Abstract: Methods of adding a catalyst to a bulk polymerization process may include mixing the catalyst with propylene to form a catalyst mixture that is substantially free of any C20 or greater hydrocarbons, feeding the catalyst mixture into a polymerization reactor, activating the catalyst mixture; and performing a polymerization on the catalyst mixture in the polymerization reactor. Polymers may be formed by polymerization processes that are substantially free of any C20 or greater hydrocarbons.

Abstract: Methods may include reacting an antistatic agent with at least one alkylaluminum to form an antistatic complex and may further include feeding the antistatic complex into a polymerization process wherein the antistatic agent is an ester of a fatty acid. Methods of using an antistatic agent in a polymerization process may include feeding the antistatic agent into the polymerization process and, subsequently, reacting the antistatic agent with at least one alkylaluminum, wherein the antistatic agent with the at least one alkylaluminum gives an antistatic complex that comprises one or more reaction products between the ester of the fatty acid and the at least one alkylaluminum, wherein the one or more reaction products comprise aluminum soaps.

Abstract: Methods of adding a catalyst to a bulk polymerization process may include mixing the catalyst with propylene to form a catalyst mixture that is substantially free of any C20 or greater hydrocarbons, feeding the catalyst mixture into a polymerization reactor, activating the catalyst mixture; and performing a polymerization on the catalyst mixture in the polymerization reactor. Polymers may be formed by polymerization processes that are substantially free of any C20 or greater hydrocarbons.

Abstract: Methods may include reacting an antistatic agent with at least one alkylaluminum to form an antistatic complex, and may further include feeding the antistatic complex into a polymerization process. Methods of using an antistatic agent in a polymerization process may include feeding the antistatic agent into the polymerization process and, subsequently, reacting the antistatic agent with at least one alkylaluminum.

Abstract: A process of producing a composition comprising a copolymer of ethylene and one or more C4-C8 ?-olefins, may include copolymerizing the ethylene and the one or more C4-C8 ?-olefins in the presence of a procatalyst and an alkylaluminum cocatalyst. The procatalyst may be a Ti-containing Ziegler Natta procatalyst and the polymerization may include the procatalyst and the alkylaluminum cocatalyst in amounts such that a molar ratio of Al:Ti ranges from about 0.5 to about 50.0.

Abstract: A process for preliminary polymerization may include washing a catalyst mud comprising a supported metallocene catalyst with at least one saturated hydrocarbon at a temperature from 0° C. to 40° C., a pressure from 20 to 40 kgf/cm2, and a residence time of at least 30 minutes; continuously feeding the washed catalytic mud to a continuous pre-polymerization reactor; and pre-polymerizing, in the continuous pre-polymerization reactor, ethylene and at least one C4 to C10 ?-olefin as comonomer, with the washed catalytic mud, to produce a pre-polymer; wherein an average residence time in the continuous pre-polymerization reactor is more than 90 minutes and less than 240 minutes, a reactor temperature is from 10° C. to 50° C., and a reactor pressure from 20 to 40 kgf/cm2.

Abstract: A process for propylene preliminary polymerization in liquid phase that occurs in a continuous preliminary polymerization reactor may include feeding a propylene monomer and a Ziegler-Natta catalyst system having (a) a pro-catalyst having an internal electron donor comprising a substituted phenylene aromatic diester, (b) a catalyst activator and optionally (c) an external donor, into the continuous preliminary polymerization reactor, wherein the feeding is carried out without pre-contact of the pro-catalyst with the catalyst activator, and also without pre-contact of the catalyst activator with the propylene monomer before entering the continuous preliminary polymerization reactor.

Abstract: A method of forming polymerization auxiliaries for a polymerization process may include combining an antifouling agent with a killer agent to form an auxiliary composition; and contacting the auxiliary composition with an alkylaluminum. An antifouling complex may be produced by combining an antifouling agent with a killer agent to form an auxiliary composition; and contacting the auxiliary composition with an alkylaluminum.

Abstract: A process for treatment of nanoparticles of mineral filler for obtaining processed nanoparticles for use in polymerization in the presence of nanoparticles which includes the steps of (a) drying a mineral filler with an inert gas to remove catalyst poisons; (b) mixing the mineral filler dried obtained in step (a) with a swelling agent in a liquid state or near a critical state or in the supercritical state; (c) subjecting the swelling agent of the mixture obtained in step (b) to an endoenthalpic or isoentalphic phase change by altering the conditions of the temperature and/or pressure; (d) subjecting the nanoparticles of the mixture obtained in step (c) to contact of scavenging agent to react with catalyst poisons; then the mixture obtained in step (d) can be dried in a step (e) with an inert gas to remove sub-products from scavenging agent and catalyst poisons to obtain the treated nanoparticles.

