Patents by Inventor Olivier Larcher

Olivier Larcher has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11897783
    Abstract: The present invention relates to a porous aluminum hydrate, to a process for preparing same and to the use of same as intermediate in the preparation of an alumina or of a mixed oxide based on aluminum, on cerium and on zirconium. The invention also relates to the alumina obtained from the aluminum hydrate.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: February 13, 2024
    Assignee: RHODIA OPERATIONS
    Inventors: Julien Hernandez, Olivier Larcher
  • Patent number: 11198616
    Abstract: Zirconium and yttrium oxide-based composition with a specific surface area of at least 12 m 2/g following calcination at 1000° C. for 10 hours. This composition is obtained via a method wherein a mixture of zirconium and yttrium compounds is precipitated with a base; the resulting precipitate-containing medium is heated; a compound selected from anionic surfactants, non-ionic surfactants, polyethylene glycols, carboxylic acids and the salts thereof and carboxymethylated fatty alcohol ethoxylate-type surfactants is then added to said precipitate, and, finally, the precipitate is calcined. Said composition can be used as a catalyst.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: December 14, 2021
    Assignee: RHODIA CHIMIE
    Inventors: Olivier Larcher, Emmanuel Rohart
  • Patent number: 11154840
    Abstract: The present teachings are directed to inorganic oxide materials that include Al2O3, CeO2, and at least one of MgO and Pr6O11. The present teachings are also directed to catalysts having at least one noble metal supported on these inorganic oxide materials, as well as methods for treating exhaust gases from internal combustion engines using such catalysts.
    Type: Grant
    Filed: December 23, 2014
    Date of Patent: October 26, 2021
    Assignee: RHODIA OPERATIONS
    Inventors: Qiang Zhao, Olivier Larcher, Barry W. L. Southward, Francis Francis, Thomas English, Fabien Ocampo
  • Publication number: 20210070623
    Abstract: The present invention relates to a porous aluminum hydrate, to a process for preparing same and to the use of same as intermediate in the preparation of an alumina or of a mixed oxide based on aluminum, on cerium and on zirconium. The invention also relates to the alumina obtained from the aluminum hydrate.
    Type: Application
    Filed: December 18, 2018
    Publication date: March 11, 2021
    Inventors: Julien HERNANDEZ, Olivier LARCHER
  • Patent number: 10384954
    Abstract: A composition including cerium and zirconium oxides, including at least 30 wt.-% cerium oxide is desired. Following calcination at a temperature of 900 DEG C. for 4 hours, the composition has two populations of pores, the diameters of the first population being centered around a value of between 5 nm and 15 nm for a composition including 30% to 65% cerium oxide or between 10 nm and 20 nm for more than 65% cerium oxide and the diameter of the second population being centered around a value of between 45 nm and 65 nm for 30% to 65% cerium oxide or between 60 nm and 100 nm for more than 65% cerium oxide.
    Type: Grant
    Filed: July 2, 2010
    Date of Patent: August 20, 2019
    Assignee: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Olivier Larcher
  • Patent number: 10350578
    Abstract: The invention relates to a composition containing zirconium, cerium and yttrium oxides with a cerium oxide proportion of between 3% and 15%, and yttrium oxide proportions corresponding to the following conditions: 6% at most if the cerium oxide proportion is between 12% excluded and 15% included; 10% at most if the cerium oxide proportion is between 7% excluded and 12% included; 30% at most if the cerium oxide proportion is between 3% and 7% included; the balance consisting of zirconium oxide. The composition may optionally include an oxide of a rare earth selected from lanthanum, neodymium and praseodymium. The composition can be used for processing the exhaust gases of a vehicle.
    Type: Grant
    Filed: November 21, 2014
    Date of Patent: July 16, 2019
    Assignee: RHODIA OPERATIONS
    Inventors: Olivier Larcher, Emmanuel Rohart, Simon Ifrah
  • Patent number: 10189010
    Abstract: A composition of zirconium oxide and at least one oxide of a rare earth other than cerium is described. The zirconium oxide has a weight proportion of at least 50% and, after calcination at a temperature of 900° C. for 4 hours, the composition exhibits two populations of pores of which their respective diameters are centered. The diameter of the first pore has a value of from 20 nm to 40 nm and in the second pore has a value of from 80 nm to 200 nm. Further described is how the composition can be used for treating the exhaust gases of internal combustion engines.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: January 29, 2019
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Olivier Larcher
  • Patent number: 9901915
    Abstract: The composition according to the invention includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, characterized in that after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The composition according to the invention can be used in the field of catalysis.
