Patent number: 7355062
Abstract: A catalyst for the selective oxidation and amoxidation of alkanes and/or alkenes, particularly in processes for obtaining acrylic acid, acrylonitrile and derivatives of these, including a least one oxide of Mo, Te, V, Cu and at least another A component selected from among Nb, Ta, Sn, Se, W, Ti, Fe, Co, Ni, Cr, Ga, Sb, Bi, a rare, alkaline or alkali-earth earth, in such a way that the catalyst presents, in a calcined form, an X-ray diffractogram with five intensive diffraction lines, typically the most intense corresponding to diffraction angles of 2? at 22.1±0.4, 27.1±0.4; 28.1±0.4, 36.0±0.4 and 45.1±0.4. In the preferred embodiment, the catalyst has the following empiric formula: MoTehViCujAkOx in which h, i, j, k are values comprised between 0.001 and 4.0 and x depends on the oxidation status or valency of the Mo, Te, V, Cu and A elements.
Type:
Grant
Filed:
January 16, 2004
Date of Patent:
April 8, 2008
Assignees:
Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de Valencia
Inventors:
Jose Manuel López Nieto, Pablo Botella Asunción, Benjamín Solsona Espriu
Patent number: 7319179
Abstract: The invention relates to a method for the oxidative dehydrogenation of ethane. The inventive method is characterized in that it consists of bringing the ethane into contact with the catalyst containing Mo, Te, V, Nb and at least a fifth element A which is selected from Cu, Ta, Sn, Se, W, Ti, Fe, Co, Ni, Cr, Zr, Sb, Bi, an alkali metal, an alkaline-earth metal and a rare earth, in which at least Mo, Te, V and Nb are present in the form of at least one oxide, said catalyst presenting, in calcined form, an X-ray diffractogram with more than ten intense diffraction lines, typically, the most intense lines corresponding to diffraction angles 2? of 7.7°±0.4, 8.9°±0.4, 22.1°+0.4, 26.6°±0.4, 26.9°±0.4, 27.1°±0.4, 28.1°±0.4, 31.2°±0.4, 35.0°±0.4 and 45.06°±0.
Type:
Grant
Filed:
July 30, 2004
Date of Patent:
January 15, 2008
Assignees:
Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de Valencia
Inventors:
José Manuel López Nieto, Pablo Botella Asunción, Maria Isabel Vazquez Navarro, Ana Dejoz García
Publication number: 20050085678
Abstract: The invention relates to a method for the oxidative dehydrogenation of ethane. The inventive method is characterized in that it consists of bringing the ethane into contact with the catalyst containing Mo, Te, V, Nb and at least a fifth element A which is selected from Cu, Ta, Sn, Se, W, Ti, Fe, Co, Ni, Cr, Zr, Sb, Bi, an alkali metal, an alkaline-earth metal and a rare earth, in which at least Mo, Te, V and Nb are present in the form of at least one oxide, said catalyst presenting, in calcined form, an X-ray diffractogram with more than ten intense diffraction lines, typically, the most intense lines corresponding to diffraction angles 2? of 7.7°±0.4, 8.9°±0.4, 22.1°+0.4, 26.6°±0.4, 26.9°±0.4, 27.1°±0.4, 28.1°±0.4, 31.2°±0.4, 35.0°±0.4 and 45.06°±0.
Type:
Application
Filed:
July 30, 2004
Publication date:
April 21, 2005
Inventors:
Jose Lopez Nieto, Pablo Botella Asuncion, Maria Vazquez Navarro, Ana Garcia