Abstract: Process for purification of unreacted vinyl acetate monomers comprising the steps of preliminarily loading an adsorbent agent bed with a mixture comprising an inert gas and fresh vinyl acetate; and feeding said adsorbent agent bed with unreacted vinyl acetate monomers to remove acetic acid.

Abstract: A process of producing a composition comprising a copolymer of ethylene and one or more C4-C8 ?-olefins, may include copolymerizing the ethylene and the one or more C4-C8 ?-olefins in the presence of a procatalyst and an alkylaluminum cocatalyst. The procatalyst may be a Ti-containing Ziegler Natta procatalyst and the polymerization may include the procatalyst and the alkylaluminum cocatalyst in amounts such that a molar ratio of Al:Ti ranges from about 0.5 to about 50.0.

Abstract: Methods may include reacting an antistatic agent with at least one alkylaluminum to form an antistatic complex, and may further include feeding the antistatic complex into a polymerization process. Methods of using an antistatic agent in a polymerization process may include feeding the antistatic agent into the polymerization process and, subsequently, reacting the antistatic agent with at least one alkylaluminum.

Abstract: Methods of adding a catalyst to a bulk polymerization process may include mixing the catalyst with propylene to form a catalyst mixture that is substantially free of any C20 or greater hydrocarbons, feeding the catalyst mixture into a polymerization reactor, activating the catalyst mixture; and performing a polymerization on the catalyst mixture in the polymerization reactor. Polymers may be formed by polymerization processes that are substantially free of any C20 or greater hydrocarbons.

Abstract: A method of forming polymerization auxiliaries for a polymerization process may include combining an antifouling agent with a killer agent to form an auxiliary composition; and contacting the auxiliary composition with an alkylaluminum. An antifouling complex may be produced by combining an antifouling agent with a killer agent to form an auxiliary composition; and contacting the auxiliary composition with an alkylaluminum.

Abstract: Process for purification of unreacted vinyl acetate monomers comprising the steps of preliminarily loading an adsorbent agent bed with a mixture comprising an inert gas and fresh vinyl acetate; and feeding said adsorbent agent bed with unreacted vinyl acetate monomers to remove acetic acid.

Abstract: A process for treatment of nanoparticles of mineral filler for obtaining 5 processed nanoparticles for use in polymerization in the presence of nanopartciles which includes the steps of (a) drying a mineral filler with an inert gas for remove catalyst poisons; (b) mixing the mineral filler dried obtained in step (a) with a swelling agent in a liquid state or near a critical state or in the supercritical state; (c) subjecting the swelling agent of the 10 mixture obtained in step (b) to an endoenthalpic or isoentalphic phase change by altering the conditions of the temperature and/or pressure; (d) subjecting the nanoparticles of the mixture obtained in step (c) to contact of scavenging agent to react with catalyst poisons; then the mixture obtained in step (d) can be dried in a step (e) with an inert gas to remove sub-products 15 from scavenging agent and catalyst poisons to obtain the treated nanoparticles.

Abstract: A process for polymerization in the presence of nanoparticles of a mineral filler for obtaining polymer nanocomposites which includes the steps of (a) mixing a mineral filler with a swelling agent in a liquid state or near a critical state or supercritical state; (b) subjecting the swelling agent of the mixture obtained in step (a) to an endoenthalpic or isoenthalpic phase change, by altering the conditions of temperature and/or pressure; and (c) polymerizing a monomer, in a continuous or a batch process, in the presence of the mixture of step (b); wherein the swelling agent is a saturated or unsaturated hydrocarbon, a polar or vinylic organic compound, the same monomer used in the polymerization reaction or an inert compound present as a component of the reaction medium.

Abstract: The present invention refers to a process for the preparation of high performance polymer nanocomposites by means of an in situ continuous or batch polymerization process. More specifically, in this process, the sheet-like (layered) or spherical-like mineral filler is previously swollen with a swelling agent consisting in a saturated or unsaturated hydrocarbon or a polar or vinylic organic compound, in liquid state or near the critical point or in supercritical state, in a stirred continuous flow or batch type reactor, prior to being introduced into a polymerization reactor. The swelling agent is subjected to an endoenthalpic or isoenthalpic phase change upon being mixed with the mineral filler, in order to exfoliate and disperse the same at the nanometric level prior to the polymerization.