Abstract: An integrated, modular system for direct air capture (DAC) and electro-microbial production (EMP) for bioelectrochemical conversion of CO2 comprises (a) a solid absorbent configured to directly capture CO2 from air; (b) a first bioreactor configured to receive enriched and purified CO2 from the absorbent and convert the CO2 to an upgradeable organic carbon intermediate by an autotrophic microorganism, wherein the autotrophic organism derives energy from oxidation of electrochemically-generated reducing equivalents; and (c) a second bioreactor configured to receive the organic carbon intermediate from the first bioreactor for use as a feedstock by a metabolically engineered microorganism to generate a value added product.

Abstract: The disclosure provides for zirconium terephthalate-based metal organic frameworks with open metal sites, and uses thereof.

Abstract: A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C5H2O4N2)(H2O)].

Abstract: Atmospheric moisture harvester systems include two beds with water capture material, such as metal-organic framework (MOF), a heater, two fans, and a condenser having two sides, operatively configured into adsorption and desorption modes, wherein the MOF beds are interchangeable to cycle between the desorption and water adsorption modes. The systems may further include a photovoltaic panel powering the fans and condenser.

Abstract: Chemically and thermally stable covalent organic framework (COF) materials are configured and operative as solid adsorbents for capturing gases and water.

Abstract: Provided are compositions that include a metal-organic framework (MOF) including a framework defining an internal volume, an enzyme disposed within the internal volume, and a surfactant. Also provided are methods of making the compositions and their use.

Abstract: Coordinative alignment uses x-ray diffraction to precisely and unambiguously determine the structure of molecules bound or crystallized within chiral metal organic frameworks.

Abstract: Atmospheric water harvesting systems utilize a sorbent cartridge configured to hold water capture material. The sorbent cartridge is made up of a plurality of permeable trays and a plurality of spacers that are arranged to provide cross-flow for adsorption and desorption airflow pathways. The systems are used for harvesting water from surrounding air.

Abstract: A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C5H2O4N2)(H2O)].

Abstract: Compositions comprising multivariate metal-organic frameworks and other single-linker metal-organic frameworks are used for containing and storing a gas or fluid or for water harvesting or water purification applications.

Abstract: Provided herein are atmospheric moisture harvester systems, as well as methods using such systems, for capturing water from surrounding air. The systems and methods use adsorbents to adsorb water from the air. For example, the adsorbents may be metal-organic frameworks. The systems and methods desorb this water in the form of water vapor, and the water vapor is condensed into liquid water and collected. The liquid water is suitable for use as drinking water.

Abstract: Atmospheric moisture harvester systems include two beds with water capture material, such as metal-organic framework (MOF), a heater, two fans, and a condenser having two sides, operatively configured into adsorption and desorption modes, wherein the MOF beds are interchangeable to cycle between the desorption and water adsorption modes. The systems may further include a photovoltaic panel powering the fans and condenser.

Abstract: A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C5H2O4N2)(H2O)].

Abstract: Provided herein are atmospheric moisture harvester systems, as well as methods using such systems, for capturing water from surrounding air. The systems and methods use adsorbents to adsorb water from the air. For example, the adsorbents may be metal-organic frameworks. The systems and methods desorb this water in the form of water vapor, and the water vapor is condensed into liquid water and collected. The liquid water is suitable for use as drinking water.

Abstract: Coordinative alignment uses x-ray diffraction to precisely and unambiguously determine the structure of molecules bound or crystallized within chiral metal organic frameworks.

Abstract: The disclosure provides for zirconium terephthalate-based metal organic frameworks with open metal sites, and uses thereof.

Abstract: The disclosure provides for multivariant zeolitic imidazolate frameworks (ZIFs), methods of making thereof, and methods of use therefrom.

Abstract: Porous calcium lactate metal-organic frameworks (MOFs) comprise non-toxic metal ions—Ca(II) and non-toxic, renewable and cheap linkers—lactate and acetate. The MOFs are nontoxic and environmentally-benign, and can be used as degradable carriers.

Abstract: Coordinative alignment uses x-ray diffraction to precisely and unambiguously determine the structure of molecules bound or crystallized within chiral metal organic frameworks.

Abstract: A water-harvesting system can operate with a material that can take up and release water with minimum energy requirements and powered by low-grade energy sources, such as sunlight, in order to potentially allow its deployment into households, especially those located in sunny regions. A water-harvesting method and system can include vapor adsorption using a porous metal-organic framework. In certain embodiments, the porous metal-organic framework can include metal-organic framework in ambient air with low relative humidity, typical of the levels found in most dry regions of the world.