Abstract: This disclosure concerns graphite materials having lattice distortion for lithium-ion secondary battery negative electrode obtained by a manufacturing method comprising the steps of: pulverizing and classifying a raw coke composition obtained from a heavy-oil composition undergone coking by delayed coking process, the raw coke composition having a H/C atomic ratio that is a ratio of hydrogen atoms H and carbon atoms C of 0.30 to 0.50 and having a micro-strength of 7 to 17 mass % to obtain powder of the raw coke composition; giving compressive stress and shear stress to the powder of the raw coke composition so that average circularity is 0.91 to 0.97 to obtain round powder; heating the round powder to obtain a carbonized composition; and graphitizing the carbonized composition.

Abstract: A method for producing an amorphous carbon material for a negative electrode of a lithium-ion secondary battery includes the steps of; pulverizing and classifying a raw coke composition obtained from a heavy-oil composition undergone coking by delayed coking process to obtain powder of the raw coke composition, the raw coke composition having a H/C atomic ratio that is a ratio of hydrogen atoms H and carbon atoms C of 0.30 to 0.50 and having a micro-strength of 7 to 17 mass %; giving compressive stress and shear stress to the powder of the raw coke composition to obtain a carbonized composition precursor; and heating the carbonized composition precursor under an inert atmosphere at a temperature from 900° C. to 1,500° C. so that a size of a crystallite Lc(002) is in a range of 2 nm to 8 nm, the size being calculated from a (002) diffraction line obtained by X-ray wide-angle diffractometry.

Abstract: A graphite material for a negative electrode is provided which can suppress capacity degradation due to repeated charging and discharging cycles, storage in a charged state, and floating charging. A method of manufacturing a graphite material for a negative electrode of a lithium ion secondary battery is provided in which an atomic ratio H/C of hydrogen atoms H and carbon atoms C in the raw coke composition is in a range of 0.30 to 0.50 and a microstrength of the raw coke composition is in a range of 7 wt % to 17 wt %.

Abstract: Provided is an amorphous carbon material for a negative electrode of a lithium ion secondary battery. The amorphous carbon material comprises a size of a crystallite Lc(002) in c-axis direction ranging from 2.0 to 8.0 nm, the size being calculated from a (002) diffraction line of the amorphous carbon material measured by powder X-ray diffractometry; a carbon-derived spectrum appearing in a range from 3,200 to 3,400 gauss (G) in an electron spin resonance measured using X band; a relative signal intensity ratio (I4.8K/I40K) of the spectrum ranging from 2.4 to 3.5, wherein the relative signal intensity ratio is a ratio of signal intensity (I4.8K) at temperature of 4.8 K to signal intensity (I40K) at temperature of 40K; and a line width (?Hpp) of the spectrum ranging from 70 to 180 gauss (G), wherein the line width is calculated from a first-order derivative spectrum at temperature of 4.8 K.

Abstract: An amorphous carbon material for lithium-ion secondary battery negative electrode is capable of reducing capacity degradation due to repeated charge and discharge cycles, storage while being charged, or floating charge. A method for producing an amorphous carbon material for a negative electrode of a lithium-ion secondary battery includes the steps of: pulverizing and classifying a raw coke composition obtained from a heavy-oil composition undergone coking by delayed coking process to obtain powder of the raw coke composition, the raw coke composition having a H/C atomic ratio that is a ratio of hydrogen atoms H and carbon atoms C of 0.30 to 0.50 and having a micro-strength of 7 to 17 mass %; giving compressive stress and shear stress to the powder of the raw coke composition to obtain a carbonized composition precursor; and heating the carbonized composition precursor under an inert atmosphere at a temperature from 900° C. to 1,500° C.

