Abstract: The clean-up of crude oil is accomplished using an oil solubilizing agent from a class of onium halides to solubilize the oil in water. The oil solubilizing agent includes a quaternary phosphonium halide, a quaternary ammonium halide, or a ternary sulfonium halide. The onium halide also includes a hydrophobic hydrocarbon chain having from 10 to 24 carbon atoms, and can include both aromatic and aliphatic components.

Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The corrosion inhibiting additive is a stannous salt of a non-carbon acid.

Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The preferred corrosion inhibiting additive is an aqueous solution of a stannous halide, preferably stannous chloride.

Abstract: The present invention provides a method and compositions useful for inhibiting corrosion of a corrodible metal resulting from contact of water and air with the metal. In this method, a stannous salt and a hydrocarbyl substituted succinimide of a polyethylene polyamine are added to the water in minor amounts and cooperatively reduce corrosion of the metal to a substantially zero rate. While the amount of each agent for an effective inhibition is minor, say in the range of from about 0.1 to 100 ppm, a relatively concentrated solution is required for addition to the water. Suitable solvent media include the lower alkanols and mixture thereof with or without added water. Isopropanol is preferred. The solvent component of the compositions also varies depending upon the particular imide and/or salt component employed and the concentration desired.

Abstract: The present invention relates to a method for chemically treating structures fabricated from titanium based alloy compositions which compositions inherently possess positive open circuit corrosion potentials and reduced rates of corrosion properties. The method comprises contacting said fabricated structures with an aqueous pickling solution of hydrofluoric and sulfuric acids at a temperature of at least ambient temperature. This contact is continued for a time sufficient to remove any deleterious oxide layers adhered to the surfaces of the alloy compositions of the fabricated structures.

Abstract: An improved process is provided for the removal and recovery of acidic gases contained in mixed gas streams. The improvements comprise cooling a process regenerated aqueous alkanolamine solution containing an alkanolamine concentration ranging up to about 20 percent by weight to a temperature ranging up to about 35.degree. C. and introducing said cooled regenerated solution into an absorption zone to contact a mixed gas stream containing acidic gases and wherein the regenerated aqueous alkanolamine solution remains essentially at the temperature to which it is cooled throughout a substantial portion of the absorption zone.

Abstract: A method for substantially removing both alkaline earth metal cations and dissolved acidic gases from a water source contaminated therewith to produce a substantially nonscaling and noncorroding water supply therefrom. The method includes contacting the contaminated water source with an ion exchange resin to substantially remove the metal cation contaminants contained therein and produce a demineralized intermediate effluent having a pH of less than about 3.5. The demineralized intermediate effluent then is stripped of the acidic gas contaminants dissolved therein and the pH of the stripped effluent adjusted to a value in the range of from about 9.0 to about 10.0.

Abstract: The present invention relates to titanium base alloy compositions having substantially improved resistance to corrosion in mineral acid environments and to structures fabricated therefrom. More particularly, the present invention relates to titanium base alloy compositions containing iron and copper in certain specified amounts, the remainder being substantially all titanium apart from incidental impurities therein and to anode structures fabricated therefrom for use in the electrolytic manufacture of battery grade manganese dioxide.

Abstract: An improved system for monitoring cathodic protection systems for marine installations wherein a reference electrode is utilized to measure and periodically monitor the cathodic reference potentials. The reference electrode is connected to one end of a cable and the opposite end portion of the cable is operatively connected to a reel. The reel is connected electrically to the marine installation through a voltmeter and the voltmeter provides readouts of the measured cathodic reference potentials. The present invention includes an improved reel which includes a contactor assembly adapted to maintain electrical continuity between the reel and the voltmeter as the cable is being wound onto and unwound from portions of the reel.

Abstract: A method for the preparation of electrolytic manganese dioxide is provided employing improved cathodes, said cathodes being characterized by their reduced tendency to corrode and undergo buildup of current inhibiting scale under electrolytic conditions. The improved cathodes are fabricated from copper comprised of at least about 99.95 weight percent of copper, from about 0.001 to about 0.085 weight percent of silver and up to about 0.003 weight percent of phosphorous. The weight ratio of phosphorous to silver in said copper cathode will be no greater than about 2.0 to 1.0.

Abstract: This invention relates to a method for preparing an improved electrode comprised of titanium and platinum joined to one another in such manner as to resist separation by corrosion when utilized in a cathodic protection system in a corrosive environment such as in a shell and tube heat exchanger.

