Patents by Inventor Ofelia Fusco

Ofelia Fusco has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9068028
    Abstract: A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 ?m comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C.
    Type: Grant
    Filed: June 16, 2010
    Date of Patent: June 30, 2015
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gianni Collina, Marco Ciarafoni, Ofelia Fusco, Benedetta Gaddi, Monica Galvan, Giampiero Morini, Roberto Pantaleoni, Francesca Verrocchio
  • Patent number: 9068029
    Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90° C.; (ii) polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with ?-olefins CH2?CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: June 30, 2015
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gianni Collina, Marco Ciarafoni, Ofelia Fusco, Benedetta Gaddi, Monica Galvan, Giampiero Morini, Roberto Pantaleoni, Joachim T. M. Pater, Fabrizio Piemontesi, Francesca Verrocchio
  • Publication number: 20140316069
    Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene (co)polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25° C.
    Type: Application
    Filed: November 7, 2012
    Publication date: October 23, 2014
    Applicant: Basell Polilefine Italia S.r.l.
    Inventors: Monica Galvan, Roberto Pantaleoni, Ofelia Fusco, Benedetta Gaddi, Andreas Neumann, Antonio Mazzucco, Gianni Collina, Marco Ciarafoni
  • Patent number: 8829113
    Abstract: Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 ?gC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: September 9, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Benedetta Gaddi, Marco Ciarafoni, Mara Destro, Ofelia Fusco, Paola Massari, Ines Mingozzi
  • Publication number: 20140235802
    Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (HD) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.
    Type: Application
    Filed: September 17, 2012
    Publication date: August 21, 2014
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Monica Galvan, Roberto Pantaleoni, Ofelia Fusco, Benedetta Gaddi, Andreas Neumann, Antonio Mazzucco, Gianni Collina, Gabriella Sartori
  • Patent number: 8729188
    Abstract: A propylene polymer composition comprising (percent by weight): A) 74%-84% of a propylene homopolymer having a Polydispersity Index (P.I.) value of from 4.6 to 10, a fraction insoluble in xylene at 25° C., higher than 90%, and a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 110 to 200 g/10 min; B) 16%-26%, of a copolymer of propylene with from 39% to 48%, of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.7 and 4.0 dl/g; and a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 30 to 80 g/10 min.
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: May 20, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Monica Galvan, Marco Ciarafoni, Gianni Collina, Ofelia Fusco, Roberto Pantaleoni, Antonio Mazzucco
  • Publication number: 20140121340
    Abstract: Films or sheets of polypropylene, particularly biaxially oriented polypropylene (BOPP) films, exhibiting excellent physical and mechanical properties combined with good processing characteristics can be prepared from propylene polymers prepared in the presence of Ziegler-Natta catalysts comprising a succinate and a diether compound.
    Type: Application
    Filed: June 21, 2012
    Publication date: May 1, 2014
    Applicant: Basell Poliolefine Italia S.r.I
    Inventors: Monica Galvan, Roberto Pantaleoni, Ofelia Fusco, Benedetta Gaddi, Andreas Neumann, Antonio Mazzucco, Gianni Collina
  • Publication number: 20130274428
    Abstract: A solid adduct comprising magnesium chloride and ethanol in which the moles of ethanol per mole of magnesium chloride range from 2 to 5 and in which the ratio between the average pore radius measured in Angstrom of said adduct, determined by mercury porosity, and the moles of ethanol, is higher than 500.
    Type: Application
    Filed: December 16, 2011
    Publication date: October 17, 2013
    Applicant: Bassell Poliolefine Italia S.r.l.
    Inventors: Gianni Collina, Daniele Evangelisti, Ofelia Fusco, Benedetta Gaddi
  • Publication number: 20130211011
    Abstract: Automotive interior element comprising a polypropylene composition comprising (percent by weight): A) from 60% to 90% of a propylene homopolymer having: i) a polydispersity Index (P.I.) value of from 3.5 to 10.0; ii) a fraction insoluble in xylene at 25° C., higher than 90%; and iii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 50 to 200 g/10 min; B) from 10% to 40%; of a copolymer of propylene with from 30% to 60% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.5 and 4.0 dl/g; a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 15 to 100 g/10 min and all the three values of carbon emission measured according to VDA 227 (C-emission) are lower than 30.0 ?gC/g; wherein the values of carbon emission are measured in the ex reactor propylene composition.
