Patents by Inventor Olivier Braun

Olivier Braun has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20170044292
    Abstract: A comb copolymer having a backbone of 2-acrylamido-2-methylpropanesulfonic acid or a derivative thereof, with grafted lateral side segments of poly(N-alkylacrylamide) or poly(N,N-dialkylacrylamide), is provided. A process for the preparation of the comb copolymer includes reacting a compound of formula (II) with a compound of formula (III) in a (tert-butanol)-water mixture, to obtain a poly(N-alkylacrylamide) or poly(N,N-dialkylacrylamide) telomere of formula (I); reacting in tert-butanol the telomer of formula (I) with an acid chloride of formula (IV) to obtain a solution of the macromonomer of formula (V); and copolymerising in tert-butanol the macromonomer of formula (V) with an ammonium salt of 2-acrylamido-2-methylpropanesulfonic acid.
    Type: Application
    Filed: October 31, 2016
    Publication date: February 16, 2017
    Inventors: Olivier BRAUN, Paul MALLO
  • Publication number: 20160167040
    Abstract: A cross-linked anionic polyelectrolyte resulting from the polymerization, for 100 mol %: (i) of a proportion no smaller than 30 mol % and smaller than 99.5 mol % monomer units from a monomer having a partially or totally salified strong acid function; (ii) of a proportion no smaller than 0.5 mol % and no greater than 5 mol % monomer units from at least one monomer having Formula (I): CH2?CH(CH3)—C(=0)-OR1 (I), wherein Ri is an alkyl radical including 6 to 18 carbon atoms; (iii) of a proportion greater than 0 mol % and no greater than 5 mol % monomer units from at least one diethylene or polyethylene cross-linking monomer; and (iv) optionally, of a proportion smaller than 69.5 mol % monomer units from a neutral monomer. Also, a method for preparing the polyelectrolyte and to the use thereof as a thickener in topical compositions.
    Type: Application
    Filed: July 18, 2014
    Publication date: June 16, 2016
    Applicant: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier BRAUN, Paul MALLO
  • Patent number: 9333162
    Abstract: A linear, branched or cross-linked anionic polyelectrolyte, resulting from the polymerisation, for 100 molar percentage: a) 50% to 99% of monomeric units including a strong, free and partially or completely salified acid function ; b) 1% to 50% of a monomeric units of formula (I): CH2?CH(R1)-C(?O)—O—(CH2)n-CF3 (I), wherein R1 represents H or CH3, and n is 1, 2 or 3; c) optionally greater than 0% to 5% of monomeric units of formula (II): R2-C(?O)—O—[(CH2-CH(R4)-O]m-R3 (II), wherein m is 0 to 50, R2 represents an unsaturated aliphatic monovalent radical with 2 to 4 carbon atoms, R4 represents H, CH3 or CH3CH2 and R3 represents a linear or branched, saturated or unsaturated hydrocarbon aliphatic radical with 8 to 30 carbon atoms, and d) optionally greater than 0% to 5% of at least one monomer with diethylenic or polyethylenic cross-linking. The use thereof as a thickener in topical compositions.
