Patents by Inventor Pamela J. Wright
Pamela J. Wright has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11952480Abstract: In some embodiments, the present disclosure provides a composition comprising 1) about 97.5 wt % to about 99.9 wt % of a first polyethylene having a density of about 0.91 g/cm3 to about 0.94 g/cm3, and a melt strength of about 10 mN or greater; and 2) about 0.1 wt % to about 2.5 wt % of a second polyethylene having an Mw of about 500,000 g/mol or more. In some embodiments, the composition is a film. In some embodiments, the present disclosure provides a method of making a composition comprising blending a first polyethylene of any embodiment described herein and a second polyethylene of any embodiment described herein.Type: GrantFiled: February 5, 2019Date of Patent: April 9, 2024Assignee: ExxonMobil Chemical Patents Inc.Inventors: Johannes M. Soulages, Arnold Lustiger, Thomas T. Sun, Pamela J. Wright, Madhavi Vadlamudi, Alexander I. Norman, Adriana S. Silva, David M. Fiscus, Timothy D. Shaffer
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Publication number: 20210371632Abstract: In some embodiments, the present disclosure provides a composition comprising 1) about 97.5 wt % to about 99.9 wt % of a first polyethylene having a density of about 0.91 g/cm3 to about 0.94 g/cm3, and a melt strength of about 10 mN or greater; and 2) about 0.1 wt % to about 2.5 wt % of a second polyethylene having an Mw of about 500,000 g/mol or more. In some embodiments, the composition is a film. In some embodiments, the present disclosure provides a method of making a composition comprising blending a first polyethylene of any embodiment described herein and a second polyethylene of any embodiment described herein.Type: ApplicationFiled: February 5, 2019Publication date: December 2, 2021Inventors: Johannes M. Soulages, Arnold Lustiger, Thomas T. Sun, Pamela J. Wright, Madhavi Vadlamudi, Alexander I. Norman, Adriana S. Silva, David M. Fiscus, Timothy D. Shaffer
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Patent number: 10947375Abstract: A system for producing a functionalized olefinic-based polymer, the system comprising a polymerization zone for producing an olefinic-based polymer comprising a mixing section, a deliquifying section, and a quenching section, wherein at least one section of the polymerization zone has a defined cross-sectional area that continually decreases from a first end to a second end of said section; a devolatilization zone comprising a kneader or extruder, wherein said devolatilization zone is downstream of said polymerization zone and in fluid communication with said polymerization zone; and a functionalization zone downstream of said devolatilization zone and in fluid communication with said devolatilization zone.Type: GrantFiled: December 9, 2016Date of Patent: March 16, 2021Assignee: ExxonMobil Chemical Patents Inc.Inventors: Yu Feng Wang, Richard D. Hembree, Michael F. McDonald, Jr., Joseph A. Maier, Richard C. M. Yeh, Leming Gu, Timothy D. Shaffer, Pamela J. Wright
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Publication number: 20200255643Abstract: A system for producing a functionalized olefinic-based polymer, the system comprising a polymerization zone for producing an olefinic-based polymer comprising a mixing section, a deliquifying section, and a quenching section, wherein at least one section of the polymerization zone has a defined cross-sectional area that continually decreases from a first end to a second end of said section; a devolatilization zone comprising a kneader or extruder, wherein said devolatilization zone is downstream of said polymerization zone and in fluid communication with said polymerization zone; and a functionalization zone downstream of said devolatilization zone and in fluid communication with said devolatilization zone.Type: ApplicationFiled: December 9, 2016Publication date: August 13, 2020Inventors: Yu Feng Wang, Richard D. Hembree, Michael F. McDonald, JR., Joseph A. Maier, Richard C.M. Yeh, Leming Gu, Timothy D. Shaffer, Pamela J. Wright
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Patent number: 9458310Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g? value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.Type: GrantFiled: August 13, 2012Date of Patent: October 4, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Pradeep P. Shirodkar, Jianya J. Cheng, Andy H. Tsou, Pamela J. Wright, Johannes M. Soulages
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Patent number: 8623980Abstract: A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.Type: GrantFiled: December 19, 2011Date of Patent: January 7, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: David John Lohse, Nikos Hadjichristidis, Andy Haishung Tsou, Pamela J. Wright, Suzzy Chen Hsi Ho, Paul Edward Schuenzel
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Patent number: 8513367Abstract: Method of reducing fouling in an elastomer polymerization process that includes providing a reactor capable of housing an industrial-scale elastomer polymerization reaction, and applying a mechanical force to the reactor so as to create a vibration in at least one wall of the reactor, in which fouling is reduced in the reactor. In one embodiment the reaction is an industrial scale butyl polymerization reaction and the reactor is a butyl polymerization reactor.Type: GrantFiled: November 11, 2011Date of Patent: August 20, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Timothy D. Shaffer, Pamela J. Wright, Limin Song
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Publication number: 20130211008Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g? value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.Type: ApplicationFiled: August 13, 2012Publication date: August 15, 2013Inventors: Pradeep P. SHIRODKAR, Jianya J. Cheng, Andy H. Tsou, Pamela J. Wright, Johannes M. Soulages