    Type: Application
    Filed: October 12, 2011
    Publication date: August 15, 2013
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Benedetta Gaddi, Marco Ciarafoni, Mara Destro, Ofelia Fusco, Paola Massari, Ines Mingozzi
  • Publication number: 20120232221
    Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90° C.; (ii) polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with a-olefins CH2?CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer.
    Type: Application
    Filed: November 15, 2010
    Publication date: September 13, 2012
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: Gianni Collina, Marco Ciarafoni, Ofelia Fusco, Benedetta Gaddi, Monica Galvan, Giampiero Morini, Roberto Pantaleoni, Joachim T.M. Pater, Fabrizio Piemontesi, Francesca Verrocchio
  • Publication number: 20120178881
    Abstract: A propylene polymer composition comprising (percent by weight): A) 74%-84% of a propylene homopolymer having a Polydispersity Index (P.I.) value of from 4.6 to 10, a fraction insoluble in xylene at 25° C., higher than 90%, and a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 110 to 200 g/10 min; B) 16%-26%, of a copolymer of propylene with from 39% to 48%, of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 2.7 and 4.0 dl/g; and a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 30 to 80 g/10 min.
    Type: Application
    Filed: August 26, 2010
    Publication date: July 12, 2012
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: Monica Galvan, Marco Ciarafoni, Gianni Collina, Ofelia Fusco, Roberto Pantaleoni, Antonio Mazzucco
  • Publication number: 20120083576
    Abstract: A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 ?m comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C.
    Type: Application
    Filed: June 16, 2010
    Publication date: April 5, 2012
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: Gianni Collina, Marco Ciarafoni, Ofelia Fusco, Benedetta Gaddi, Monica Galvan, Giampiero Morini, Roberto Pantaleoni, Francesca Verrocchio
  • Publication number: 20110251352
    Abstract: Prepolymerized catalyst component for the polymerization of olefins CH2?CHR, wherein R is hydrogen or a C1-C12 hydrocarbyl group, comprising a solid catalyst component characterized by comprising Mg, Ti halogen and an electron donor (ID) selected from the alkyl esters of aromatic dicarboxylic acids in such an amount that the molar ratio ID/Mg ranges from 0.025 to 0.07 and the Mg/Ti molar ratio is higher than 13, said prepolymerized catalyst component containing an amount of ethylene pre-polymer up to 50 g per g of said solid catalyst component.
    Type: Application
    Filed: September 17, 2009
    Publication date: October 13, 2011
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: Gianni Collina, Anna Fait, Ofelia Fusco, Giampiero Morini, Lorella Pedriali, Rosa Spoto, Paolo Vincenzi
  • Patent number: 7932206
    Abstract: Solid Lewis adducts comprising MgCl2, a Lewis base (LB) belonging to ethers, esters, ketones, silanes or amines and an alcohol ROH, in which R is a C1-C15 hydrocarbon group optionally substituted with heteroatoms containing groups, which compounds are in molar ratios to each other defined by the following formula MgCl2(ROH)m(LB)n in which m ranges from 0.05 to 6, n ranges from 0.08 to 6. The solid Lewis adducts herein can be used to prepare catalysts having good morphological stability, and high polymerization activity.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: April 26, 2011
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Diego Brita, Andrea Casalini, Daniele Evangelisti, Ofelia Fusco, Gianni Collina
  • Publication number: 20100292419
    Abstract: Prepolymerized catalyst component for the polymerization of olefins CH2?CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, having average particle size equal to or lower than 30 ?m comprising a solid catalyst component comprising magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other one being selected from esters of aromatic mono or dicarboxylic acids, said solid catalyst component being prepolymerized with an olefin, having from 2 to 10 carbon atoms, to such an extent that the amount of the olefin prepolymer is equal to or lower than 50 g per g of solid catalyst component.
    Type: Application
    Filed: December 22, 2008
    Publication date: November 18, 2010
    Applicant: Basell Poliolefine Italia s.r.l.
