Abstract: An ethylene oxide (EO) production process comprising (a) introducing a first reactant mixture (C2H6, O2) to a first reactor to produce a first effluent stream (C2H4, C2H6, O2); (b) introducing a second reactant mixture to a second reactor to produce a second effluent stream (EO, C2H4, C2H6, O2); wherein the second reactant mixture comprises at least a portion of first effluent stream; (c) separating the second effluent stream into an EO product stream (EO) and recycle stream (C2H4, C2H6, O2); wherein ethylene is not separated from recycle stream and/or first effluent stream; and (d) recycling a first portion of recycle stream to the first reactor, and a second portion of recycle stream to the second reactor; wherein recycle split ratio <0.6; and wherein recycle split ratio is defined as ratio of volumetric flowrate of first portion of recycle stream divided by the sum of volumetric flowrates of first portion and second portion of recycle stream.

Abstract: The invention relates to a composition containing an oxide supported oxidative coupling of methane catalyst having an excellent balance of catalytic activity and selectivity while retaining desired levels mechanical stability suitable for commercial reactor application. Particularly, the inventive catalyst is an oxide supported catalyst with the oxide catalyst support having a spherical diameter of less than 2 mm and a surface area of less than less than 9.5 m2/g while retaining a water sorption volume of at least 0.2 cc/g. The invention further provides a method for preparing such a composition containing an oxide supported catalyst, using a combination of thermal treatment of the oxide catalyst support, active component impregnation and followed up by calcination. Additionally, the invention also describes a process for producing C2+ hydrocarbons, using such a catalyst composition.

Abstract: An ethylene oxide (EO) production process comprising (a) introducing a first reactant mixture (C2H6, C2H4, O2) to a first reactor to produce a first effluent stream (C2H4, C2H6, O2), wherein the mole fraction of ethylene in first effluent stream is greater than in first reactant mixture; wherein the first reactant mixture is characterized by a molar ratio of ethylene to ethane of ?1.3; (b) introducing the first effluent stream to a second reactor to produce a second effluent stream (EO, C2H4, C2H6, O2); (c) separating the second effluent stream into an EO product stream (EO) and recycle stream (C2H4, C2H6, O2); wherein ethylene is not separated from recycle stream and/or first effluent stream; and (d) recycling at least a portion of recycle stream to the first reactor, and a portion of recycle stream to the second reactor.

Abstract: An ethylene oxide (EO) production process comprising (a) introducing a first reactant mixture (C2H6, C2H4, O2) to a first reactor system to produce a first effluent stream (C2H4, C2H6, O2), wherein the mole fraction of ethylene in first effluent stream is greater than in first reactant mixture; wherein the first reactor system is characterized by a first reactor system operating temperature of 270° C.-320° C.; wherein the first reactor system comprises oxidative dehydrogenation (ODH) stage(s); (b) introducing the first effluent stream to a second reactor to produce a second effluent stream (EO, C2H4, C2H6, O2); (c) separating the second effluent stream into an EO product stream (EO) and recycle stream (C2H4, C2H6, O2); wherein ethylene is not separated from recycle stream and/or first effluent stream; (d) recycling at least a portion of recycle stream to the first reactor system, and a optionally portion of recycle stream to the second reactor.

Abstract: Disclosed are methods and systems for desulfurization of CO-rich streams. A method can include contacting a CO-rich gas stream with activated carbon and/or contacting the CO-rich gas stream with a zinc-oxide sorbent material at a temperature of 0 to 50° C. to remove at least a portion of the sulfur-containing compounds present in the stream.

Abstract: Provided are improved steam-drying systems, the systems being configured so as to multiple resin streams into steam streams.

Abstract: A method of preparing a poly(ester-carbonate) includes contacting an aqueous solution including a dicarboxylic acid with a first solution including phosgene and a first organic solvent in a tubular reactor to provide a first reaction mixture. A dihydroxy aromatic compound, the corresponding dialkali metal salt of the dihydroxy aromatic compound, or a combination comprising at least one of the foregoing, water, and a second organic solvent are combined to provide a second reaction mixture. The method further includes introducing the first reaction mixture, the second reaction mixture, and a second solution comprising phosgene to a tank reactor, wherein the tank reactor has a first pH of 7 to 10. The pH is optionally raised to 9 to 11 to provide a third reaction mixture including the poly(ester-carbonate). Poly(ester-carbonate)s prepared according to the method described herein are also disclosed.

Abstract: A method for producing ethylene and methanol comprising contacting fuel gas and oxidant gas to produce combustion product; contacting hydrocarbons and combustion product to produce pyrolysis product comprising unconverted hydrocarbons, acetylene, ethylene, CO, H2, H2O, CO2; separating pyrolysis product into CO2 stream and CO2 free product comprising unconverted hydrocarbons, acetylene, ethylene, CO, H2; contacting a first portion of CO2 free product with aprotic polar solvent to produce acetylene solution and first gas stream comprising unconverted hydrocarbons, ethylene, CO, H2; contacting acetylene solution with a second portion of CO2 free product to produce hydrogenation product comprising aprotic polar solvent, unconverted hydrocarbons, ethylene, CO, H2; separating hydrogenation product into aprotic polar solvent stream and second gas stream comprising unconverted hydrocarbons, ethylene, CO, H2; separating second gas stream into ethylene stream and third gas stream comprising unconverted hydrocarbons, CO

Abstract: In an embodiment, a continuous method of forming a bisphenol A oil comprises forming the bisphenol A oil by mixing a molten bisphenol A and water; wherein the bisphenol A oil comprises 10 to 30 wt % water based on a total weight of the bisphenol A oil and is at a temperature of 100 to 140° C.; flowing at least a portion of the bisphenol A oil through an inline densitometer and measuring a real-time density and a real-time temperature of the bisphenol A oil; determining a real-time concentration of the bisphenol A oil based on said real-time density and said real-time temperature.