Abstract: A process for oxidizing a metal of variable valence to a higher valence state by electrochemical means. More particularly, a process for oxidizing a metal of variable valence, such as, for example, uranium or vanadium contained in wet process phosphoric acid to a higher valence state for extraction by subsequent contact with complex organic extractants. The wet process phosphoric acid is oxidized in an electrolytic cell operated at a constant current density. The cell comprises a tank having at least one anode having a surface coating containing manganese dioxide and at least one cathode, said anode and cathode having a ratio of surface areas exposed to the electrolyte in said cell of from at least about 100:1.

Abstract: A process for beneficiating ilmenite ore using electrolytic reduction. The ilmenite ore is admixed with an acidic solution to form a mixture. The mixture is electrolytically reduced to convert at least a portion of any ferric iron that is present to ferrous iron. The acidic solution dissolves the ferrous iron in the ilmenite ore and yields beneficiated ilmenite having a relatively high titanium dioxide content.

Abstract: A process for oxidizing a metal of variable valence to a higher valence state by electrochemical means. More particularly, a process for oxidizing a metal of variable valence, such as, for example, uranium or vanadium contained in wet process phosphoric acid to a higher valence state for extraction by subsequent contact with complex organic extractants. The wet process phosphoric acid is oxidized in an electrolytic cell operated at a controlled potential via use of a reference electrode. The cell comprises a tank having at least one anode and at least one cathode, said anode and cathode having a ratio of surface areas exposed to the electrolyte in said cell of from at least about 100:1.

Abstract: An apparatus and procedure for measuring internal metal stress and determining the effectiveness of metal stress-relief treatments. More specifically, an apparatus and procedure for determining the effectiveness of metal stress-relief by heat treatment in the heat-affected zone surrounding a metal weld. The apparatus comprises an electrical half-cell and a unique bridge system designed to provide intimate physical contact between the electrical half-cell and a metal surface. The apparatus permits a metal to half-cell electrical potential measurement to be made at various locations upon the metal surface. The electrical potential measurements provide a means of evaluating the efficiency of a stress-relief treatment in reducing internal stress within a metal.

Abstract: A process and apparatus for oxidizing vanadium and uranium in wet process phosphoric acid to a higher valence state for extraction by subsequent contact with complex organic extractants. The wet process phosphoric acid is oxidized in an electrolytic cell operated at a controlled potential via use of a reference electrode. The cell comprises a tank having at least one high surface area anode and at least one high surface area cathode separated by an ion exchange membrane.

Abstract: The present invention provides a process for rapidly and efficiently oxidizing either or both vanadium and uranium from the trivalent and guadrivalent oxidation states, respectively, to the pentavelent and hexavalent oxidation states, respectively, through the use of a special electrode. The electrode is produced by anodically treating a substrate material selected from the group of titanium, zirconium, niobium, hafnium and alloys thereof in an aqueous electrolyte. The electrolyte comprises an aqueous solution of manganous ion in a concentration of from about 15 to 50 gm/l and from about 10 to 40 gm/l sulfuric acid. Manganese dioxide is electrodeposited on the substrate to form the electrode. The manganese dioxide coated electrode then is placed in an oxidation cell as an anode wherein it is potentiostaticly controlled to oxidize either or both vanadium and uranium without significant anode deterioration and without oxygen generation at the anode.

Abstract: An apparatus and procedure for measuring internal metal stress and determining the effectiveness of metal stress-relief treatments. More specifically, an apparatus and procedure for determining the effectiveness of metal stress-relief by heat treatment in the heat-affected zone surrounding a metal weld. The apparatus comprises an electrical half-cell and a unique bridge system designed to provide intimate physical contact between the electrical half-cell and a metal surface. The apparatus permits a metal to half-cell electrical potential measurement to be made at various locations upon the metal surface. The electrical potential measurements provide a means of evaluating the efficiency of a stress-relief treatment in reducing internal stress within a metal.

Abstract: The present invention relates to an improved method of treating a substrate material selected from the group consisting of titanium, tantalum, zirconium, niobium, hafnium and their alloys to form an electrode. Broadly, the improved method comprises anodically treating the substrate material in an electrolyte containing fluoride ions under controlled potential conditions.

Abstract: An improved bipolar electrode having an anodic member and a cathodic member connected in an assembled position spaced a distance apart via a fastener assembly disposed between the anodic member and the cathodic member. In one aspect of the present invention, a portion of the fastener assembly is constructed of an electrically conductive material and, in this aspect, the fastener assembly establishes electrical continuity between the anodic member and the cathodic member in addition to providing the mechanical interconnection between the anodic member and the cathodic member.