    Type: Grant
    Filed: February 4, 2015
    Date of Patent: February 27, 2018
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Olivier Larcher, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
  • Patent number: 9731286
    Abstract: The present invention is directed to a high surface area, high pore volume porous alumina, comprising: aluminum oxide, optionally, silicon oxide and aluminosilicates, and optionally one or more dopants, said alumina having a specific surface area of from about 100 to about 500 square meters per gram and a total pore volume after calcination at 900° C. for 2 hours of greater than or equal to 1.2 cubic centimeters per gram, wherein less than or equal to 15% of the total pore volume is contributed by pores having a diameter of less than 10 nm.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: August 15, 2017
    Assignee: Rhodia Operations
    Inventors: Andrew Polli, Francis Francis, Thomas English, Naotaka Ohtake, Olivier Larcher
  • Patent number: 9592498
    Abstract: A porous inorganic composite oxide containing oxides of aluminum and of cerium and/or zirconium, and, optionally, oxides of one or more dopants selected from transition metals, rare earths, and mixtures thereof, and having a specific surface area, in m2/g, after calcining at 1100° C. for 5 hours, of ?0.8235[Al]+11.157 and a total pore volume, in cm3/g, after calcining at 900° C. for 2 hours, of ?0.0097[Al]+0.0647, wherein [Al] is the amount of oxides of aluminum, expressed as pbw Al2O3 per 100 pbw of the composite oxide; a catalyst containing one or more noble metals dispersed on the porous inorganic composite oxide; and a method for making the porous inorganic composite oxide.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: March 14, 2017
    Assignee: Rhodia Operations
    Inventors: Olivier Larcher, Francis Francis, Thomas English, Simon Ifrah, Andrew Polli
  • Publication number: 20170001172
    Abstract: The present teachings are directed to inorganic oxide materials that include Al2O3, CeO2, and at least one of MgO and Pr6O11. The present teachings are also directed to catalysts having at least one noble metal supported on these inorganic oxide materials, as well as methods for treating exhaust gases from internal combustion engines using such catalysts.
    Type: Application
    Filed: December 23, 2014
    Publication date: January 5, 2017
    Applicant: RHODA OPERATIONS
    Inventors: Qiang ZHAO, Olivier LARCHER, Barry W. L. SOUTHWARD, Francis FRANCIS, Thomas ENGLISH, Fabien OCAMPO
  • Publication number: 20160166988
    Abstract: Compositions useful for treating the exhaust gases of diesel engines contain zirconium oxide, silicon oxide and at least one oxide of at least one element M selected from among titanium, aluminum, tungsten, molybdenum, cerium, iron, tin, zinc, and manganese, in the following mass proportions of these different elements: silicon oxide: 5%-30%; M-element oxide: 1%-20%; the balance being zirconium oxide; such compositions also have an acidity, as measured by the methylbutynol test, of at least 90% and are prepared by placing a zirconium compound, a silicon compound, at least one M-element compound and a basic compound in a liquid medium, thereby generating a precipitate, maturing the precipitate in a liquid medium and separating and calcining the precipitate.
    Type: Application
    Filed: December 15, 2015
    Publication date: June 16, 2016
    Inventors: Olivier LARCHER, Emmanuel ROHART, Stephan VERDIER, Heather BRADSHAW, Clive BUTLER, Deborah HARRIS, Mairead FEELEY, Guillaume CRINIERE
  • Patent number: 9181104
    Abstract: The composition is based on zirconium oxide and at least one additive selected from zirconium oxide and at least one additive chosen from praseodymium, lanthanum or neodymium oxides, has a specific surface of at least 29 m 2/g after calcination at 1000° C. during a period of 10 hours and is obtained by a method wherein a mixture of zirconium compounds and additive is precipitated with a base; the medium thus obtained, containing a precipitate, is heated and a compound chosen from anionic surfactants, non-ionic surfactants, polyethylene glycols, carboxylic acids and the salts thereof and surfactants such as the ethoxylates of caroboxymethyl fatty alcohols is added to the compound and the precipitate is calcinated; the composition can be used as a catalyst.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: November 10, 2015
    Assignee: Rhodia Chimie
    Inventors: Olivier Larcher, Philippe Moissonnier, Emmanuel Rohart
  • Publication number: 20150202596
    Abstract: The invention relates to a composition containing zirconium, cerium and yttrium oxides with a cerium oxide proportion of between 3% and 15%, and yttrium oxide proportions corresponding to the following conditions: 6% at most if the cerium oxide proportion is between 12% excluded and 15% included; 10% at most if the cerium oxide proportion is between 7% excluded and 12% included; 30% at most if the cerium oxide proportion is between 3% and 7% included; the balance consisting of zirconium oxide. The composition may optionally include an oxide of a rare earth selected from lanthanum, neodymium and praseodymium. The composition can be used for processing the exhaust gases of a vehicle.
