Patents by Inventor Olivier Guillon
Olivier Guillon has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240139805Abstract: The disclosure relates to a device and a method for sintering. The device for sintering comprises an electrically conductive first component, an electrically conductive second component and at least one electrically conductive surface element for heating a green body to be sintered. The first component and the second component are movable relative to each other and/or relative to the surface element such that an electrical circuit comprising the first component, the surface element and the second component can be closed by the relative movement. In this way, a rapid sintering process is enabled on an industrial scale. The device can be integrated in a particularly simple manner into existing sintering plants, for example, a FAST/SPS sintering plant.Type: ApplicationFiled: February 2, 2022Publication date: May 2, 2024Inventors: Tarini Prasad MISHRA, Martin BRAM, Olivier GUILLON, Ralf STEINERT
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Publication number: 20230397306Abstract: A method and a device for generating light and to a use of a component for emitting light is disclosed. In a method for generating light, a component comprising a first material from the group of cuprates is subjected to an electric voltage and/or an electric field at a temperature T below 0° C. such that the component emits light. In this way, a light generation is provided which is accompanied by a substantial energy saving as well as a significantly reduced technical effort and which is also possible at cryogenic temperatures.Type: ApplicationFiled: September 21, 2021Publication date: December 7, 2023Inventors: Apurv DASH, Robert MÜCKE, Olivier GUILLON
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Publication number: 20230387455Abstract: A solid-state cell, a solid-state battery, and an associated method for producing a solid-state cell is disclosed. A solid-state cell has an electrolyte comprising NaSICON. The solid-state cell comprises a first electrode arranged at a first region of the electrolyte and a second electrode arranged at a second region of the electrolyte. A continuous material layer is arranged at least a third region of the electrolyte on an outer surface of the electrolyte. Alternatively, a chemical composition of the outer surface in the third region of the electrolyte is changed. In this way, the formation of filaments and/or dendrites can be effectively prevented and operation at significantly increased current densities is possible.Type: ApplicationFiled: October 28, 2021Publication date: November 30, 2023Inventors: Qianli MA, Frank TIETZ, Dina FATTAKHOVA-ROHLFING, Olivier GUILLON
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Publication number: 20230382807Abstract: A method for producing a densified component and an article comprising a densified component is disclosed. In a method for producing a densified component, a starting material is subjected to an electric field at a temperature (T) below 800° C. The starting material comprises a first material from the group consisting of cuprates. The method has a low technical effort, since densification is possible without heating the starting material.Type: ApplicationFiled: September 13, 2021Publication date: November 30, 2023Inventors: Apurv DASH, Robert MÜCKE, Olivier GUILLON
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Patent number: 11786870Abstract: Disclosed are a CMS membrane, characterized in that it is obtainable by pyrolysis of a polyimide composed of the monomers 1-(4-aminophenyl)-1,3,3-trimethyl-2H-inden-5-amine and 5-(1,3-dioxo-2-benzofuran-5-carbonyl-2-benzofuran-1,3-dione of the following formulae: preferably by pyrolysis of the polyimide having the CAS number 62929-02-6, and a supported CMS membrane comprising a CMS membrane obtainable from a polyimide by pyrolysis and a porous support, characterized in that a mesoporous intermediate layer is provided between the CMS membrane and the porous support. Further disclosed are a process for preparing the supported membrane, the use of the membranes for separating gas mixtures or liquid mixtures, an apparatus for gas separation or for liquid separation, and the use of the polyimide for preparing a CMS membrane by pyrolysis.Type: GrantFiled: September 16, 2019Date of Patent: October 17, 2023Assignee: Forschungszentrum Jülich GmbHInventors: Patrick Tchoua Ngamou, Mariya E. Ivanova, Wilhelm Albert Meulenberg, Olivier Guillon
