Patents by Inventor Panagiotis I. Kordomenos
Panagiotis I. Kordomenos has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4952626Abstract: Coating composition containing hydroxy functional polyester graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1,300 and about 15,000, has a hydroxy number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polyester macromonomer. The macromonomer is the reaction product of (i) isocyanato monomer having the formula: ##STR1## with (ii) hydroxy functional polyester reactant containing 0-1- urethane linkages per molecule.Type: GrantFiled: December 9, 1988Date of Patent: August 28, 1990Assignee: E. I. du pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Rose A. Ryntz
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Patent number: 4902757Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: October 5, 1988Date of Patent: February 20, 1990Assignee: E. I. Du Pont de Nemours & Co.Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Tab Semanision
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Patent number: 4902755Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: October 5, 1988Date of Patent: February 20, 1990Assignee: E. I. Du Pont de Nemours & Co.Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Tab Semanision
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Patent number: 4902754Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: October 5, 1988Date of Patent: February 20, 1990Assignee: E. I. Du Pont de Nemours & Co.Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Tab Semanision
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Patent number: 4902756Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: October 5, 1988Date of Patent: February 20, 1990Assignee: E. I. Du Pont de Nemours & Co.Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Tab Semanision
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Patent number: 4870141Abstract: Novel solvent-based thermosetting composition comprising (a) hydroxy functional epoxy ester resin of number average molecular weight (Mn) between about 1,000 and about 5,000, comprising the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising (i) hydroxy functional acid and, optionally, (ii) fatty acid; and (b) polyfunctional, hydroxy-reactive crosslinking agent, for example, aminoplast crosslinking agent or blocked polyisocyanate crosslinking agent comprising isocyanate groups blocked by reaction with an active hydrogen bearing blocking agent. Coating composition may be formulated as primer sprayable with conventional spraying equipment.Type: GrantFiled: November 4, 1987Date of Patent: September 26, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: Panagiotis I. Kordomenos
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Patent number: 4833216Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional urethane modified polyester resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the produce of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: October 7, 1987Date of Patent: May 23, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Tab Semanision
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Patent number: 4824917Abstract: A solvent-based thermosetting coating composition comprising hydroxy functional urethane modified polyester resin and amine-aldehyde crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on motor vehicle body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: November 4, 1987Date of Patent: April 25, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan
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Patent number: 4816528Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy-polyester graft copolymer and polyfunctional, hydroxy-reactive crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. The composition also may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone monomers in presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the product of modified diepoxide and hydroxy functional secondary amine, the modified diepoxide being the product of the polymerization of lactone monomers in the presence of diepoxide which has been chain extended with dicarboxylic acid.Type: GrantFiled: September 3, 1987Date of Patent: March 28, 1989Assignee: E. I. DuPont de Nemours and CompanyInventors: Andrew H. Dervan, Panagiotis I. Kordomenos
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Patent number: 4812535Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy-polyester graft copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide chain extended with diphenol and chain terminated with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.Type: GrantFiled: September 3, 1987Date of Patent: March 14, 1989Assignee: E. I. DuPont de Nemours and CompanyInventors: Andrew H. Dervan, Panagiotis I. Kordomenos
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Patent number: 4804718Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy-polyester graft copolymer and polyfunctional, hydroxy-reactive crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. The composition also may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone monomers in presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the product of modified diepoxide and hydroxy functional secondary amine, the modified diepoxide being the product of the polymerization of lactone monomers in the presence of diepoxide which has been chain extended with diphenol.Type: GrantFiled: September 3, 1987Date of Patent: February 14, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Panagiotis I. Kordomenos
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Patent number: 4794149Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: September 3, 1987Date of Patent: December 27, 1988Assignee: E. I. Du Pont De Nemours and CompanyInventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
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Patent number: 4791179Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy-polyester graft copolymer and polyfunctional, hydroxy-reactive crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. The composition may also be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor is the reaction product of modified diepoxide and hydroxy functional secondary amine in about a 1:1 equivalent ratio.Type: GrantFiled: September 3, 1987Date of Patent: December 13, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Panagiotis I. Kordomenos
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Patent number: 4786691Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, and polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: August 7, 1987Date of Patent: November 22, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Panagiotis I. Kordomenos
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Patent number: 4778861Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.Type: GrantFiled: August 7, 1987Date of Patent: October 18, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
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Patent number: 4769425Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy amine adduct precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with hydroxy functional secondary amine. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.Type: GrantFiled: August 7, 1987Date of Patent: September 6, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
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Patent number: 4767829Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: June 11, 1987Date of Patent: August 30, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
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Patent number: 4754002Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: December 16, 1985Date of Patent: June 28, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
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Patent number: 4742129Abstract: An organic solvent based, thermosetting coating composition of a hydroxy functional epoxy-polyester graft copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: August 7, 1987Date of Patent: May 3, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
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Patent number: 4737551Abstract: A solvent-based thermosetting coating composition comprising hydroxy functional urethane modified polyester resin and amine-aldehyde crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on motor vehicle body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.Type: GrantFiled: June 23, 1986Date of Patent: April 12, 1988Assignee: E. I. DuPont de Nemours and CompanyInventors: Andrew H. Dervan, Panagiotis I. Kordomenos