    Type: Application
    Filed: November 21, 2014
    Publication date: July 23, 2015
    Inventors: Olivier LARCHER, Emmanuel ROHART, Simon IFRAH
  • Publication number: 20150148219
    Abstract: The composition according to the invention includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, characterized in that after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The composition according to the invention can be used in the field of catalysis.
    Type: Application
    Filed: February 4, 2015
    Publication date: May 28, 2015
    Inventors: Simon IFRAH, Olivier LARCHER, Rui JORGE COELHO MARQUES, Michael LALLEMAND, Julien HERNANDEZ
  • Patent number: 8974764
    Abstract: A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminum or manganese, in the form of particles dispersed on an alumina or aluminum oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.
    Type: Grant
    Filed: February 25, 2010
    Date of Patent: March 10, 2015
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Olivier Larcher, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
  • Patent number: 8956994
    Abstract: A composition is described that includes zirconium oxide, cerium oxide and yttrium oxide, or zirconium oxide, cerium oxide and at least two oxides of two rare earths different from cerium in a mass proportion of at least 20% of zirconium oxide and of at most 70% of cerium oxide, wherein the composition further includes, after calcination at 900° C. for 4 hours, two populations of pores having respective diameters centered, for the first population, about a value of 20 nm to 40 nm and, for the second, about a value of 80 nm to 200 nm. The composition can be used for processing exhaust gases of internal combustion engines.
    Type: Grant
    Filed: May 2, 2011
    Date of Patent: February 17, 2015
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Olivier Larcher
  • Patent number: 8728435
    Abstract: Catalyst/catalyst support composition essentially consist of oxides of zirconium, cerium and lanthanum and of another rare earth selected from among yttrium, gadolinium and samarium, having a proportion of the lanthanum oxide and the oxide of the other rare earth of at least 15% and specific surfaces of at least 40 m2/g and at least 15 m2/g after calcination respectively for 4 hours at 1,000° C. and 10 hours at 1,150° C.; after calcination for 10 hours at 1,200° C. these have a surface of at least 7 m2/g and such surface is at least 5 m2/g for an embodiment in which after 10 hours of calcination at 1,150° C. the composition is in the form of a pure solid solution.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: May 20, 2014
    Assignee: Rhodia Operations
    Inventors: Olivier Larcher, Emmanuel Rohart, Stephan Verdier
  • Publication number: 20140072492
    Abstract: A composition of zirconium oxide and at least one oxide of a rare earth other than cerium is described. The zirconium oxide has a weight proportion of at least 50% and, after calcination at a temperature of 900° C. for 4 hours, the composition exhibits two populations of pores of which their respective diameters are centered. The diameter of the first pore has a value of from 20 nm to 40 nm and in the second pore has a value of from 80 nm to 200 nm. Further described is how the composition can be used for treating the exhaust gases of internal combustion engines.
    Type: Application
    Filed: November 21, 2011
    Publication date: March 13, 2014
    Applicant: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Olivier Larcher
  • Patent number: 8460626
    Abstract: The inventive composition, according to a first embodiment, consists essentially of a cerium oxide and a zirconium oxide in an atomic ratio Ce/Zr of at least 1. According to a second embodiment, said composition is based on cerium oxide, zirconium oxide with an atomic ratio Ce/Zr of at least 1 and at least one rare earth oxide other than cerium. After calcination at 1100° C., said composition has a specific surface of at least 9 m2/g in the second embodiment. The inventive composition can be used as a catalyst especially for the treatment of waste gases from internal combustion engines.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: June 11, 2013
    Assignee: Rhodia Electronics and Catalysis
    Inventors: Olivier Larcher, Emmanuel Rohart