Abstract: Sensing systems include a tube defining a Fabry-Perot cavity and an optical fiber including a distal end disposed within the Fabry-Perot cavity and a proximal end. A corrodible material caps the Fabry-Perot cavity. Devices for sensing corrosion of downhole equipment include an optical fiber with a corrodible material disposed over a distal end of the optical fiber. Systems for sensing a condition in equipment include an optical fiber with a fiber Bragg grating proximate a distal end thereof and a mass of sensor material coupled to the distal end of the optical fiber. The mass of sensor material is suspended from above the fiber Bragg grating. Other systems for sensing a condition in a wellbore include an optical fiber and a plurality of fiber Bragg gratings along a length thereof. A plurality of sensor materials are coupled to the optical fiber and surround respective fiber Bragg gratings.

Abstract: Sensing systems include a tube defining a Fabry-Perot cavity and an optical fiber including a distal end disposed within the Fabry-Perot cavity and a proximal end. A corrodible material caps the Fabry-Perot cavity. Devices for sensing corrosion of downhole equipment include an optical fiber with a corrodible material disposed over a distal end of the optical fiber. Systems for sensing a condition in equipment include an optical fiber with a fiber Bragg grating proximate a distal end thereof and a mass of sensor material coupled to the distal end of the optical fiber. The mass of sensor material is suspended from above the fiber Bragg grating. Other systems for sensing a condition in a wellbore include an optical fiber and a plurality of fiber Bragg gratings along a length thereof. A plurality of sensor materials are coupled to the optical fiber and surround respective fiber Bragg gratings.

Abstract: Sensing systems include a tube defining a Fabry-Perot cavity and an optical fiber including a distal end disposed within the Fabry-Perot cavity and a proximal end. A corrodible material caps the Fabry-Perot cavity. Devices for sensing corrosion of downhole equipment include an optical fiber with a corrodible material disposed over a distal end of the optical fiber. Systems for sensing a condition in equipment include an optical fiber with a fiber Bragg grating proximate a distal end thereof and a mass of sensor material coupled to the distal end of the optical fiber. The mass of sensor material is suspended from above the fiber Bragg grating. Other systems for sensing a condition in a wellbore include an optical fiber and a plurality of fiber Bragg gratings along a length thereof. A plurality of sensor materials are coupled to the optical fiber and surround respective fiber Bragg gratings.

Abstract: A method of coating a substrate includes dispersing functionalized diamond nanoparticles in a fluid comprising metal ions to form a deposition composition; disposing a portion of the deposition composition over at least a portion of a substrate; and electrochemically depositing a coating over the substrate. The coating comprises the diamond nanoparticles and a metal formed by reduction of the metal ions in the deposition composition.

Abstract: A Polycrystalline Diamond Compact (PDC) cutter for a rotary drill bit is provided with an integrated sensor and circuitry for making measurements of a property of a fluid in the borehole and/or an operating condition of the drill bit. A method of manufacture of the PDC cutter and the rotary drill bit is discussed.

Abstract: Sensing systems include a tube defining a Fabry-Perot cavity and an optical fiber including a distal end disposed within the Fabry-Perot cavity and a proximal end. A corrodible material caps the Fabry-Perot cavity. Devices for sensing corrosion of downhole equipment include an optical fiber with a corrodible material disposed over a distal end of the optical fiber. Systems for sensing a condition in equipment include an optical fiber with a fiber Bragg grating proximate a distal end thereof and a mass of sensor material coupled to the distal end of the optical fiber. The mass of sensor material is suspended from above the fiber Bragg grating. Other systems for sensing a condition in a wellbore include an optical fiber and a plurality of fiber Bragg gratings along a length thereof. A plurality of sensor materials are coupled to the optical fiber and surround respective fiber Bragg gratings.

