and reaching the elastic layer; and the cracks each have convexly raised edges, by which the surface thereof is roughened.

Abstract: Provided are a charging member capable of maintaining excellent wear resistance even after repeated use, and a process cartridge and an electrophotographic apparatus each having the charging member. The charging member is characterized in that its surface layer has a polysiloxane to which a silsesquioxane is bonded.

Abstract: A charging member is provided with a surface layer that can not easily wear even due to its contact with a photosensitive member and also has an appropriate elasticity contributing to the formation of an appropriate nip between it and the photosensitive member.

Abstract: A charging member is provided which has a surface layer that can more surely keep bleeding from occurring. It is a charging member having a substrate, an elastic layer and a surface layer; the surface layer containing a high-molecular compound having a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (2), and having an Si—O—Zr linkage.

Abstract: Provided is a charging member provided with a surface layer capable of suppressing the bleeding of a low-molecular weight component from an elastic layer with improved reliability. The charging member comprises a support, an elastic layer, and a surface layer, and the surface layer contains a polymer having an Si—O—Ta bond and having a structural unit represented by the following structural formula (1) and a structural unit represented by the following structural formula (2).

Abstract: A charging member that achieves a high level of compatibility between the suppression of the bleeding of a low-molecular weight component from its elastic layer to its surface and charging performance for an electrophotographic photosensitive member. The charging member has a substrate, an elastic layer, and a surface layer. The surface layer contains a polymer having a Si-O-Ti bond, and the polymer has a constitutional unit represented by the following general formula (1) and a constitutional unit represented by the following general formula (2).

Abstract: To provide a charging member to the surface of which any toners and so forth can be kept from adhering and which can exhibit a stable charging performance. The charging member has a substrate, an elastic layer and a surface layer; the surface layer containing a high-molecular compound having an Si—O—B linkage and having a constitutional unit represented by the following formula (1) and a constitutional unit represented by the following formula (2).

Abstract: Provided is a charging member capable of suppressing adhesion of toner or the like to a surface. The charging member comprises: a support; an elastic layer; and a surface layer, and the surface layer contains a polymer having an Si—O—Sr bond and having a structural unit represented by the following formula (1) and a structural unit represented by the following formula (2).

Abstract: To provide a charging member to the surface of which any toners and so forth can be kept from adhering and which can exhibit a stable charging performance. The charging member has a substrate, an elastic layer and a surface layer; the surface layer containing a high-molecular compound having an Si—O—B linkage and having a constitutional unit represented by the following formula (1) and a constitutional unit represented by the following formula (2).

Abstract: A charging member is provided with a surface layer that can not easily wear even due to its contact with a photosensitive member and also has an appropriate elasticity contributing to the formation of an appropriate nip between it and the photosensitive member.

Abstract: Provided is a charging member provided with a surface layer capable of suppressing the bleeding of a low-molecular weight component from an elastic layer with improved reliability. The charging member comprises a support, an elastic layer, and a surface layer, and the surface layer contains a polymer having an Si—O—Ta bond and having a structural unit represented by the following structural formula (1) and a structural unit represented by the following structural formula (2).

Abstract: Provided is a charging member capable of suppressing adhesion of toner or the like to a surface. The charging member comprises: a support; an elastic layer; and a surface layer, and the surface layer contains a polymer having an Si—O—Sr bond and having a structural unit represented by the following formula (1) and a structural unit represented by the following formula (2).

Abstract: Provided is a charging member, which has excellent follow-up property to the rotation of a photosensitive drum and can charge an electrophotographic photosensitive member more stably. The charging member is a charging member, comprising a mandrel, an elastic layer formed on an outer periphery of the mandrel, and a surface layer formed on an outer periphery of the elastic layer, in which the surface layer comprises at least one selected from hydroxylated fullerene and oxidized fullerene, and a binder.

Abstract: Provided is a charging member having a rough surface, thereby suppressing adhesion of dirt on the surface. A charging member having a supporting member, an elastic layer and a surface layer, in which the surface layer contains a polymer compound, which has a Si—O-M bond and at least one structural unit selected from structural units represented by the following general formula (1) and the following general formula (2), and has a structural unit represented by the following general formula (3); the charging member has cracks developing from the surface thereof and reaching the elastic layer; and the cracks each have convexly raised edges, by which the surface thereof is roughened.

Abstract: Provided is a charging member having a high relative dielectric constant and a small surface free energy, the charging member being capable of maintaining its high relative dielectric constant over a long time period. Also provided are a process cartridge and an electrophotographic apparatus effective in increasing a printing speed and lengthening the lifetime of the electrophotographic apparatus. The charging member is a charging member comprising a support, an elastic layer, and a surface layer, wherein the surface layer comprises a cured product layer of a coating agent containing a reaction product between a hydrolyzable silane compound and titanium oxide particles having hydroxyl groups on surfaces thereof at a content of from 0.7 mass % to 35 mass %. The electrophotographic apparatus and the process cartridge each include the charging member.

Abstract: A charging member is provided which has a surface layer that can more surely keep bleeding from occurring. It is a charging member having a substrate, an elastic layer and a surface layer; the surface layer containing a high-molecular compound having a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (2), and having an Si—O—Zr linkage.

Abstract: A charging member is provided in which exudation of a low molecular weight component from an elastic layer to the surface is suppressed, and at the same time, charging performance of the electrophotographic photosensitive member are provided at a high level.

Abstract: The present invention provides a charging member which can maintain excellent wear resistance even though being used repeatedly. In the charging member having a surface layer, the surface layer is a surface layer constituted by at least one selected from silsesquioxanes having structures represented by a compound (1), a compound (2), a compound (3), a compound (4), a compound (5) and a compound (6), and a polysiloxane having a first unit represented by SiO0.5R1(OR2)(OR3), a second unit represented by SiO1.0R4(OR5) and a third unit represented by SiO1.5R6, wherein the silsesquioxane is contained in the polysiloxane.

Abstract: The present invention relates to a charging member that achieves a high level of compatibility between the suppression of the bleeding of a low-molecular weight component from its elastic layer to its surface and charging performance for an electrophotographic photosensitive member. The charging member has a substrate, an elastic layer, and a surface layer. The surface layer contains a polymer having a Si—O—Ti bond, and the polymer has a constitutional unit represented by the following general formula (1) and a constitutional unit represented by the following general formula (2).

Abstract: The present invention provides a charging member which can maintain excellent wear resistance even though being used repeatedly. In the charging member having a surface layer, the surface layer is a surface layer constituted by at least one selected from silsesquioxanes having structures represented by a compound (1), a compound (2), a compound (3), a compound (4), a compound (5) and a compound (6), and a polysiloxane having a first unit represented by SiO0.5R1(OR2)(OR3), a second unit represented by SiO1.0R4(OR5) and a third unit represented by SiO1.5R6, wherein the silsesquioxane is contained in the polysiloxane.