Abstract: Methods, systems, and apparatuses for mitigating battery defects are provided. In some embodiments, a method comprises: monitoring one or more battery parameters associated with a rechargeable battery; obtaining a rate of change of at least one battery parameter of the one or more battery parameters; and determining a defect status of the rechargeable battery based at least in part on the rate of change of the at least one battery parameter.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 60 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting of LiCoO2, LiMn2O4, Li(M1x1M2x2Co1-x1-x2)O2 where M1 and M2 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1?0.5 and 0?x2?0.5, or alternatively, LiM1(1-x)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 60 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting of LiCoO2, LiMn2O4, Li(M1x1M2x2Co1-x1-x2)O2 where M1 and M2 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1?0.5 and 0?x2?0.5, or alternatively, LiM1(1-x)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 60 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting of LiCoO2, LiMn2O4, Li(M1x1M2x2Co1-x1-x2)O2 where M1 and M2 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1?0.5 and 0?x2?0.5, or alternatively, LiM1(1-x)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 60 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting of LiCoO2, LiMn2O4, Li(M1x1M2x2Co1-x1-x2)O2 where M1 and M2 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1?0.5 and 0?x2?0.5, or alternatively, LiM1(1-x)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: Loss of flow battery electrode catalyst layers during self-discharge or charge reversal may be prevented by establishing and maintaining a negative electrolyte imbalance during at least parts of a flow battery's operation. Negative imbalance may be established and/or maintained actively, passively or both. Actively establishing a negative imbalance may involve detecting an imbalance that is less negative than a desired threshold, and processing one or both electrolytes until the imbalance reaches a desired negative level. Negative imbalance may be effectively established and maintained passively within a cell by constructing a cell with a negative electrode chamber that is larger than the cell's positive electrode chamber, thereby providing a larger quantity of negative electrolyte for reaction with positive electrolyte.

Abstract: Loss of flow battery electrode catalyst layers during self-discharge or charge reversal may be prevented by establishing and maintaining a negative electrolyte imbalance during at least parts of a flow battery's operation. Negative imbalance may be established and/or maintained actively, passively or both. Actively establishing a negative imbalance may involve detecting an imbalance that is less negative than a desired threshold, and processing one or both electrolytes until the imbalance reaches a desired negative level. Negative imbalance may be effectively established and maintained passively within a cell by constructing a cell with a negative electrode chamber that is larger than the cell's positive electrode chamber, thereby providing a larger quantity of negative electrolyte for reaction with positive electrolyte.

Abstract: Loss of flow battery electrode catalyst layers during self-discharge or charge reversal may be prevented by establishing and maintaining a negative electrolyte imbalance during at least parts of a flow battery's operation. Negative imbalance may be established and/or maintained actively, passively or both. Actively establishing a negative imbalance may involve detecting an imbalance that is less negative than a desired threshold, and processing one or both electrolytes until the imbalance reaches a desired negative level. Negative imbalance may be effectively established and maintained passively within a cell by constructing a cell with a negative electrode chamber that is larger than the cell's positive electrode chamber, thereby providing a larger quantity of negative electrolyte for reaction with positive electrolyte.

Abstract: Methods for forming a cathode active material comprise sintering flakes formed from a nickel, manganese, cobalt and lithium-containing slurry to form the cathode material having the formula Li2Ni1?x?yMnxCoyO2, wherein ‘x’ is a number between about 0 and 1, ‘y’ is a number between about 0 and 1, and ‘z’ is a number greater than or equal to about 0.8 and less than 1. Lithium-ion batteries having cathode active materials formed according to methods of embodiments of the invention are provided.

Abstract: Systems and methods for configuring tabs on a rechargeable battery may include a current collector comprising one or more collector foil and one or more tabs connected to the collector foil for conveying generated current from the current collector. The tabs may be configured to extract greater capacity from the battery electrodes so that the resulting battery may exhibit higher performance. The tabs may be configured so that the length of the tab is greater than the height of the collector foil so the tab may cover the height of the collector foil and may protrude from the foil.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 100 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting Of LiCoO2, LiMn2O4, Li(M1x1M2x2M3x3CO1-X1-X2)O2 where M1, M2 and M3 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1<0.9, 0<x2<0.5 and 0<x3<0.5, or alternatively, LiM1(1-X)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: Positive electrodes for secondary batteries formed with a plurality of substantially aligned flakes within a coating. The flakes can be formed from metal oxide materials and have a number average longest dimension of greater than 60 ?m. A variety of metal oxide or metal phosphate materials may be selected such as a group consisting of LiCoO2, LiMn2O4, Li(M1x1M2x2Co1-x1-x2)O2 where M1 and M2 are selected from among Li, Ni, Mn, Cr, Ti, Mg, or Al, 0?x1?0.5 and 0?x2?0.5, or alternatively, LiM1(1-x)MnxO2 where 0<x<0.8 and M1 represents one or more metal elements. Methods for making positive electrode materials are also provided involving the formation of structures with a desired longest dimension, preferably polycrystalline flakes. A cathode coating containing polycrystalline flakes may be deposited onto a conductive substrate and pressed to a desired final electrode thickness.

Abstract: Systems and methods for configuring tabs on a rechargeable battery may include a current collector comprising one or more collector foil and one or more tabs connected to the collector foil for conveying generated current from the current collector. The tabs may be configured to extract greater capacity from the battery electrodes so that the resulting battery may exhibit higher performance. The tabs may be configured so that the length of the tab is greater than the height of the collector foil so the tab may cover the height of the collector foil and may protrude from the foil.