Abstract: Devices and methods for detecting chemicals are disclosed. A device configured for use in a wellbore includes a sensor including a quantum tunneling composite (QTC) material configured to exhibit a change in electrical resistance responsive to the sensor contacting a target chemical. The sensor includes electrical resistance measuring circuitry operably coupled to the QTC material and configured to measure the electrical resistance of the QTC material and output a sensor signal indicating the electrical resistance. A method comprises deploying the sensor into the wellbore, measuring the electrical resistance of the QTC material, and determining the presence of the target chemical responsive to detecting changes in the electrical resistance of the QTC material. Another method includes selecting at least one of the QTC material and an active material to interact with a target wellbore chemical to change the electrical resistance of the QTC material.

Abstract: Sensing systems include a tube defining a Fabry-Perot cavity and an optical fiber including a distal end disposed within the Fabry-Perot cavity and a proximal end. A corrodible material caps the Fabry-Perot cavity. Devices for sensing corrosion of downhole equipment include an optical fiber with a corrodible material disposed over a distal end of the optical fiber. Systems for sensing a condition in equipment include an optical fiber with a fiber Bragg grating proximate a distal end thereof and a mass of sensor material coupled to the distal end of the optical fiber. The mass of sensor material is suspended from above the fiber Bragg grating. Other systems for sensing a condition in a wellbore include an optical fiber and a plurality of fiber Bragg gratings along a length thereof. A plurality of sensor materials are coupled to the optical fiber and surround respective fiber Bragg gratings.

Abstract: In a composition including a plurality of coated diamond nanoparticles, each diamond nanoparticle may have at least one silane functional group covalently bonded to a surface thereof. A method of forming coated diamond nanoparticles may include functionalizing surfaces of diamond nanoparticles with at least one of a fluorine-containing compound and an oxidant; dispersing the functionalized diamond nanoparticles in a solvent comprising a silane functional group; and forming covalent bonds between the silane functional group and the diamond nanoparticles. A method of forming a diamond coating may include depositing the diamond nanoparticles over a substrate.

Abstract: Methods of determining a pH of a wellbore fluid within a wellbore in communication with a subterranean formation comprise introducing carbon quantum dots into a wellbore fluid, exposing the wellbore fluid to radiation from an electromagnetic radiation source, and measuring at least one fluorescence property of the carbon quantum dots within the wellbore fluid to determine a pH of the wellbore fluid. Related methods of determining a pH of a fluid within a wellbore extending through a subterranean formation are also disclosed.

Abstract: A method of detecting at least one of an analyte or a condition of a fluid within a subterranean formation includes operably coupling a radiation source to at least one optical fiber coupled to a sensor having optically sensitive materials including at least one of chromophores, fluorophores, metal nanoparticles, or metal oxide nanoparticles dispersed within an optically transparent permeable matrix material. The sensor is contacted within a wellbore with a fluid and the fluid is passed through at least a portion of the sensor. Electromagnetic radiation is transmitted from the radiation source through at least one optical fiber to the sensor and at least one of an absorbance spectrum, an emission spectrum, a maximum absorption intensity, or a maximum emission intensity of electromagnetic radiation passing through the sensor after contacting at least some of the optically sensitive materials with the fluid is measured.

Abstract: Devices and methods for detecting chemicals are disclosed. A device configured for use in a wellbore includes a sensor including a quantum tunneling composite (QTC) material configured to exhibit a change in electrical resistance responsive to the sensor contacting a target chemical. The sensor includes electrical resistance measuring circuitry operably coupled to the QTC material and configured to measure the electrical resistance of the QTC material and output a sensor signal indicating the electrical resistance. A method comprises deploying the sensor into the wellbore, measuring the electrical resistance of the QTC material, and determining the presence of the target chemical responsive to detecting changes in the electrical resistance of the QTC material. Another method includes selecting at least one of the QTC material and an active material to interact with a target wellbore chemical to change the electrical resistance of the QTC material.

