Abstract: A process for the preparation of kinetically stable semiconductor/polymer nanodispersion whereby the aqueous stability of the dispersed photocatalysts and polymer latex particles are ensured by the high surface charge. Consequently, the thin photocatalytically active antimicrobial coating prepared from this electrostatically stabilized aqueous dispersion by spray-coating method contains well-dispersed and evenly distributed surface photocatalyst particles immobilized by polymer and thus it provides homogeneous, transparent and mechanically stable photoreactive and antimicrobial thin film on arbitrary surfaces.