Patents by Inventor Oleg V. Samsonov
Oleg V. Samsonov has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11613593Abstract: Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values. M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R1, R1?, R3, R3?, R4, R4?, R7 and R7? are hydrogen. R5, R5?, R6, and R6? are independently a C1-C10, optionally substituted, hydrocarbyl group, or R5 and R6 and/or R5? and R6? are bonded together to form an optionally substituted hydrocarbyl ring structure.Type: GrantFiled: February 11, 2021Date of Patent: March 28, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jo Ann M. Canich, Jian Yang, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Oleg V. Samsonov, Georgy P. Goryunov
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Patent number: 11578148Abstract: A metal complex of the formula (1) TCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is the number 1 or 2, TCy is a thiophene-fused cyclopentadienyl-type ligand of the formula (2) is described. Methods of making and using the metal complex are also described.Type: GrantFiled: December 13, 2018Date of Patent: February 14, 2023Inventors: Alexandra Berthoud, Maxence Valla, Georgy P. Goryunov, Oleg V. Samsonov, Dmitry Y. Mladentsev, Dmitry V. Uborsky, Alexander Z. Voskoboynikov
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Patent number: 11472895Abstract: The present invention provides a compound according to formula (I): (I) wherein: •R2 is abridging moiety containing at least one sp2 hybridised carbon atom; •each R4, R4?, R7 and R7? are hydrogen or moieties comprising 1-10 carbon atoms, wherein each R4, R4?, R7 and R7? are the same; •each R5, R5?, R6 and R6? are moieties comprising 1-10 carbon atoms, wherein each R5, R5?, R6 and R6? are the same; and •Z is a moiety selected from ZrX2, HfX2, or TiX2, wherein X is selected from the group of halogens, alkyls, aryls and aralkyls. Such compound allows for the preparation of catalyst systems that provide improved olefin reactivity, such as ethylene reactivity, increased molecular weight in olefin polymerisation, such as increased Mw in ethylene polymerisation, and increased comonomer incorporation in copolymerisation reactions of olefins, such as in copolymerisation reactions of ethylene with 1-hexene.Type: GrantFiled: August 29, 2019Date of Patent: October 18, 2022Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Coen Hendriksen, Nicolaas Hendrika Friederichs, Jaiprakash Brijlal Sainani, Anamitra Chatterjee, Vyatcheslav Izmer, Dmitry Kononovich, Alexander Voskoboynikov, Vincenzo Busico, Roberta Cipullo, Antonio Vittoria, Oleg V. Samsonov
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Patent number: 11214634Abstract: The present disclosure relates to Lewis base catalysts. Catalysts, catalyst systems, and processes of the present disclosure can provide high temperature ethylene polymerization, propylene polymerization, or copolymerization as the Lewis base catalysts can be stable at high polymerization temperatures and have good activity at the high polymerization temperatures. The stable catalysts with good activity can provide formation of polymers having high melting points, high isotacticity, and controllable molecular weights, and the ability to make an increased amount of polymer in a given reactor, as compared to conventional catalysts. Hence, the present disclosure demonstrates highly active catalysts capable of operating at high reactor temperatures while producing polymers with controlled molecular weights and or robust isotacticity.Type: GrantFiled: February 11, 2020Date of Patent: January 4, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: Georgy P. Goryunov, Oleg V. Samsonov, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
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Publication number: 20210269561Abstract: Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values. M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R1, R1?, R3, R3?, R4, R4?, R7 and R7? are hydrogen. R5, R5?, R6, and R6? are independently a C1-C10, optionally substituted, hydrocarbyl group, or R5 and R6 and/or R5? and R6? are bonded together to form an optionally substituted hydrocarbyl ring structure.Type: ApplicationFiled: February 11, 2021Publication date: September 2, 2021Inventors: Jo Ann M. Canich, Jian Yang, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Oleg V. Samsonov, Georgy P. Goryunov
