Abstract: Disclosed in certain embodiments are carbon dioxide sorbents that include porous particles impregnated with an amine compound.

Abstract: Catalytic articles comprising a substrate having a catalytic coating thereon, the catalytic coating comprising a catalytic layer having a thickness and an inner surface proximate to the substrate and an outer surface distal to the substrate; where the catalytic layer comprises a noble metal component on support particles and where the concentration of the noble metal component towards the outer surface is greater than the concentration towards the inner surface are highly effective towards treating exhaust gas streams of internal combustion engines. The articles are prepared via a method comprising providing a first mixture comprising micron-scaled support particles and applying the first mixture to a substrate to form a micro-particle layer; providing a second mixture comprising nano-scaled support particles and a noble metal component having an initial pH and applying the second mixture to the micro-particle layer and calcining the substrate.

Abstract: Described herein are coatings. The coatings can, for example, catalyze carbon gasification. In some examples, the coatings comprise: a first region having a first thickness, the first region comprising a manganese oxide, a chromium-manganese oxide, or a combination thereof; a second region having a second thickness, the second region comprising Ni, Fe, W, Cr, Co, Mn, Ti, Mo, V, Nb, Zr, Si, C, or a combination thereof; and an alkaline earth metal, an alkaline earth oxide, an alkaline earth carbonate, an alkaline earth silicate, molybdemun, a molybdemn oxide, a molybdemn carbide, a mixed-metal perovskite, a mixed metal inorganic oxide, or a combination thereof.

Abstract: The present disclosure provides catalytic materials formed of co-precipitates of vanadium, tungsten, and titanium, catalytic articles formed using such co-precipitates, and methods of making such precipitates. The co-precipitates may be used in the form of calcined particles, and catalytic articles incorporating coatings formed of the co-precipitate can exhibit improved adhesion and performance.

Abstract: Catalytic articles comprising a substrate having a catalytic coating thereon, the catalytic coating comprising a catalytic layer having a thickness and an inner surface proximate to the substrate and an outer surface distal to the substrate; where the catalytic layer comprises a noble metal component on support particles and where the concentration of the noble metal component towards the outer surface is greater than the concentration towards the inner surface are highly effective towards treating exhaust gas streams of internal combustion engines. The articles are prepared via a method comprising providing a first mixture comprising micron-scaled support particles and applying the first mixture to a substrate to form a micro-particle layer; providing a second mixture comprising nano-scaled support particles and a noble metal component having an initial pH and applying the second mixture to the micro-particle layer and calcining the substrate.

Abstract: Disclosed herein are a catalyst composition, catalyst devices, and methods for removing formaldehyde, volatile organic compounds, and other pollutants from an air flow stream. The catalyst composition including manganese oxide, optionally one or more of alkali metals, alkaline earth metals, zinc, iron, binder, an inorganic oxide, or carbon.

Abstract: Catalytic articles comprising a substrate having a catalytic coating thereon, the catalytic coating comprising a catalytic layer having a thickness and an inner surface proximate to the substrate and an outer surface distal to the substrate; where the catalytic layer comprises a noble metal component on support particles and where the concentration of the noble metal component towards the outer surface is greater than the concentration towards the inner surface are highly effective towards treating exhaust gas streams of internal combustion engines. The articles are prepared via a method comprising providing a first mixture comprising micron-scaled support particles and applying the first mixture to a substrate to form a micro-particle layer; providing a second mixture comprising nano-scaled support particles and a noble metal component having an initial pH and applying the second mixture to the micro-particle layer and calcining the substrate.

Abstract: Disclosed herein are a catalyst composition, catalyst devices, and methods for removing formaldehyde, volatile organic compounds, and other pollutants from an air flow stream. The catalyst composition including manganese oxide, optionally one or more of alkali metals, alkaline earth metals, zinc, iron, binder, an inorganic oxide, or carbon.

Abstract: Disclosed in certain embodiments are carbon dioxide and VOC sorbents that include a porous support impregnated with an amine compound.

