Patents by Inventor Norio Tsubokawa

Norio Tsubokawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10899893
    Abstract: The aminosilane-modified colloidal silica dispersion contains colloidal silica particles having surfaces to which there are bound a first silyl group represented by the following formula (1): R1aSi(OR2)3-aO— and a second silyl group represented by the following formula (2): R3bSi(OR4)3-bO— and, as a dispersion medium, a mixed solvent formed of a polar solvent S1 having a dielectric constant at 20° C. of 15 or higher and lower than 60 and a non-polar solvent S2 having a dielectric constant at 20° C. of 1 or higher and lower than 15, at a mass ratio (S1/S2) of 0.3 to 6.
    Type: Grant
    Filed: May 11, 2016
    Date of Patent: January 26, 2021
    Assignees: NISSAN CHEMICAL INDUSTRIES, LTD., NIIGATA UNIVERSITY
    Inventors: Natsumi Murakami, Masahiro Hida, Norio Tsubokawa, Takeshi Yamauchi, Tomoya Maeta
  • Publication number: 20180355117
    Abstract: The aminosilane-modified colloidal silica dispersion contains colloidal silica particles having surfaces to which there are bound a first silyl group represented by the following formula (1): R1aSi(OR2)3-aO— and a second silyl group represented by the following formula (2): R3bSi(OR4)3-bO— and, as a dispersion medium, a mixed solvent formed of a polar solvent S1 having a dielectric constant at 20° C. of 15 or higher and lower than 60 and a non-polar solvent S2 having a dielectric constant at 20° C. of 1 or higher and lower than 15, at a mass ratio (S1/S2) of 0.3 to 6.
    Type: Application
    Filed: May 11, 2016
    Publication date: December 13, 2018
    Applicants: NISSAN CHEMICAL INDUSTRIES, LTD., NIIGATA UNIVERSITY
    Inventors: Natsumi MURAKAMI, Masahiro HIDA, Norio TSUBOKAWA, Takeshi YAMAUCHI, Tomoya MAETA
  • Patent number: 9688594
    Abstract: Providing a modified-graphene-like carbon material into which hydroxyl groups are introduced. By reacting a graphene-like carbon material with hydrogen peroxide, a hydroxyl group is introduced into the graphene-like carbon material.
    Type: Grant
    Filed: May 14, 2013
    Date of Patent: June 27, 2017
    Assignees: SEKISUI CHEMICAL CO., LTD., NIIGATA UNIVERSITY
    Inventors: Takuya Wada, Norio Tsubokawa
  • Patent number: 9346748
    Abstract: Provided are a functional-group-modified carbon material modified with an isocyanate group or amino group, and a method for producing the material. The material is an isocyanate-group-modified carbon material in which an isocyanate group of a diisocyanate compound is bonded to a graphene-like carbon material, or an amino-group-modified carbon material in which a fragment obtained by radical-decomposing an amino-group-containing azo-type radical initiator is added to the graphene-like carbon material by radical-trapping. The method is a method for producing a functional-group-modified carbon material, including heating and stirring, in a solvent, a graphene-like carbon material, and a diisocyanate compound or an amino-group-containing azo-type radical initiator.
    Type: Grant
    Filed: November 20, 2012
    Date of Patent: May 24, 2016
    Assignees: SEKISUI CHEMICAL CO., LTD., NIIGATA UNIVERSITY
    Inventors: Takuya Wada, Norio Tsubokawa
  • Patent number: 9074101
    Abstract: Silica particles having 4-30% of an organopolysiloxane grafted to surfaces thereof are provided. A silicone composition loaded with such silica particles has high transparency, minimized permeability to corrosive gases, and improved encapsulation ability.
    Type: Grant
    Filed: November 13, 2008
    Date of Patent: July 7, 2015
    Assignees: NIIGATA UNIVERSITY, SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Norio Tsubokawa, Toshio Shiobara, Tsutomu Kashiwagi
  • Publication number: 20150080513
    Abstract: Providing a modified-graphene-like carbon material into which hydroxyl groups are introduced. By reacting a graphene-like carbon material with hydrogen peroxide, a hydroxyl group is introduced into the graphene-like carbon material.
    Type: Application
    Filed: May 14, 2013
    Publication date: March 19, 2015
    Inventors: Takuya Wada, Norio Tsubokawa
  • Publication number: 20140080950
    Abstract: Provided are a functional-group-modified carbon material modified with an isocyanate group or amino group, and a method for producing the material. The material is an isocyanate-group-modified carbon material in which an isocyanate group of a diisocyanate compound is bonded to a graphene-like carbon material, or an amino-group-modified carbon material in which a fragment obtained by radical-decomposing an amino-group-containing azo-type radical initiator is added to the graphene-like carbon material by radical-trapping. The method is a method for producing a functional-group-modified carbon material, including heating and stirring, in a solvent, a graphene-like carbon material, and a diisocyanate compound or an amino-group-containing azo-type radical initiator.
    Type: Application
    Filed: November 20, 2012
    Publication date: March 20, 2014
    Applicants: NIIGATA UNIVERSITY, SEKISUI CHEMICAL CO., LTD.
    Inventors: Takuya Wada, Norio Tsubokawa
  • Patent number: 8541624
    Abstract: Disclosed are: a novel palladium catalyst which does not undergo leakage, can be recycled, does not require the use of any phosphorus-containing ligand, and has a high catalytic activity; and a process for producing a novel bisaryl compound using the palladium catalyst. In the production of a bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of a palladium catalyst and a base, the palladium catalyst comprises a dendrimer containing a silica particle as a core and a palladium compound dissolved in an ionic liquid and supported on the dendrimer.
    Type: Grant
    Filed: November 11, 2010
    Date of Patent: September 24, 2013
    Assignee: Niigata University
    Inventors: Hisahiro Hagiwara, Norio Tsubokawa
  • Publication number: 20120232310
    Abstract: Disclosed are: a novel palladium catalyst which does not undergo leakage, can be recycled, does not require the use of any phosphorus-containing ligand, and has a high catalytic activity; and a process for producing a novel bisaryl compound using the palladium catalyst. In the production of a bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of a palladium catalyst and a base, the palladium catalyst comprises a dendrimer containing a silica particle as a core and a palladium compound dissolved in an ionic liquid and supported on the dendrimer.
    Type: Application
    Filed: November 11, 2010
    Publication date: September 13, 2012
    Applicant: Niigata University
    Inventors: Hisahiro Hagiwara, Norio Tsubokawa
  • Publication number: 20090121180
    Abstract: Silica particles having 4-30% of an organopolysiloxane grafted to surfaces thereof are provided. A silicone composition loaded with such silica particles has high transparency, minimized permeability to corrosive gases, and improved encapsulation ability.
    Type: Application
    Filed: November 13, 2008
    Publication date: May 14, 2009
    Inventors: Norio TSUBOKAWA, Toshio Shiobara, Tsutomu Kashiwagi
  • Patent number: 5374379
    Abstract: A method for making a PTC element grafts a crystalline polymer to conductive particles to form a PTC composition. The step of grafting including solution polymerization. The PTC composition is formed into a PTC element. The PTC element is cross-linked after forming. The PTC element according to this invention exhibits superior PTC behavior when the temperature of the PTC element reaches the crystal melting point of the crystalline polymer.
    Type: Grant
    Filed: September 15, 1992
    Date of Patent: December 20, 1994
    Assignee: Daito Communication Apparatus Co., Ltd.
    Inventors: Norio Tsubokawa, Naoki Yamazaki