    Type: Grant
    Filed: January 16, 2013
    Date of Patent: May 10, 2016
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo
  • Patent number: 9309342
    Abstract: An anionic polyelectrolyte resulting from the polymerization, for 100% by mass of: a) a mass ratio ?70% and ?98.5% of monomeric units from a monomer with a strong acid function; b) a mass ratio ?0.5% and ?10%, —either of a monomer of formula (1a) : R—(CH2)3-Si(CH2)2-[0-Si(CH3)2-]nO—Si(CH3)2—(CH2)3—R (1a), wherein R represents the monovalent radical: -(0-CH2-CH2-)x[0-CH2—CH(CH3)-]yO—C(?0)-CH?CH2;—or (Ib): Si(CH3)3-[0-Si(CH3)2-]m[0-Si(CH3)[(CH2)3—R]—]pO—Si(CH2)3 (Ib), c) a mass ratio ?1% and ?20% of a monomer of formula (II) : CH2?CH(R1)-C(?0)-0-(CH2)n-CF3 (II), formula (I) wherein radical Ri represents a hydrogen atom or a methyl radical, and n is equal to 1, 2 or 3; d) optionally a mass ratio >0% and ?5% of monomeric units from a monomer of formula (III): R2—C(?0)-0-[(CH2—CH(R4)-0]m-R3 (III), e) optionally a mass ratio >0% and ?5% of a cross-linking monomer, method for its preparation and use as a thickener in topical compositions.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: April 12, 2016
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo
  • Publication number: 20160040028
    Abstract: A straight, branched or cross-linked polymer, including, per 100 mol %: a) a mole fraction from 75% to 99.95% of monomer units from an N,N-dialkyl acrylamide; b) a mole fraction from 0.05% to 1% of monomer units from a monomer of formula (I): CH2=C(Ri)-C(=0)-0-[(CH2-CH(R2)-0]n-R3 (I); c) optionally a mole fraction higher than 0% to 24% either of monomer units from a monomer including a free strong acid function, partially or totally salified, or of monomer units from a monomer of formula (II): CH2=C(R4)-C(=0)-Y-(CH2)m-N(R5)(R6) (II); d) optionally a mole fraction higher than 0% to 1% of a diethylene or polyethylene cross-linking monomer. Also, a method for treating a surface made of a hydrophobic material, using the polymer, and an aqueous, hydro-organic or organic solution including the polymer for modifying interactions between the species contained the solution and the hydrophobic surface.
    Type: Application
    Filed: March 21, 2014
    Publication date: February 11, 2016
    Applicants: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, INSTITUT CURIE, UNIVERSITÉ PIERRE ET MARIE CURIE (PARIS 6)
    Inventors: Jean-Louis VIOVY, Olivier BRAUN
  • Patent number: 9243094
    Abstract: A copolymer that includes for 100 mol %: a) more than 70 mol % and up to 99.9 mol % of hydrophobic monomer units (A) from stearyl methacrylate; and b) 0.1 mol % to 30 mol % of monomer units (B) from at least one monomer of a compound of formula (I) where R1 is a linear or branched alkyl radical comprising 12 to 22 carbon atoms, R2 is a hydrogen atom or a methyl radical, and n is an integer greater than or equal to 0 and lower than or equal to 30, wherein it is understood that said compound of formula (I) is not stearyl methacrylate. The invention also relates to a method for preparing and using same as a modifier of the rheology of the oil phase of a topical cosmetic, dermopharmaceutical, or pharmaceutical composition.
    Type: Grant
    Filed: December 9, 2014
    Date of Patent: January 26, 2016
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Jean-Noel Ollagnier
  • Patent number: 9226889
    Abstract: An anionic polyelectrolyte resulting from the polymerization: a) of a mass ratio greater than or equal to 80% and less than or equal to 99.5% of monomeric units from a monomer with a weak acid function; b) of a mass ratio greater than or equal to 0.5% and less than or equal to 20%, —Either of a monomer of formula (Ia): R—(CH2)3—Si(CH3)2—[O—Si(CH3)2—]nO—Si(CH3)2—(CH2)3—R (Ia), wherein R represents the monovalent radical: —(O—CH2—CH2-)x[O—CH2—CH(CH3)-]yO—C(?O)—CH?CH2, —Or of a monomer of formula (Ib): Si(CH3)3—[O—Si(CH3)2—]m[O—Si(CH3)[(CH2)3—R]—]pO—Si(CH2)3 (Ib), c) optionally of a mass ratio greater than 0% and less than or equal to 5% of monomeric units from at least one monomer of formula (II): R2—C(?O)—O—[(CH2—CH(R4)—O]m—R3 (II), d) optionally of a mass ratio greater than 0% and less than or equal to 5% of at least one monomer with diethylenic or polyethylenic cross-linking; method for the preparation thereof and use as a thickener in topical compositions.