    Inventors: Gianni Collina, Ofelia Fusco
  • Publication number: 20100249330
    Abstract: Process for the production of propylene polymers having a Melt Flow rate (230° C., 2.16 Kg) higher than 30 g/10? and preferably higher than 50 g/10? and also characterized by having broad molecular weight distribution (MWD) carried out in the presence of a catalyst system comprising (a) a solid catalyst component containing Mg, Ti, halogen and an electron donor compound selected from succinates; (b) an alkylaluminum cocatalyst; and (c) a silicon compound of formula R1Si(OR)3 in which R1 is a branched alkyl and R is, independently, a C1-C10 alkyl.
    Type: Application
    Filed: October 2, 2008
    Publication date: September 30, 2010
    Applicant: Basell Poliolefine Italia s.r.l.
    Inventors: Paola Massari, Marco Ciarafoni, Ofelia Fusco, Hirofumi Murakami, Takeshi Nakajima, Shintaro Takemiya
  • Publication number: 20100240845
    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor is obtained by a batch process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, in a liquid medium comprising a titanium compound having at least a Ti—Cl bond at a temperature ranging from 0° C. to 80° C. and then removing the liquid medium; (B) A subsequent step comprising reacting the solid product obtained in (A) in a liquid medium comprising an electron donor ED selected from ethers, esters, ketones, silanes, amines, nitriles and amides, and a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C. and then, after removing the liquid medium; (C) A subsequent step comprising reacting the solid product coming from (B) with a liquid medium comprising a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.
    Type: Application
    Filed: June 7, 2007
    Publication date: September 23, 2010
    Applicant: Basell Poliolefine Italia s.r.l.
    Inventors: Gianni Collina, Maria Di Diego, Ofelia Fusco, Giampiero Morini, Paolo Vincenzi
  • Publication number: 20100240846
    Abstract: Catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and 1,3-diethers as internal donors having an improved balance of properties in terms of activity and morphological stability are obtained by a process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, with a titanium compound having at least a Ti—Cl bond at a reaction temperature ranging from 0° C. to 80° C.; (B) A subsequent step comprising contacting the solid product obtained in (A) with an electron donor ED selected from 1,3 diethers with a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.; and (C) A subsequent step comprising reacting the solid product coming from (B) with a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.
    Type: Application
    Filed: June 1, 2007
    Publication date: September 23, 2010
    Applicant: BASEL POLIOLEFINE ITALIA S.R.L.
    Inventors: Gianni Collina, Ofelia Fusco, Benedetta Gaddi, Giampiero Morini, Mario Sacchetti, Gianni Vitale
  • Patent number: 7772324
    Abstract: An olefin polymer composition comprising (by weight, unless otherwise specified): A) 60-85% of a crystalline propylene homopolymer or a crystalline copolymer of propylene containing 3% or less of ethylene or C4-C10 ?-olefin(s) or of combinations thereof, said homopolymer or copolymer having a Polydispersity Index (P.I.) value of from 4.5-6 and a content of isotactic pentads (mmmm), measured by 13C NMR on the fraction insoluble in xylene at 25° C., higher than 96%; B) 15-40% of a partially amorphous copolymer of ethylene containing from 35% to 70% of propylene or C4-C10 ?-olefin(s) or of combinations thereof, and optionally minor proportions of a diene. The said olefin polymer composition exhibits a value of elongation at break ranging from 150 to 600% according to ISO method 527.
    Type: Grant
    Filed: September 5, 2005
    Date of Patent: August 10, 2010
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Paola Massari, Andreas Newmann, Gianni Collina, Ofelia Fusco
  • Patent number: 7560521
    Abstract: A catalyst component for the polymerization of olefins comprising a titanium compound, a Mg-dihalide, a difunctional electron donor compound (ED) selected from diesters, diketones, diamines or diethers, and a monofunctional electron donor compound (MD) selected from ethers, esters, amines or ketones, wherein a molar ratio ED/MD is higher than 10.
    Type: Grant
    Filed: August 5, 2005
    Date of Patent: July 14, 2009
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Gianni Collina, Ofelia Fusco, Diego Brita