Abstract: A process for drying resinous materials, comprising: delivering, by way of a plurality of resin channels, resin fluid comprising polymer and solvent into at least first and second steam channels (101) having within a flow of steam, the first and second steam channels (101) each receiving resin fluid from a plurality of resin channels, the first and second steam channels each (101) being received by a stage 1 manifold (121), the steam and resin being delivered under conditions so as to separate at least some of the solvent from the resin fluid; and collecting at least some of the polymer from the resin fluid.

Abstract: Integrated processes for the conversion of hydrocarbons to C2 and C3 unsaturated hydrocarbons include combustion and cracking of hydrocarbons, dry oxidative reforming of methane, and catalytic hydrogenation of acetylene. Reactive products formed among the integrated processes may be distributed and recycled among the processes for the conversion of the hydrocarbon feedstock.

Abstract: A methane conversion process for producing C2+ hydrocarbons comprising (a) introducing a reactant mixture comprising methane (>20 mol %) and an inert compound to a reaction unit to produce a reactor effluent stream comprising C2+ hydrocarbons, methane, the inert compound, and water and/or carbon dioxide; (b) removing at least a portion of the water and/or at least a portion of the carbon dioxide from the reactor effluent stream to produce a demethanizer feed stream; (c) feeding at least a portion of the demethanizer feed stream to a demethanizer unit to produce two or more vapor streams (methane rich stream and inert rich stream), and at least one liquid stream (C2+ hydrocarbons); (d) withdrawing at least a portion of the inert rich stream as a purge stream; (e) recycling any remaining portion of the inert rich stream to the reaction unit; and (f) recycling the methane rich stream to the reaction unit.

Abstract: A systems and method for production of acetylene by pyrolysing a feedstock through combustion products are disclosed.

Abstract: A methane conversion process for producing C2+ hydrocarbons comprising (a) introducing a reactant mixture comprising methane (>20 mol %) and an inert compound to a reaction unit to produce a reactor effluent stream comprising C2+ hydrocarbons, methane, the inert compound, and water and/or carbon dioxide; (b) removing at least a portion of the water and/or at least a portion of the carbon dioxide from the reactor effluent stream to produce a demethanizer feed stream; (c) feeding at least a portion of the demethanizer feed stream to a demethanizer unit to produce two or more vapor streams (methane rich stream and inert rich stream), and at least one liquid stream (C2+ hydrocarbons); (d) withdrawing at least a portion of the inert rich stream as a purge stream; (e) recycling any remaining portion of the inert rich stream to the reaction unit; and (f) recycling the methane rich stream to the reaction unit.

Abstract: Disclosed herein are processes, apparatuses, and systems for producing chemicals. One system may comprise a wall defining a chamber; a plurality of burners configured in an arrangement within the chamber, wherein each of the burners is supplied with a material and facilitates combustion of the material, and wherein the arrangement defines an inner volume disposed radially inwardly relative thereto; and an injector disposed within the inner volume and configured to introduce a feedstock into the chamber, wherein the plurality of burners provide thermal energy to facilitate thermal pyrolysis of the feedstock.

Abstract: A method of preparing a poly(ester-carbonate) includes contacting an aqueous solution including a dicarboxylic acid with a first solution including phosgene and a first organic solvent in a tubular reactor to provide a first reaction mixture. A dihydroxy aromatic compound, the corresponding dialkali metal salt of the dihydroxy aromatic compound, or a combination comprising at least one of the foregoing, water, and a second organic solvent are combined to provide a second reaction mixture. The method further includes introducing the first reaction mixture, the second reaction mixture, and a second solution comprising phosgene to a tank reactor, wherein the tank reactor has a first pH of 7 to 10. The pH is optionally raised to 9 to 11 to provide a third reaction mixture including the poly(ester-carbonate). Poly(ester-carbonate)s prepared according to the method described herein are also disclosed.

Abstract: In an embodiment, a continuous method of forming a bisphenol A oil comprises forming the bisphenol A oil by mixing a molten bisphenol A and water; wherein the bisphenol A oil comprises 10 to 30 wt % water based on a total weight of the bisphenol A oil and is at a temperature of 100 to 140° C.; flowing at least a portion of the bisphenol A oil through an inline densitometer and measuring a real-time density and a real-time temperature of the bisphenol A oil; determining a real-time concentration of the bisphenol A oil based on said real-time density and said real-time temperature.

Abstract: In an embodiment, a method of producing phosgene in a tube reactor comprises introducing a feed comprising carbon monoxide and chlorine to a tube of the reactor, the tube having a particulate catalyst disposed therein, wherein a thermally conductive material separate from the tube contacts at least a portion of the particulate catalyst; to produce a product composition comprising phosgene, and carbon tetrachloride in an amount of 0 to 10 ppm by volume based on the volume of the phosgene.

Abstract: Provided are improved steam-drying systems, the systems being configured so as to multiple resin streams into steam streams.

Abstract: A process for drying resinous materials, comprising: delivering, by way of a plurality of resin channels, resin fluid comprising polymer and solvent into at least first and second steam channels (101) having within a flow of steam, the first and second steam channels (101) each receiving resin fluid from a plurality of resin channels, the first and second steam channels each (101) being received by a stage 1 manifold (121), the steam and resin being delivered under conditions so as to separate at least some of the solvent from the resin fluid; and collecting at least some of the polymer from the resin fluid.