Abstract: The present invention relates to a process for restabilizing free-radically polymerizable monomers. The process comprises the steps: (a) introduction of a solution of an inhibitor of the free-radical polymerization by means of an inert pressurized gas into a vessel (1) comprising the monomers via a line (10) which comprises an ascending region, and (b) mixing of the contents of the vessel and the inhibitor solution by blowing gas through the line (10). In step (a), the flow velocity of the pressurized gas is set so that plug flow or annular flow is obtained as flow regime of the inhibitor solution and in step (b) the superficial gas velocity is set to ?0.1 mm/s. The present invention further relates to a supply unit (11) for carrying out the process.

Abstract: The invention relates to the use of a gas or liquid-jet curtain generated by spraying non-flammable gases or liquids for diluting and/or ejecting clouds of flammable gases, the density of which does not exceed the density of air, from containments that have one or more outer openings, and also to a method for diluting and/or ejecting clouds of flammable gases, the density of which does not exceed the density of air, from containments that have one or more outer openings, wherein, by spraying non-flammable gases or liquids at at least one outer opening, a gas or liquid-jet curtain is generated that dilutes the clouds of flammable gases situated in the containment or bears them in the direction of the at least one outer opening and thus ejects them.

Abstract: The invention relates to the use of a gas or liquid-jet curtain generated by spraying non-flammable gases or liquids for diluting and/or ejecting clouds of flammable gases, the density of which does not exceed the density of air, from containments that have one or more outer openings, and also to a method for diluting and/or ejecting clouds of flammable gases, the density of which does not exceed the density of air, from containments that have one or more outer openings, wherein, by spraying non-flammable gases or liquids at at least one outer opening, a gas or liquid-jet curtain is generated that dilutes the clouds of flammable gases situated in the containment or bears them in the direction of the at least one outer opening and thus ejects them.

Abstract: The present invention relates to a process for restabilizing free-radically polymerizable monomers. The process comprises the steps: (a) introduction of a solution of an inhibitor of the free-radical polymerization by means of an inert pressurized gas into a vessel (1) comprising the monomers via a line (10) which comprises an ascending region, and (b) mixing of the contents of the vessel and the inhibitor solution by blowing gas through the line (10). In step (a), the flow velocity of the pressurized gas is set so that plug flow or annular flow is obtained as flow regime of the inhibitor solution and in step (b) the superficial gas velocity is set to ?0.1 mm/s. The present invention further relates to a supply unit (11) for carrying out the process.

Abstract: A process for preparing chlorine by oxidation of hydrogen chloride in the presence of a heterogeneous particulate catalyst by the Deacon process in a fluidized-bed reactor (1), in which the heat of reaction is removed by evaporative cooling by means of water which circulates in the tubes (2) of a shell-and-tube heat exchanger, with the water being fed from a steam drum (4) via a feed line (5) to the tubes (2) of the shell-and-tube heat exchanger at one end of these, being heated in the tubes (2) by uptake of the heat of reaction and partly vaporizing to give a water/steam mixture which at the other end of the tubes (2) of the shell-and-tube heat exchanger is recirculated via a return line (6) to the steam drum (4), wherein the maximum pressure for which the fluidized-bed reactor (1) has to be designed to allow for the event of rupture of a tube (2) of the shell-and-tube heat exchanger is minimized by a valve (7) which in the event of a pressure increase as a result of rupture of a tube (2) closes the feed lin

Abstract: A supply system for feeding a fluid to a vessel (1) is described, which is provided with a feedline (10), having a reservoir which is filled with the fluid and a compressed-gas store (14) which can be brought into communication with this reservoir (13), in which system the reservoir (13) and the compressed-gas store (14) are arranged in immediate proximity to one another, and wherein the reservoir (13) can, when required, be brought into communication with the feedline (10) via connection pieces (11, 12).