    Type: Grant
    Filed: February 18, 2013
    Date of Patent: January 5, 2016
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo
  • Publication number: 20150337232
    Abstract: This invention involves a process for reducing friction in ethanol during its transport through pipelines. This process involves combining ethanol with a polymer-based composition, characterised in that the polymer is obtained from at least 50 mol % of at least one monomer selected from the group comprising N-substituted acrylamides, N-substituted methacrylamides, N,N-substituted acrylamides, N,N-substituted methacrylamides, substituted acrylates and substituted methacrylates.
    Type: Application
    Filed: May 15, 2015
    Publication date: November 26, 2015
    Applicant: S.P.C.M. SA
    Inventors: Cédrick FAVERO, Olivier BRAUN, Pierrick CHEUCLE, Bernard QUILLIEN
  • Publication number: 20150322192
    Abstract: A comb polymer of which the backbone is 2-acrylamido-2-methylpropanesulfonic acid, onto which poly(N-alkylacrylamide) or poly(N,N-dialkylacrylamide) lateral segments are grafted; process for the preparation thereof comprising: a step (a) of reacting a compound of formula (II) with a compound of formula (III), in a (tert-butanol)-water mixture, so as to obtain a poly(N-alkylacrylamide) or poly(N,N-dialkylacrylamide) telomere of formula (I); a step (c) of reacting, in tert-butanol, the telomer of formula (I) obtained in step (a), with an acid chloride of formula (IV) so as to obtain a solution of the macromonomer of formula (V); a step (e) of copolymerising, in tert-butanol, the macromonomer of formula (V) resulting from step (c), with the ammonium salt of 2-acrylamido-2-methylpropanesulfonic acid and, if desired, a step (f) of purifying the comb polymer obtained in step (e).
    Type: Application
    Filed: May 29, 2013
    Publication date: November 12, 2015
    Applicant: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier BRAUN, Paul MALLO
  • Patent number: 9180085
    Abstract: Novel inverse latices based on fatty alcohol ethers of formula R1—O—R2 (I) in which R1 and R2 represent, independently from one another, a linear or branched alkyl radical comprising from 5 to 18 carbon atoms; and cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical compositions comprising them.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: November 10, 2015
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo, Hervé Rolland
  • Publication number: 20150315319
    Abstract: A comb copolymer consisting of a polymer backbone on which lateral macromonomer segments are grafted, characterised in that said polymer backbone consists: Of more than 55% and up to 90% molar of monomeric units from 2-methyl-2-[(1-oxo-2-propenyl)-amino]-1-propanesulphonic acid (hereinafter referred to as ATBS), Of between 1% and 20% molar, and more specifically of between 4% and 15% molar, either of monomeric units from a cationic monomer or of monomeric units from a monomer of formula (I): CH2?C(R1)—C(?O)—Y—(CH2)m-N(R2)(R3) in which m represents a number of between 1 and 4, Y represents O or NH, R-i represents a hydrogen atom or a methyl radical, R2 and R3, identical or different, represent a methyl radical or an ethyl radical; Optionally of 0.
    Type: Application
    Filed: November 26, 2013
    Publication date: November 5, 2015
    Inventors: Paul MALLO, Olivier BRAUN
  • Publication number: 20150299365
    Abstract: Method for preparing a comb copolymer, includes sequentially: (a) reacting a compound of formula (II): CH2?C(R2)—C(?O)—N(R3)(R4) (II), with a chain-limiting compound of formula (IIIa): HS—R1—NH2 (IIIa) or of formula (IIIb): HS—R1—C(?O)—OH (IIIb), to obtain a poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) telomer, of formula (Ia): H2N—R1—S—{CH2—C(R2)[C(?O)N(R3)(R4)]-}n-H (Ia) or of formula (Ib): HO—C(?O)—R1—S—{CH2—C(R2)[C(?O)N(R3)(R4)]-}n-H (Ib) formula (IIIa) or (IIIb) where n represents a whole number ?2 and ?100; (b) isolating and/or drying the obtained telomer; (c) reacting the telomer of formula (Ia) or of formula (Ib) in tert-butanol with glycidyl methacrylate (IV) to obtain a solution of the macromonomer of formula (Va): CH2?C(R5)-C(?O)—NH—R1—Z—{CH2—C(R2)[C(?O)N(R3)(R4)]-}n-H (Va) or of formula (Vb); CH2?C(R5)-C(?O)—O—(C?O)-R1—Z—{CH2—C(R2)[C(?O)N(R3) (R4)]-}n-H (Vb); (d) isolating and/or drying the obtained telomer; (e) copolymerizing the macromonomer of formula (Va) or of formula (Vb) in tert
    Type: Application
    Filed: November 26, 2013
