Abstract: Heavy polycyclic aromatic hydrocarbons (HPAHs) are analyzed using aromatic-selective size exclusion chromatography for the separation and quantitation of HPAHs. This method is suitable to determine the concentration of HPAHs in mixtures that include coronene and other HPAHs including 8 or more rings, such as contained in hydrocracker bottoms, or in pyrolysis oil or tar.

Abstract: The present disclosure is directed to a method of manufacture of zeolite. A sol-gel formulation includes a water-soluble fraction of ODSO as an additional component. The resulting products include zeolite with increased SAR relative to comparable sol-gel formulations without ODSO as a precursor. In addition, the SAR is increased by increasing the ODSO content during synthesis. In additional embodiments, zeolite yield is also increased.

Abstract: Modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm, wherein the microporous framework includes at least silicon atoms and oxygen atoms; a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite also includes: isolated terminal primary amine functionalities bonded to silicon atoms of the microporous framework; or silazane functionalities, wherein the nitrogen atom of the silazane bridges two silicon atoms of the microporous framework; or both.

Abstract: The present disclosure relates to methods for petrochemical production integrating a slurry phase hydrocracking process and an inline hydrotreating process. A slurry-phase hydrocracking feed comprising residue stream and/or a deasphalted residue stream is processed in a slurry-phase hydrocracking reaction zone to produce slurry-phase hydrocracking effluents. A first stream of slurry-phase hydrocracking effluents is discharged including unreacted hydrogen and which is under hydrogen partial pressure. The slurry-phase hydrocracking effluents are processed in an inline hydrotreating zone for hydrodesulfurization and/or hydrodenitrogenation to produce a hydrotreated effluent. Downstream FCC and petrochemicals production complex units are used to produce light olefins and aromatic products.

Abstract: Systems and methods are disclosed for providing virtual assays of an oil sample such as crude oil based on time of flight mass spectroscopy (TOF-MS) carried out on the oil sample, and the density of the oil sample. The virtual assay provides a full range of information about fractions of the oil sample including naphtha, gas oil, vacuum gas oil, vacuum residue, and other information about the properties of the oil sample. Using the system and method herein, the virtual assay data pertaining to these several fractions of the oil sample and the oil sample itself are obtained without fractionation of the oil sample into the several components.

Abstract: Systems and methods are disclosed for providing virtual assays of an oil sample such as crude oil based on gel permeation chromatography (GPC) carried out on the oil sample or a solution of the oil sample in a GPC solvent, and the density of the oil sample. The virtual assay provides a full range of information about fractions of the oil sample including naphtha, gas oil, vacuum gas oil, vacuum residue, and other information about the properties of the oil sample. Using the system and method herein, the virtual assay data pertaining to these several fractions of the oil sample and the oil sample itself are obtained without fractionation of the oil sample into the several components.

Abstract: Systems and methods are disclosed for providing virtual assays of an oil sample such as crude oil based on Fourier transform ion cyclotron resonance (FT-ICR) mass spectroscopy carried out on the oil sample, and the density of the oil sample. The virtual assay provides a full range of information about fractions of the oil sample including naphtha, gas oil, vacuum gas oil, vacuum residue, and other information about the properties of the oil sample. Using the system and method herein, the virtual assay data pertaining to these several fractions of the oil sample and the oil sample itself are obtained without fractionation of the oil sample into the several components.

Abstract: Methods for processing a hydrocarbon feedstock may include cracking at least a portion of the hydrocarbon feedstock by contacting the hydrocarbon feedstock with a modified zeolite in the presence of hydrogen to form an intermediate cracked product and steam cracking at least a portion of the intermediate cracked product to form a steam cracked product. The intermediate cracked product may include at least 30 wt. % of one or more linear alkanes. The modified zeolite may include a microporous framework. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite also includes a plurality of Group 4-6 metal atoms each bonded to four bridging oxygen atoms, wherein each of the bridging oxygen atoms bonded to the Group 4-6 metal atoms bridges one of the plurality of the Group 4-6 metal atoms and a silicon atom of the microporous framework.

Abstract: Modified zeolites may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite may include a plurality of titanium atoms each bonded to four bridging oxygen atoms, wherein each of the bridging oxygen atoms bonded to the titanium atoms bridges one of the plurality of the titanium atoms and a silicon atom of the microporous framework.

Abstract: A functionalized fibrous hierarchical zeolite includes a framework comprising aluminum atoms, silicon atoms, and oxygen atoms, the framework further comprising a plurality of micropores and a plurality of mesopores. The functionalized fibrous hierarchical zeolite is functionalized with at least one amine. A plurality of nanoparticles comprising platinum are immobilized on the framework.

