Abstract: The invention relates to a soft-magnetic powder coated with a silicon based coating, wherein the silicon based coating comprises at least one of the following fluorine containing compositions: a) a fluorine containing composition of formula (I) Si1-0,25aM1aO2-0,5bFb??(I) wherein a is in the range of 0.015 to 0.52, b is in the range of 0.015 to 0.52, M1 is H, K, Rb, Cs or NR14, wherein each R1 is independently selected from the group consisting of H, C1-6 alkyl, phenyl and benzyl; or b) a fluorine containing composition of formula (II) Si1-0,75cM2cO2-0,5dFd??(II) wherein c is in the range of 0.005 to 0.17, d is in the range of 0.015 to 0.52, M2 is B or Al; or c) a fluorine containing composition of formula (III) Si1-1,25ePeO2-0,5fFf??(III) wherein e is in the range of 0.003 to 0.10, f is in the range of 0.015 to 0.52. The invention further relates to a process of coating the soft-magnetic powder, the use of such soft-magnetic powder and an electronic component including such soft-magnetic powder.

Abstract: The invention relates to a soft-magnetic powder coated with a silicon based coating, wherein the silicon based coating comprises at least one of the following fluorine containing compositions: a) a fluorine containing composition of formula (I) Si1-0,25aM1aO2-0,5bFb??(I) wherein a is in the range of 0.015 to 0.52, b is in the range of 0.015 to 0.52, M1 is H, K, Rb, Cs or NR14, wherein each R1 is independently selected from the group consisting of H, C1-6 alkyl, phenyl and benzyl; or b) a fluorine containing composition of formula (II) Si1-0,75cM2cO2-0,5dFd??(II) wherein c is in the range of 0.005 to 0.17, d is in the range of 0.015 to 0.52, M2 is B or Al; or c) a fluorine containing composition of formula (III) Si1-1,25ePeO2-0,5fFf??(III) wherein e is in the range of 0.003 to 0.10, f is in the range of 0.015 to 0.52.

Abstract: Integrated process, in which pure carbonyl iron powder (CIP) is prepared by decomposition of pure iron pentacarbonyl (IPC) in a plant A, carbon monoxide (CO) liberated in the decomposition of the IPC is used in plant A for the preparation of further CIP from iron or is fed to an associated plant B for the preparation of synthesis gas or is fed to an associated plant C for the preparation of hydrocarbons from synthesis gas, and the CIP prepared in plant A is used as catalyst or catalyst component in an associated plant C for the preparation of hydrocarbons from synthesis gas from plant B.

Abstract: Integrated process, in which pure carbonyl iron powder (CIP) is prepared by decomposition of pure iron pentacarbonyl (IPC) in a plant A, carbon monoxide (CO) liberated in the decomposition of the IPC is used in plant A for the preparation of further CIP from iron or is fed to an associated plant B for the preparation of synthesis gas or is fed to an associated plant C for the preparation of hydrocarbons from synthesis gas, and the CIP prepared in plant A is used as catalyst or catalyst component in an associated plant C for the preparation of hydrocarbons from synthesis gas from plant B.

Abstract: Iron pentacarbonyl is prepared by reacting iron with carbon monoxide in suspension and in the presence of a mixture of alkali metal sulfide and sulfur as a catalyst.

Abstract: Iron pentacarbonyl is prepared by reacting iron with carbon monoxide in suspension and in the presence of a polysulfide of the general formula RSxR? as a catalyst, where R is an organic radical and x is a number from 2 to 8.

Abstract: Iron pentacarbonyl is prepared by reacting iron with carbon monoxide in suspension and in the presence of a polysulfide of the general formula RSxR? as a catalyst, where R is an organic radical and x is a number from 2 to 8.

Abstract: Iron pentacarbonyl is prepared by reacting iron with carbon monoxide in suspension and in the presence of a mixture of alkali metal sulfide and sulfur as a catalyst.

Abstract: Hydroxylamine solutions stabilized using tri(4-(2,3-dihydroxyphenyl)-4-oxabutyl)amine, tri(4-(2,3-dihydroxyphenyl)-4-keto-3-azabutyl)amine or salts thereof, and methods of stabilizing hydroxylamine solutions using these compounds.