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Patent number: 8487061Abstract: Provided is a process for making a saturated star hydrocarbon polymer. The process has the following steps: (A) hydrosilylating tetraethylene silicon with methyldichlorosilane in the presence of a hydrosilylating catalyst to form a chlorosilane dendrimer; (B) reacting the chlorosilane dendrimer with vinylmagnesium bromide in the presence of a lithium and/or organolithium initiator stepwise to build a higher generation chlorosilane dendrimer; (C) anionically polymerizing polybutadiene in the presence of a lithium and/or organolithium initiator to form living poly(butadienyl)lithium; (D) attaching the living poly(butadienyl)lithium to the higher generation dendrimer to form a star polybutadiene; and (E) hydrogenating the star polybutadiene to form the saturated star hydrocarbon polymer. There is also provided a saturated star hydrocarbon polymer made according to the above process and a polymer composition of a matrix ethylene polymer and the saturated star hydrocarbon polymer.Type: GrantFiled: May 17, 2011Date of Patent: July 16, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Andy H. Tsou, Nikos Hadjichristidis, Pamela J. Wright, Johannes M. Soulages
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Publication number: 20120296046Abstract: Provided is a process for making a saturated star hydrocarbon polymer. The process has the following steps: (A) hydrosilylating tetraethylene silicon with methyldichlorosilane in the presence of a hydrosilylating catalyst to form a chlorosilane dendrimer; (B) reacting the chlorosilane dendrimer with vinylmagnesium bromide in the presence of a lithium and/or organolithium initiator stepwise to build a higher generation chlorosilane dendrimer; (C) anionically polymerizing polybutadiene in the presence of a lithium and/or organolithium initiator to form living poly(butadienyl)lithium; (D) attaching the living poly(butadienyl)lithium to the higher generation dendrimer to form a star polybutadiene; and (E) hydrogenating the star polybutadiene to form the saturated star hydrocarbon polymer. There is also provided a saturated star hydrocarbon polymer made according to the above process and a polymer composition of a matrix ethylene polymer and the saturated star hydrocarbon polymer.Type: ApplicationFiled: May 17, 2011Publication date: November 22, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Andy H. Tsou, Nikos Hadjichristidis, Pamela J. Wright, Johannes M. Soulages
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Publication number: 20120157633Abstract: A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.Type: ApplicationFiled: December 19, 2011Publication date: June 21, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: David John Lohse, Nikos Hadjichristidis, Andy Haishung Tsou, Pamela J. Wright, Suzzy Chen Hsi Ho, Paul Edward Schuenzel
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Publication number: 20120130026Abstract: Method of reducing fouling in an elastomer polymerization process that includes providing a reactor capable of housing an industrial-scale elastomer polymerization reaction, and applying a mechanical force to the reactor so as to create a vibration in at least one wall of the reactor, in which fouling is reduced in the reactor. In one embodiment the reaction is an industrial scale butyl polymerization reaction and the reactor is a butyl polymerization reactor.Type: ApplicationFiled: November 11, 2011Publication date: May 24, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Timothy D. SHAFFER, Pamela J. WRIGHT, George P. AKEHURST, Limin SONG
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Patent number: 8178465Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.Type: GrantFiled: January 12, 2011Date of Patent: May 15, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Timothy D. Shaffer, Michael F. McDonald, David Y. Chung, Robert N. Webb, Deborah J. Davis, Pamela J. Wright
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Publication number: 20110111950Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.Type: ApplicationFiled: January 12, 2011Publication date: May 12, 2011Inventors: Timothy D. Shaffer, Michael F. McDonald, David Y. Chung, Robert N. Webb, Deborah J. Davis, Pamela J. Wright
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Patent number: 7893176Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.Type: GrantFiled: March 23, 2007Date of Patent: February 22, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Timothy D. Shaffer, Michael F. McDonald, David Y. Chung, Robert N. Webb, Deborah J. Davis, Pamela J. Wright
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Patent number: 7557170Abstract: The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 ?m (12 microinches).Type: GrantFiled: July 24, 2008Date of Patent: July 7, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Timothy D. Shaffer, Pamela J. Wright, J. Davis Deborah, Michael F. McDonald
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Publication number: 20090062484Abstract: The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 ?m (12 microinches).Type: ApplicationFiled: July 24, 2008Publication date: March 5, 2009Inventors: Timothy D. Shaffer, Pamela J. Wright, J. Davis Deborah, Michael F. McDonald
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Publication number: 20090062496Abstract: Provided is a method for reducing depositions in polymerization vessels, where the method includes the steps of providing a reaction vessel having polymerization contact surfaces, polishing a majority of the polymerization contact surfaces to have an average percent excess surface areas (SAxs) of 2% or less, introducing a catalyst system and at least one monomer or comonomer mixture in the reaction vessel, and polymerizing the at least one monomer or comonomer mixture. The catalyst may be soluble in the diluent used for polymerization. The method may be useful for low temperature polymerization systems.Type: ApplicationFiled: July 24, 2008Publication date: March 5, 2009Inventors: Timothy D. Shaffer, Pamela J. Wright, J. Davis Deborah, Michael F. McDonald
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Publication number: 20080234447Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.Type: ApplicationFiled: March 23, 2007Publication date: September 25, 2008Inventors: Timothy D. Shaffer, Michael F. McDonald, David Y. Chung, Robert N. Webb, Deborah J. Davis, Pamela J. Wright
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Patent number: 7402636Abstract: The disclosure provides a slurry polymerization system and method to decrease polymer deposition on reactor surfaces using an oxygenate such as alcohol (16) supplied to the polymerization medium (32) separate from the catalyst feed (34).Type: GrantFiled: March 23, 2007Date of Patent: July 22, 2008Assignee: ExxonMobil Chemical Patents IncInventors: Timothy D. Shaffer, Michael F. McDonald, David Y. Chung, Robert N. Webb, Deborah J. Davis, Pamela J. Wright