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Publication number: 20230184132Abstract: The disclosure relates to a method for operating a gas turbine at a high temperature and to a gas turbine assembly. In the method, a gas turbine having a structural material and a thermal barrier layer disposed on the structural material is cooled down in a decelerated manner after operation at an operating temperature above 1000° C., so that damage to the structural material and/or the thermal barrier layer is minimized. In this way, the gas turbine can be operated permanently at temperatures above 1500° C.Type: ApplicationFiled: April 22, 2021Publication date: June 15, 2023Inventors: Robert VAßEN, Daniel Emil MACK, Martin TANDLER, Olivier GUILLON
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Patent number: 11542204Abstract: The invention relates to a method for producing a non-oxide ceramic powder comprising a nitride, a carbide, a boride or at least one MAX phase with the general composition Mn+1AXn, where M=at least one element from the group of transition elements (Sc, Ti, V, Cr, Zr, Nb, Mo, Hf and Ta), A=at least one A group element from the group (Si, Al, Ga, Ge, As, Cd, In, Sn, Tl and Pb), X=carbon (C) and/or nitrogen (N) and/or boron (B), and n=1, 2 or 3. According to the invention, corresponding quantities of elementary starting materials or other precursors are mixed with at least one metal halide salt (NZ), compressed (pellet), and heated for synthesis with a metal halide salt (NZ). The compressed pellet is first enveloped with another metal halide salt, compressed again, arranged in a salt bath and heated therewith until the melting temperature of the salt is exceeded. Optionally, melted silicate can be added, which prevents the salt from evaporating at high temperatures.Type: GrantFiled: June 7, 2018Date of Patent: January 3, 2023Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Apurv Dash, Jesus Gonzalez, Robert Vassen, Olivier Guillon
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Patent number: 11417870Abstract: Provided is a method for producing an electrode for a solid-state battery comprising providing a multilayer solid ceramic electrolyte that comprises at least one dense layer having a total ion conductivity of at least 1 mS/cm at 25° C. and at least one porous layer having continuous and open pores having an average pore diameter between 1 and 50 ?m; providing an aqueous infiltration fluid comprising at least one organic additive that can be at least partially converted into carbon; introducing the aqueous infiltration fluid into the at least one porous layer of the multilayer solid ceramic electrolyte; and subjecting the multilayer solid ceramic electrolyte to a thermal treatment in the form of sintering in a reducing atmosphere at temperatures between 400° C. and 900° C., whereby the electrode material is synthesized from the precursor of the electrode material on the surface of the pores in situ.Type: GrantFiled: January 15, 2020Date of Patent: August 16, 2022Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Tu Lan, Qianli Ma, Frank Tietz, Olivier Guillon
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Publication number: 20220093910Abstract: Provided is a method for producing an electrode for a solid-state battery comprising providing a multilayer solid ceramic electrolyte that comprises at least one dense layer having a total ion conductivity of at least 1 mS/cm at 25° C. and at least one porous layer having continuous and open pores having an average pore diameter between 1 and 50 ?m; providing an aqueous infiltration fluid comprising at least one organic additive that can be at least partially converted into carbon; introducing the aqueous infiltration fluid into the at least one porous layer of the multilayer solid ceramic electrolyte; and subjecting the multilayer solid ceramic electrolyte to a thermal treatment in the form of sintering in a reducing atmosphere at temperatures between 400° C. and 900° C., whereby the electrode material is synthesized from the precursor of the electrode material on the surface of the pores in situ.Type: ApplicationFiled: January 15, 2020Publication date: March 24, 2022Inventors: Tu Lan, Qianli Ma, Frank Tietz, Olivier Guillon
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Publication number: 20220032237Abstract: Disclosed are a CMS membrane, characterized in that it is obtainable by pyrolysis of a polyimide composed of the monomers 1-(4-aminophenyl)-1,3,3-trimethyl-2H-inden-5-amine and 5-(1,3-dioxo-2-benzofuran-5-carbonyl-2-benzofuran-1,3-dione of the following formulae: preferably by pyrolysis of the polyimide having the CAS number 62929-02-6, and a supported CMS membrane comprising a CMS membrane obtainable from a polyimide by pyrolysis and a porous support, characterized in that a mesoporous intermediate layer is provided between the CMS membrane and the porous support. Further disclosed are a process for preparing the supported membrane, the use of the membranes for separating gas mixtures or liquid mixtures, an apparatus for gas separation or for liquid separation, and the use of the polyimide for preparing a CMS membrane by pyrolysis.Type: ApplicationFiled: September 16, 2019Publication date: February 3, 2022Inventors: Patrick Tchoua Ngamou, Mariya E. Ivanova, Wilhelm Albert Meulenberg, Olivier Guillon