Abstract: When a tab wire 20 is connected to a busbar electrode 12 on a surface side of a photovoltaic cell 6, the bonding strength at the connection part can be improved and electric resistance can be reduced without reducing the amount of received light. The busbar electrode 12 and the tab wire 20 are bonded via conductive resin 22 having light-transmission property. This conductive resin 22 covers at least a part of a side face of the busbar electrode 12, and preferably reaches the surface of the photovoltaic cell 6. The tab wire 20 may have a width smaller than a width of the busbar electrode 12.

Abstract: A graphite material for a negative electrode is provided which can suppress capacity degradation due to repeated charging and discharging cycles, storage in a charged state, and floating charging. A method of manufacturing a graphite material for a negative electrode of a lithium ion secondary battery is provided in which an atomic ratio H/C of hydrogen atoms H and carbon atoms C in the raw coke composition is in a range of 0.30 to 0.50 and a microstrength of the raw coke composition is in a range of 7 wt % to 17 wt %.

Abstract: A graphite material for a negative electrode of a lithium ion secondary cell is capable of suppressing capacity degradation caused by the repetition of charging and discharging cycles, storage in a charged state, floating charging and the like. A graphite material for a negative electrode of a lithium ion secondary cell, in which Lc (112), which is a crystallite size in a c-axis direction calculated from a (112) diffraction line measured using powder X-ray diffraction method, is within 4.0 nm to 30 nm, a carbon-derived spectrum appearing in electron spin resonance spectroscopy, which is measured using an X band, is in a range of 3200 gauss (G) to 3400 gauss (G), a relative signal intensity ratio (I4.8K/I40K) of the signal intensity (I4.8K) of the spectrum measured at a temperature of 4.8 K to the signal intensity (I40K) of the spectrum measured at a temperature of 40 K is within 1.5 to 3.0, and ?Hpp, which is a line width of the spectrum calculated from a primary derivative spectrum of the temperature of 4.

Abstract: An amorphous carbon material for lithium-ion secondary battery negative electrode is capable of reducing capacity degradation due to repeated charge and discharge cycles, storage while being charged, or floating charge. A method for producing an amorphous carbon material for a negative electrode of a lithium-ion secondary battery includes the steps of: pulverizing and classifying a raw coke composition obtained from a heavy-oil composition undergone coking by delayed coking process to obtain powder of the raw coke composition, the raw coke composition having a H/C atomic ratio that is a ratio of hydrogen atoms H and carbon atoms C of 0.30 to 0.50 and having a micro-strength of 7 to 17 mass %; giving compressive stress and shear stress to the powder of the raw coke composition to obtain a carbonized composition precursor; and heating the carbonized composition precursor under an inert atmosphere at a temperature from 900° C. to 1,500° C.

Abstract: A graphite material for a negative electrode is provided which can suppress capacity degradation due to repeated charging and discharging cycles, storage in a charged state, and floating charging. A method of manufacturing a graphite material for a negative electrode of a lithium ion secondary battery is provided in which an atomic ratio H/C of hydrogen atoms H and carbon atoms C in the raw coke composition is in a range of 0.30 to 0.50 and a microstrength of the raw coke composition is in a range of 7 wt % to 17 wt %.

Abstract: Provided is an amorphous carbon material for a negative electrode of a lithium ion secondary battery. The amorphous carbon material comprises a size of a crystallite Lc(002) in c-axis direction ranging from 2.0 to 8.0 nm, the size being calculated from a (002) diffraction line of the amorphous carbon material measured by powder X-ray diffractometry; a carbon-derived spectrum appearing in a range from 3,200 to 3,400 gauss (G) in an electron spin resonance measured using X band; a relative signal intensity ratio (I4.8K/I40K) of the spectrum ranging from 2.4 to 3.5, wherein the relative signal intensity ratio is a ratio of signal intensity (I4.8K) at temperature of 4.8 K to signal intensity (I40K) at temperature of 40K; and a line width (?Hpp) of the spectrum ranging from 70 to 180 gauss (G), wherein the line width is calculated from a first-order derivative spectrum at temperature of 4.8 K.