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Publication number: 20210253749Abstract: The present invention provides a compound according to formula (I): (I) wherein: R2 is a bridging moiety containing at least one sp2 hybridised carbon atom; each R4, R4?, R7 and R7? are hydrogen or moieties comprising 1-10 carbon atoms, wherein each R4, R4?, R7 and R7? are the same; each R5, R5?, R6 and R6? are moieties comprising 1-10 carbon atoms, wherein each R5, R5?, R6 and R6? are the same; and Z is a moiety selected from ZrX2, HfX2, or TiX2, wherein X is selected from the group of halogens, alkyls, aryls and aralkyls. Such compound allows for the preparation of catalyst systems that provide improved olefin reactivity, such as ethylene reactivity, increased molecular weight in olefin polymerisation, such as increased Mw in ethylene polymerisation, and increased comonomer incorporation in copolymerisation reactions of olefins, such as in copolymerisation reactions of ethylene with 1-hexene.Type: ApplicationFiled: August 29, 2019Publication date: August 19, 2021Inventors: Coen HENDRIKSEN, Nicolaas Hendrika FRIEDERICHS, Jaiprakash Brijlal SAINANI, Anamitra CHATTERJEE, Vyatcheslav IZMER, Dmitry KONONOVICH, Alexander VOSKOBOYNIKOV, Vincenzo BUSICO, Roberta CIPULLO, Antonio VITTORIA, Oleg V. SAMSONOV
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Publication number: 20210087305Abstract: A metal complex of the formula (1) TCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is the number 1 or 2, TCy is a thiophene-fused cyclopentadienyl-type ligand of the formula (2) is described. Methods of making and using the metal complex are also described.Type: ApplicationFiled: December 13, 2018Publication date: March 25, 2021Applicant: ARLANXEO NETHERLANDS B.V.Inventors: Alexandra BERTHOUD, Maxence Valla, Georgy P. GORYUNOV, Oleg V, SAMSONOV, Dmitry Y. MLADENTSEV, Dmitry V. UBORSKY, Alexander Z. VOSKOBOYNIKOV
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Patent number: 10807997Abstract: The present disclosure provides methods for making quinolinyldiamine products from quinolinyl starting materials. In addition, the quinolinyldiamines can be used as ligands or ligand precursors for catalysts, e.g. for use in olefin polymerization.Type: GrantFiled: August 26, 2019Date of Patent: October 20, 2020Assignee: ExxonMobil Chemical Patents Inc.Inventors: Oleg V. Samsonov, Mikhail I. Sharikov, Georgy P. Goryunov, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Michelle E. Titone, John R. Hagadorn, Jo Ann M. Canich
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Publication number: 20200255555Abstract: The present disclosure relates to Lewis base catalysts. Catalysts, catalyst systems, and processes of the present disclosure can provide high temperature ethylene polymerization, propylene polymerization, or copolymerization as the Lewis base catalysts can be stable at high polymerization temperatures and have good activity at the high polymerization temperatures. The stable catalysts with good activity can provide formation of polymers having high melting points, high isotacticity, and controllable molecular weights, and the ability to make an increased amount of polymer in a given reactor, as compared to conventional catalysts. Hence, the present disclosure demonstrates highly active catalysts capable of operating at high reactor temperatures while producing polymers with controlled molecular weights and or robust isotacticity.Type: ApplicationFiled: February 11, 2020Publication date: August 13, 2020Inventors: Georgy P. Goryunov, Oleg V. Samsonov, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
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Publication number: 20200071344Abstract: The present disclosure provides methods for making quinolinyldiamine products from quinolinyl starting materials. In addition, the quinolinyldiamines can be used as ligands or ligand precursors for catalysts, e.g. for use in olefin polymerization.Type: ApplicationFiled: August 26, 2019Publication date: March 5, 2020Inventors: Oleg V. Samsonov, Mikhail I. Sharikov, Georgy P. Goryunov, Dmitry Dmitry Uborsky, Alexander Z. Voskoboynikov, Michelle E. Titone, John R. Hagadorn, Jo Ann M. Canich