Abstract: A functionalized fibrous hierarchical zeolite includes a framework comprising aluminum atoms, silicon atoms, and oxygen atoms, the framework further comprising a plurality of micropores and a plurality of mesopores. The functionalized fibrous hierarchical zeolite is functionalized with at least one terminal amine bonded to a silicon atom. Terminal organometallic functionalities are bonded to a nitrogen atom of the at least one terminal amine, the terminal organometallic functionalities comprising a platinum atom.

Abstract: A functionalized fibrous hierarchical zeolite includes a framework comprising aluminum atoms, silicon atoms, and oxygen atoms, the framework further comprising a plurality of micropores and a plurality of mesopores. The functionalized fibrous hierarchical zeolite is functionalized with at least one amine. A plurality of nanoparticles comprising nickel are immobilized on the framework.

Abstract: A method and a system for predicting a molecular weight of a hydrocarbon fluid are provided. An exemplary method includes measuring a density of the hydrocarbon fluid, obtaining an alternative measurement of a physical property of the hydrocarbon fluid, calculating an index value for the hydrocarbon fluid from the alternative measurement, and calculating a predicted molecular weight using an equation that combines the density with the index value. The predicted molecular weight is provided as an output.

Abstract: Modified zeolites may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite may include a plurality of titanium hydride moieties each bonded to at least two bridging oxygen atoms, wherein a titanium atom of the titanium hydride is bonded to the bridging oxygen atom, and wherein the bridging oxygen atom bridges the titanium atom of the titanium hydride moiety and a silicon atom of the microporous framework.

Abstract: Modified zeolites may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite may include a plurality of zirconium hydride moieties each bonded to at least two bridging oxygen atoms, wherein a zirconium atom of the zirconium hydride is bonded to the bridging oxygen atom, and wherein the bridging oxygen atom bridges the zirconium atom of the zirconium hydride moiety and a silicon atom of the microporous framework.

Abstract: An integrated catalyst/adsorbent manufacturing process. The process includes generating electrical energy from a green energy source and providing the electrical energy to operate an electrolyzer, a steam generation unit, and a catalyst/adsorbent manufacturing unit. The electrolyzer operates to generate a hydrogen stream and an oxygen stream from electrolysis of a first stream of water and the steam generation unit operates by burning the hydrogen in the steam generation unit to generate heat to convert a second stream of water into steam. The catalyst/adsorbent manufacturing unit operates to produce the catalyst/adsorbent from the electrical energy, the steam, the hydrogen, the oxygen, and catalyst/adsorbent precursor chemicals provided to the catalyst/adsorbent manufacturing unit.

Abstract: A method of loading a catalyst includes providing a catalyst loading apparatus including an optically transparent tube, a metal tube and a horizontal divider, coating the interior surface of the optically transparent tube, the metal tube, or both with a first wax; adding a first inert material to the optically transparent tube, to form a first layer including the first inert material; adding a catalyst into the optically transparent tube, to form a second layer including the catalyst disposed above the first layer; adding a second inert material to the optically transparent tube at least until substantially no void space is observed in the second layer, the second inert material having a lesser diameter than the first inert material and the catalyst; actuating a gate of the horizontal divider into the opened position; and displacing the first and second layers into the metal tube.

Abstract: Described herein are zeolite Beta particles with radially arranged mesopores and methods of making the same. In one or more embodiments, a zeolite Beta particle may include a Beta zeolitic framework including a plurality of micropores having diameters of less than or equal to 2 nm. In embodiments, the Beta zeolitic framework may include alumina and silica. In embodiments, the zeolite Beta particles disclosed herein may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. In embodiments, the plurality of mesopores may be arranged in a center-radial configuration, such that mesopores run from a central region of the zeolite Beta particle towards the edge of the zeolite Beta particle.

Abstract: A method of loading a catalyst includes providing a catalyst loading apparatus having an optically transparent tube removably coupled to a metal tube and a horizontal divider having a shaft coupled to a plate, the horizontal divider positioned within the optically transparent tube, the metal tube or at least partially within both. The method also includes adding a first inert material to the optically transparent tube, adding a catalyst into the optically transparent tube, adding a second inert material to the optically transparent tube, inserting a distal end of a leveling device having a shaft and a disc into the catalyst loading apparatus from the top surface of the optically transparent tube, contacting the disc of the leveling device against the second layer comprising the catalyst; and displacing at least the horizontal divider into the metal tube.

Abstract: Modified zeolites may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite may include a plurality of hafnium hydride moieties each bonded to at least two bridging oxygen atoms, wherein a hafnium atom of the hafnium hydride is bonded to the bridging oxygen atom, and wherein the bridging oxygen atom bridges the hafnium atom of the hafnium hydride moiety and a silicon atom of the microporous framework.