    Publication date: October 22, 2015
    Inventors: Paul MALLO, Olivier BRAUN
  • Patent number: 9144610
    Abstract: A composition including an oil phase, an aqueous phase, at least one water-in-oil emulsifying system in the form of a positive latex, characterized in that the composition includes a straight, branched, or cross-linked anionic polyelectrolyte, including: a) a non-zero molar proportion of monomer units from acrylic acid in free or partially salified form; and b) a non-zero molar proportion of monomer units from the acid of formula (I): CH2?CH—C(?O)—O—[CH2—CH2—C(?O)—O]n—H??(I), where n is a number greater than or equal to (1) and less than or equal to (5), in free or partially salified form. A method for preparing the same, a polymer powder, and the use thereof as a thickening agent for cosmetic or pharmaceutical compositions are also described.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: September 29, 2015
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo
  • Patent number: 9138703
    Abstract: A novel composition made of polyalkoxylated derivatives of trimethylolpropane and fatty alcohols, the preparation thereof and the use thereof as a reversing agent for a reversible reverse latex.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: September 22, 2015
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Paul Mallo, Herve Rolland, Georges Da Costa, Olivier Braun
  • Patent number: 9101552
    Abstract: A self-reversible reverse latex, and its use as a thickener. The self-reversible reverse latex includes: 50%-70 of a cross-linked polyelectrolyte obtained by the polymerization of a monomer of formula (I), with R1 being 8 to 20 carbon atoms and 1?n?30 for a neutral monomer, and a monomer having an acid function; 4%-10% of a water-in-oil emulsifier; 1%-10% of an oil-in-water emulsifier including a surface-active composition (C); 15%-45% oil; and 0%-5% water. Composition (C) is 10%-50% composition (CII) and 50%-90% composition(CIII). Composition(CII) is 60%-100% of a composition of formula (II), with R2 being a 12 carbon alkyl, T1, T2, and T3 being H or a (—CH2—CH2—O—)mi—H radical with 0?mi?10 and 0<?mi?10. Composition (CIII) is 60%-100% of a compound of formula (III) or mixtures of (III) and (IV), with R2 being as defined previously.
    Type: Grant
    Filed: April 11, 2011
    Date of Patent: August 11, 2015
    Assignee: SOCIETE DEXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo
  • Patent number: 9072684
    Abstract: Polyelectrolyte resulting from polymerization, for 100 mol %, of: a) a molar ratio ?50% and ?99% of monomer units originating from at least one cationic monomer; b) a molar ratio >1% and ?50% of monomer units originating from at least one monomer including a fully or partially salified free weak acid function; c) optionally a molar ratio >0 mol % and ?5 mol % of monomer units originating from at least one monomer of formula A-C(?O)—O—[(CH2—CH(R1)—O]n—R (I), where n is, independently, a number from 1 to 50, A is a monovalent unsaturated aliphatic radical having 2 to 6 carbon atoms, R1 is a hydrogen atom, a methyl radical, or an ethyl radical, and R is a linear or branched, saturated or unsaturated aliphatic hydrocarbon radical having 8 to 30 carbon atoms; and d) optionally a molar ratio >0% and ?1% of a diethylene or polyethylene cross-linking monomer.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: July 7, 2015
    Assignee: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier Braun, Paul Mallo
  • Publication number: 20150098915
    Abstract: Disclosed is a self-reversible reverse latex including: a) 25-80% by mass of a cross-linked anionic polyelectrolyte (P), resulting from the polymerisation, for 100 mole percent: i)—of a molar proportion 30% and 95% of monomeric units from at least one monomer including a free, partially- or totally-salified strong acid function; and ii)—of a molar proportion >0% and <5% of at least one monomer with diethylenic or polyethylenic crosslinking; b) 0.5-10% by mass of a terpolymer of stearyl methacrylate, pentacosaethoxylated behenyl methacrylate and N,N-dimethylacrylamide, resulting from the polymerisation, for 100 mole percent: of 80-95 mole percent of stearyl methacrylate, of 2.5-10 mole percent of N,N-dimethylacrylamide, and of 2.5-10 mole percent of pentacosaethoxylated behenyl methacrylate, c) 5-40% by mass of at least one oil, and d) 0.1-40% by mass of water; method of preparing same and use thereof as a thickener.