Abstract: A method of detecting an analyte includes vaporizing at least a portion of a fluid within a wellbore, passing the vaporized fluid adjacent a chemiresistive sensing element coupled to a drill string within the wellbore and sensing a resistivity of the chemiresistive sensing element. A sensor for detecting an analyte includes an expansion device for vaporizing a portion of a fluid within a wellbore, a chemiresistive sensing element configured to contact the vaporized fluid within the wellbore and a controller configured to pass a current through the chemiresistive sensing element and calculate a resistance of the chemiresistive sensing element in contact with the gaseous portion of the fluid. An earth-boring tool may include a bit body coupled to a drill string and the sensor.

Abstract: Devices and methods for detecting chemicals are disclosed. A device configured for use in a wellbore includes a sensor including a quantum tunneling composite (QTC) material configured to exhibit a change in electrical resistance responsive to the sensor contacting a target chemical. The sensor includes electrical resistance measuring circuitry operably coupled to the QTC material and configured to measure the electrical resistance of the QTC material and output a sensor signal indicating the electrical resistance. A method comprises deploying the sensor into the wellbore, measuring the electrical resistance of the QTC material, and determining the presence of the target chemical responsive to detecting changes in the electrical resistance of the QTC material. Another method includes selecting at least one of the QTC material and an active material to interact with a target wellbore chemical to change the electrical resistance of the QTC material.

Abstract: Methods of determining a pH of a wellbore fluid within a wellbore in communication with a subterranean formation comprise introducing carbon quantum dots into a wellbore fluid, exposing the wellbore fluid to radiation from an electromagnetic radiation source, and measuring at least one fluorescence property of the carbon quantum dots within the wellbore fluid to determine a pH of the wellbore fluid. Related methods of determining a pH of a fluid within a wellbore extending through a subterranean formation are also disclosed.

Abstract: A Polycrystalline Diamond Compact (PDC) cutter for a rotary drill bit is provided with an integrated sensor and circuitry for making measurements of a property of a fluid in the borehole and/or an operating condition of the drill bit. A method of manufacture of the PDC cutter and the rotary drill bit is discussed.

Abstract: A method of detecting at least one of an analyte or a condition of a fluid within a subterranean formation comprises operably coupling a radiation source to at least one optical fiber coupled to a sensor comprising optically sensitive materials including at least one of chromophores, fluorophores, metal nanoparticles, or metal oxide nanoparticles dispersed within an optically transparent permeable matrix material. The sensor is contacted within a wellbore with a fluid and the fluid is passed through at least a portion of the sensor. Electromagnetic radiation is transmitted from the radiation source through at least one optical fiber to the sensor and at least one of an absorbance spectrum, an emission spectrum, a maximum absorption intensity, or a maximum emission intensity of electromagnetic radiation passing through the sensor after contacting at least some of the optically sensitive materials with the fluid is measured.

Abstract: A system for determining at least one property of at least one fluid in at least one subterranean formation comprises a fluid delivery system configured and positioned to deliver a fluid into at least one of at least one subterranean formation and a wellbore extending through the at least one subterranean formation. The system comprises a radiation source within the wellbore, the radiation source configured to generate excitation radiation, carbon quantum dots disposed in the fluid, and a detector within the wellbore, the detector configured to measure at least one fluorescence property of the carbon quantum dots. Related methods of determining a property of a wellbore and methods of forming the carbon quantum dots are also disclosed.

Abstract: A method of reducing the presence of particles in a downhole environment, comprising contacting sediment particles contained in a downhole environment, with a composition comprising: a metallic composition, an inorganic oxide-based polymer, and a solvent; the contacting occurring in the presence of a fluid capable of decomposing the metallic composition.

Abstract: A method of detecting an analyte includes vaporizing at least a portion of a fluid within a wellbore, passing the vaporized fluid adjacent a chemiresistive sensing element coupled to a drill string within the wellbore and sensing a resistivity of the chemiresistive sensing element. A sensor for detecting an analyte includes an expansion device for vaporizing a portion of a fluid within a wellbore, a chemiresistive sensing element configured to contact the vaporized fluid within the wellbore and a controller configured to pass a current through the chemiresistive sensing element and calculate a resistance of the chemiresistive sensing element in contact with the gaseous portion of the fluid. An earth-boring tool may include a bit body coupled to a drill string and the sensor.