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Patent number: 11065686Abstract: A method for sintering metallic and/or non-oxide components includes completely encapsulating, in a metal halide salt, a green body comprising at least one metallic and/or non-oxide powder, and compressing the encapsulated green body so as to be gastight. The method further includes heating, together with a metal halide salt in the presence of oxygen up to sintering temperatures, the compressed, encapsulated green body. The method additionally includes at least partially dissolving, after cooling, the metal halide salt in a liquid so that the sintered component can be removed.Type: GrantFiled: June 8, 2018Date of Patent: July 20, 2021Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Apurv Dash, Jesus Gonzalez, Robert Vassen, Olivier Guillon
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Publication number: 20210147301Abstract: The invention relates to a method for producing a non-oxide ceramic powder comprising a nitride, a carbide, a boride or at least one MAX phase with the general composition Mn+1AXn, where M=at least one element from the group of transition elements (Sc, Ti, V, Cr, Zr, Nb, Mo, Hf and Ta), A=at least one A group element from the group (Si, Al, Ga, Ge, As, Cd, In, Sn, Tl and Pb), X=carbon (C) and/or nitrogen (N) and/or boron (B), and n=1, 2 or 3. According to the invention, corresponding quantities of elementary starting materials or other precursors are mixed with at least one metal halide salt (NZ), compressed (pellet), and heated for synthesis with a metal halide salt (NZ). The compressed pellet is first enveloped with another metal halide salt, compressed again, arranged in a salt bath and heated therewith until the melting temperature of the salt is exceeded. Optionally, melted silicate can be added, which prevents the salt from evaporating at high temperatures.Type: ApplicationFiled: June 7, 2018Publication date: May 20, 2021Inventors: Apurv DASH, Jesus GONZALEZ, Robert VASSEN, Olivier GUILLON
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Patent number: 10752555Abstract: A method for producing a transparent polycrystalline ceramic includes forming at least one planar transparent region near a surface within the ceramic, wherein the at least one planar transparent region has a lower thermal expansion coefficient than other regions of the ceramic. The method further includes generating compressive stresses in the at least one planar transparent region near the surface after a thermal treatment and cooling.Type: GrantFiled: June 29, 2017Date of Patent: August 25, 2020Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Olivier Guillon, Marc Rubat Du Merac, Martin Bram
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Publication number: 20200216942Abstract: A method for coating, with a coating material, a monocrystalline substrate surface of a component comprising a monocrystalline alloy includes polishing the monocrystalline substrate surface, transferring the substrate to a vacuum chamber, and heating the entire substrate to a temperature of at least half a melting temperature of the substrate but less than a melting temperature of the substrate. The method further includes applying the coating material in powder form onto the polished monocrystalline substrate surface by vacuum plasma spraying. The powder has a mean particle size in a range of 10 to 200 ?m. A pressure in a range of 1 to 200 mbar is set for the vacuum plasma spraying, and an argon atmosphere having a hydrogen content in a range of 10 to 50 vol. % is used as a working gas for the vacuum plasma spraying.Type: ApplicationFiled: October 4, 2018Publication date: July 9, 2020Inventors: Tobias Kalfhaus, Robert Vassen, Olivier Guillon
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Publication number: 20200171575Abstract: A method for sintering metallic and/or non-oxide components includes completely encapsulating, in a metal halide salt, a green body comprising at least one metallic and/or non-oxide powder, and compressing the encapsulated green body so as to be gastight. The method further includes heating, together with a metal halide salt in the presence of oxygen up to sintering temperatures, the compressed, encapsulated green body. The method additionally includes at least partially dissolving, after cooling, the metal halide salt in a liquid so that the sintered component can be removed.Type: ApplicationFiled: June 8, 2018Publication date: June 4, 2020Inventors: Apurv DASH, Jesus GONZALEZ, Robert VASSEN, Olivier GUILLON