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Patent number: 10487161Abstract: This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.Type: GrantFiled: October 31, 2017Date of Patent: November 26, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jo Ann M. Canich, Alexander Z. Voskoboynikov, Dmitry V. Uborsky, Ilya S. Borisov, Alexey A. Tsarev, Pavel S. Kulyabin, Mikhail I. Sharikov, Oleg V. Samsonov, Georgy P. Goryunov
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Publication number: 20180066083Abstract: This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.Type: ApplicationFiled: October 31, 2017Publication date: March 8, 2018Inventors: Jo Ann M. Canich, Alexander Z. Voskoboynikov, Dmitry V. Uborsky, Ilya S. Borisov, Alexey A. Tsarev, Pavel S. Kulyabin, Mikhail I. Sharikov, Oleg V. Samsonov, Georgy P. Goryunov
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Patent number: 9834628Abstract: This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.Type: GrantFiled: July 7, 2014Date of Patent: December 5, 2017Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jo Ann M. Canich, Alexander Z. Voskoboynikov, Dmitry V. Uborsky, Ilya S. Borisov, Alexey A. Tsarev, Pavel S. Kulyabin, Mikhail I. Sharikov, Oleg V. Samsonov, Georgy P. Goryunov
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Patent number: 9321858Abstract: Disclosed are new classes of pyridyldiamide catalyst components useful in olefin polymerization, an example of which includes: wherein M is a hafnium or zirconium; R1 and R11 are selected from phenyl and substituted phenyl, wherein the substitutions are selected from C1 to C5 hydrocarbyls, preferably C2 to C4 hydrocarbyls, and can reside in any of the ortho, meta, para positions on the phenyl ring; R2? and R2? are selected independently from hydrogen and C1 to C6 hydrocarbyls, preferably hydrogen; R10 is a hydrocarbyl bridging group; R3, R4, and R5 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; and R6, R7, R8, and R9 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; wherein R6 and R7 form an aromatic ring or R7 is hydrogen and R6 is selected from methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, and tert-butyl, preferably methyl.Type: GrantFiled: April 22, 2014Date of Patent: April 26, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R. Hagadorn, Ilya S. Borisov, Arkady K. Golenishchev, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Oleg V. Samsonov, Michail I. Sharikov
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Publication number: 20150025207Abstract: This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.Type: ApplicationFiled: July 7, 2014Publication date: January 22, 2015Inventors: Jo Ann M. Canich, Alexander Z. Voskoboynikov, Dmitry V. Uborsky, Ilya S. Borisov, Alexey A. Tsarev, Pavel S. Kulyabin, Mikhail I. Sharikov, Oleg V. Samsonov, Georgy P. Goryunov
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Publication number: 20140316089Abstract: Disclosed are new classes of pyridyldiamide catalyst components useful in olefin polymerization, an example of which includes: wherein M is a hafnium or zirconium; R1 and R11 are selected from phenyl and substituted phenyl, wherein the substitutions are selected from C1 to C5 hydrocarbyls, preferably C2 to C4 hydrocarbyls, and can reside in any of the ortho, meta, para positions on the phenyl ring; R2? and R2? are selected independently from hydrogen and C1 to C6 hydrocarbyls, preferably hydrogen; R10 is a hydrocarbyl bridging group; R3, R4, and R5 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; and R6, R7, R8, and R9 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; wherein R6 and R7 form an aromatic ring or R7 is hydrogen and R6 is selected from methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, and tert-butyl, preferably methyl.Type: ApplicationFiled: April 22, 2014Publication date: October 23, 2014Inventors: John R. Hagadorn, Ilya S. Borisov, Arkady K. Golenishchev, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Oleg V. Samsonov, Michail I. Sharikov