Abstract: A process for working up hydroxylamine-containing solutions as obtained in particular in the electronics industry during the cleaning of electronic components is described. According to the invention, the hydroxylamine is stripped from the wastewater with steam. The products obtained are aqueous hydroxylamine and an aqueous solution of the amines. Both product streams can be purified in further process steps to give a saleable product.

Abstract: The present invention relates to a process for the preparation of high-purity, stabilized hydroxylamine solutions in which an aqueous hydroxylamine starting solution is treated with an anion exchanger which has been pre-loaded with a hydroxylamine stabilizer in order to remove anions.

Abstract: The present invention relates to a process for the preparation of an aqueous hydroxylamine solution which is essentially free of metal ions, wherein the hydroxylamine solution is subjected to at least one treatment with an acidic cation exchanger.

Abstract: Compounds of the formula (I)

Abstract: Recuperative heat exchangers or regenerative heat exchangers are used for the thermal decomposition of N2O in N2O-containing gases. The process for the thermal decomposition of N2O in N2O-containing gases at from 800 to 1200° C. comprises passing the N2O-containing gas through one or more recuperative heat exchangers or regenerative heat exchangers in such a way that when the gas to be reacted is passed through a charge of heat transfer material it is heated to a temperature in the range from 800 to 1200° C. and the N2O present is decomposed thermally, and cooling the reacted gas by heat exchange so as to heat the charge of heat transfer material and the gas to be reacted.

Abstract: An aqueous solution of free hydroxylamine is prepared by treating a hydroxylammonium salt with ammonia by the countercurrent method in a stripping column by a process in which hydroxylamine is liberated and at the same time the solution obtained is separated by distillation into an aqueous hydroxylamine solution and a salt fraction. The novel process can be carried out in a simple and gentle manner and on a large scale. The danger of decomposition is minimized owing to the low thermal load, the low concentration of hydroxylamine and the short residence time in the process.

Abstract: A process for working up hydroxylamine-containing solutions as obtained in particular in the electronics industry during the cleaning of electronic components is described. According to the invention, the hydroxylamine is stripped from the wastewater with steam. The products obtained are aqueous hydroxylamine and an aqueous solution of the amines. Both product streams can be purified in further process steps to give a saleable product.

Abstract: A process for separating a fraction containing low and middle boilers from a mixture of low, middle and high boilers, which involves treating the mixture in a column with low-boiler vapor in the bottom, so that the middle-boiling component accumulates in the low-boiler vapor and can be obtained at the temperature level of the low-boiling component.

Abstract: A layered catalyst support or carrier provides a core member for carrying out non-steady state heterogeneously catalyzed processes where reaction gases and their products come in contact with a conventional catalyst applied to the carrier. The support as a carrier is made up of a large number of individually shaped particulate bodies or monolithic packings to be loaded into a reactor and maintained as a fluidized bed or a fixed bed during the non-steady state reaction and the recovery of the products. The support or carrier may consist of glass, quartz, oxides, nitrides, aluminosilicates, magnesium silicates, metals and carbon or their mixtures. Each shaped particle or monolithic packing of this core support is then completely enclosed by depositing thereon a thin protective layer of a nitride, oxide, carbide or chloride of a metal, a non-metal or a mixture thereof, which exhibits a dense, pore-free microstructure and a nonpolar surface having a very low density of acid centers.

Abstract: A process for breaking down hydroxylamine in aqueous solutions, especially wastewaters, by treatment with an oxidizing agent, which comprises using as said oxidizing agent an alkali metal hypohalite or alkaline earth metal hypohalite or peroxomonosulfuric or peroxodisulfuric acid or a salt thereof and carrying out the treatment with said oxidizing agent at a pH<8.

Abstract: A very pure aqueous solution of free hydroxylamine is prepared by a process in which the dilute, aqueous hydroxylamine solution is concentrated in a column by removing hydroxylamine-containing vapors via a side take-off in the bottom of the column, and very pure hydroxylamine is obtained by condensing the vapors. The novel process can be carried out simply, in a gentle manner and on a large scale and gives electronic grade hydroxylamine.