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Patent number: 10566654Abstract: A method for preparing electrolyte material having a NASICON structure, based on a Na3+xScxZr2?x(SiO4)2(PO4) compound where 0?x<2. The method includes providing an acidic, aqueous solution which, according to a desired stoichiometry, comprises sodium, scandium and zirconium in the form of water-soluble nitrates, acetates or carbonates, and soluble silicates or orthosilicic acids or organic silicon compounds in dissolved form; subsequently adding phosphoric acid or ammonium dihydrogenphosphate or other soluble phosphates, according to the desired stoichiometry, complex zirconium dioxide phosphates forming as colloidal precipitations; and subsequently drying and calcining the mixture.Type: GrantFiled: August 27, 2016Date of Patent: February 18, 2020Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Qianli Ma, Frank Tietz, Sahir Naqash, Olivier Guillon
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Patent number: 10403881Abstract: A method for producing a ceramic cathode layer on an electrically conductive substrate includes applying a coating to the electrically conductive substrate, the coating being in a form of a suspension including at least one suspending agent and at least one ceramic material. The method further includes heating the coating in a reducing atmosphere such that the ceramic material is completely or in part reduced to a fusible reaction product, heating the coating in a reducing atmosphere to temperatures above the melting point of the reaction product so as to form a melt, densifying or sintering the coating in a reducing atmosphere at temperatures that are 100° C. greater than a melting temperature of the reaction product, and reoxidizing the densified or sintered coating in an oxidizing atmosphere in a temperature range of between 400° C. and 1,200° C.Type: GrantFiled: December 9, 2016Date of Patent: September 3, 2019Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Juergen Dornseiffer, Hans-Gregor Gehrke, Manuel Krott, Olivier Guillon, Sven Uhlenbruck
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Publication number: 20190127285Abstract: A method for producing a transparent polycrystalline ceramic includes forming at least one planar transparent region near a surface within the ceramic, wherein the at least one planar transparent region has a lower thermal expansion coefficient than other regions of the ceramic. The method further includes generating compressive stresses in the at least one planar transparent region near the surface after a thermal treatment and cooling.Type: ApplicationFiled: June 29, 2017Publication date: May 2, 2019Inventors: Olivier GUILLON, Marc RUBAT DU MERAC, Martin BRAM
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Patent number: 10270126Abstract: A method for preparing a lithium titanium phosphate, wherein a sol-gel process is used to prepare the phosphate, includes producing a sol from source materials; converting the sol to a gel; and drying the gel to obtain a corresponding powder comprising the lithium titanium phosphate. In a substep, the method further includes adding titanium(IV) isopropoxide to water to produce precipitates of titanium hydroxide oxide, cooling a system down to a temperature of less than 10° C., and redissolving the precipitates by adding nitric acid to form an aqueous TiO2+ nitrate solution. The lithium titanium phosphate has a general composition Li1+x+yMxTi2?x(PO4)3?y(SiO4)y, wherein M=Al, Ga, In, Sc, V, Cr, Mn, Co, Fe, Y, La—Lu, wherein 0?x?0.5, and wherein 0?y?0.5.Type: GrantFiled: August 19, 2015Date of Patent: April 23, 2019Assignee: FORSCHUNGSZENTRUM JUELICH GMBHInventors: Qianli Ma, Frank Tietz, Olivier Guillon
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Publication number: 20190013512Abstract: A method for producing a ceramic cathode layer on an electrically conductive substrate includes applying a coating to the electrically conductive substrate, the coating being in a form of a suspension including at least one suspending agent and at least one ceramic material. The method further includes heating the coating in a reducing atmosphere such that the ceramic material is completely or in part reduced to a fusible reaction product, heating the coating in a reducing atmosphere to temperatures above the melting point of the reaction product so as to form a melt, densifying or sintering the coating in a reducing atmosphere at temperatures that are 100° C. greater than a melting temperature of the reaction product, and reoxidizing the densified or sintered coating in an oxidizing atmosphere in a temperature range of between 400° C. and 1,200° C.Type: ApplicationFiled: December 9, 2016Publication date: January 10, 2019Applicant: Forschungszentrum Juelich GmbHInventors: Juergen Dornseiffer, Hans-Gregor Gehrke, Manuel Krott, Olivier Guillon, Sven Uhlenbruck