    Type: Application
    Filed: May 29, 2013
    Publication date: April 9, 2015
    Applicant: SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Paul Mallo, Olivier Braun
  • Publication number: 20150094440
    Abstract: A copolymer that includes for 100 mol %: a) more than 70 mol % and up to 99.9 mol % of hydrophobic monomer units (A) from stearyl methacrylate; and b) 0.1 mol % to 30 mol % of monomer units (B) from at least one monomer of a compound of formula (I) where R1 is a linear or branched alkyl radical comprising 12 to 22 carbon atoms, R2 is a hydrogen atom or a methyl radical, and n is an integer greater than or equal to 0 and lower than or equal to 30, wherein it is understood that said compound of formula (I) is not stearyl methacrylate. The invention also relates to a method for preparing and using same as a modifier of the rheology of the oil phase of a topical cosmetic, dermopharmaceutical, or pharmaceutical composition.
    Type: Application
    Filed: December 9, 2014
    Publication date: April 2, 2015
    Applicant: SOCIETE D'EXPLOITATION DES PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    Inventors: Olivier BRAUN, Jean-Noel OLLAGNIER
  • Patent number: 8937101
    Abstract: A copolymer that includes for 100 mol %: a) more than 70 mol % and up to 99.9 mol % of hydrophobic monomer units (A) from stearyl methacrylate; and b) 0.1 mol % to 30 mol % of monomer units (B) from at least one monomer of a compound of formula (I) where R1 is a linear or branched alkyl radical comprising 12 to 22 carbon atoms, R2 is a hydrogen atom or a methyl radical, and n is an integer greater than or equal to 0 and lower than or equal to 30, wherein it is understood that said compound of formula (I) is not stearyl methacrylate. The invention also relates to a method for preparing and using same as a modifier of the rheology of the oil phase of a topical cosmetic, dermopharmaceutical, or pharmaceutical composition.
    Type: Grant
    Filed: June 6, 2011
    Date of Patent: January 20, 2015
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC
    Inventors: Olivier Braun, Jean-Noel Ollagnier
  • Publication number: 20150017114
    Abstract: An anionic polyelectrolyte resulting from the polymerization, for 100% by mass of: a) a mass ratio ?70% and ?98.5% of monomeric units from a monomer with a strong acid function; b) a mass ratio ?0.5% and ?10%,—either of a monomer of formula (1a) : R—(CH2)3-Si(CH2)2-[0-Si(CH3)2-]nO—Si(CH3)2—(CH2)3—R (1a), wherein R represents the monovalent radical: -(0-CH2-CH2-)x[0-CH2—CH(CH3)-]yO—C(?0)-CH?CH2;—or (Ib): Si(CH3)3-[0-Si(CH3)2-]m[0-Si(CH3)[(CH2)3—R]—]pO—Si(CH2)3 (Ib), c) a mass ratio ?1% and ?20% of a monomer of formula (II) : CH2?CH(R1)-C(?0)-0-(CH2)n—CF3 (II), formula (I) wherein radical Ri represents a hydrogen atom or a methyl radical, and n is equal to 1, 2 or 3; d) optionally a mass ratio >0% and ?5% of monomeric units from a monomer of formula (III): R2—C(?0)-0-[(CH2—CH(R4)-0]m-R3 (III), e) optionally a mass ratio >0% and ?5% of a cross-linking monomer, method for its preparation and use as a thickener in topical compositions.
    Type: Application
    Filed: February 15, 2013
    Publication date: January 15, 2015
    Inventors: Olivier Braun, Paul Mallo