Abstract: Disclosed herein are catalyst devices for removing formaldehyde, volatile organic compounds, and other pollutants from an air flow stream, A catalyst device includes a housing, a solid substrate disposed within the housing, and a catalyst layer disposed on the substrate. The catalyst layer includes a base metal catalyst at a first mass percent and a rare earth metal catalyst at a second mass percent.

Abstract: Disclosed in certain embodiments are carbon dioxide sorbents that include porous particles impregnated with an amine compound.

Abstract: This application discloses catalysts and methods of making the catalysts. In one embodiment, a catalyst comprising: a reduced precious group metal in an amount greater than about 30 wt % based on the total precious group metal weight in the catalyst, wherein the catalyst oxidizes volatile organic compounds and/or carbon monoxide at a temperature of about 150° C. or lower, is disclosed. In another embodiment, a catalyst for oxidation of formaldehyde, methanol, formic acid, and/or carbon monoxide to form carbon dioxide at a temperature of from about 20° C. to about 45° C. and at about atmospheric pressure, the catalyst comprising: a reduced precious group metal dispersed on a support selected from the group consisting of CeO2, TiO2, ZrO2, Al2O3, SiO2, and combinations thereof, is disclosed.

Abstract: This application discloses catalysts and methods of making the catalysts. In one embodiment, a catalyst comprising: a reduced precious group metal in an amount greater than about 30 wt % based on the total precious group metal weight in the catalyst, wherein the catalyst oxidizes volatile organic compounds and/or carbon monoxide at a temperature of about 150° C. or lower, is disclosed. In another embodiment, a catalyst for oxidation of formaldehyde, methanol, formic acid, and/or carbon monoxide to form carbon dioxide at a temperature of from about 20° C. to about 45° C. and at about atmospheric pressure, the catalyst comprising: a reduced precious group metal dispersed on a support selected from the group consisting of CeO2, TiO2, ZrO2, Al2O3, SiO2, and combinations thereof, is disclosed.

Abstract: A structure and system for the adsorption of carbon dioxide from air, the system comprising a sorbent structure comprising a porous substrate having a porous alumina coating on the surfaces of said substrate, and the sorbent for carbon dioxide is embedded on the surfaces of said porous alumina coating. The substrate is preferably a porous monolith, formed from silica or mesocellular foam. The sorbent is an amine group-containing material, preferably loaded at 40 to 60 percent by volume relative to the porous alumina coating.

Abstract: Catalysts, catalyst systems, and methods for removing ammonia and/or carbon monoxide in flue gases are provided where ammonia is used with a selective catalytic reduction catalyst for reducing oxides of nitrogen. An oxidation catalyst is utilized, which comprises particulate platinum or platinum/palladium dispersed on zirconia particles, the particulate platinum or platinum/palladium having an average particle size less than about 10 nm. The catalyst is effective to convert less than 20% of NO to NO2 passing through the oxidation catalyst.

Abstract: A gas stream containing nitrous oxide and ammonia is contacted with a catalyst composition containing a zeolite. N2O is reduced to N2 and H2O at low temperatures in a highly efficient manner. Ammonia-mediated reduction of nitrous oxide can be effectuated from gas streams having N2O concentrations as low as 1%. The gas stream may also contact a catalytic composition selective for the reduction of NOx. In this way, N2O and NOx treatment may be effectuated in a single process stream.

Abstract: Catalysts are provided that are capable of use at low temperatures (<80° C.) to remove volatile organic compounds (VOCs) in an enclosed space. The catalyst is combined with an adsorbent to form a catalytic article. Methods of manufacturing catalytic articles are described in which the catalyst is mixed with discrete particles of adsorbent or supported directly on the adsorbent.

Abstract: Catalyst articles comprising palladium and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first catalytic layer formed on a substrate, wherein the first catalytic layer comprises palladium impregnated on a ceria-free oxygen storage component and platinum impregnated on a refractory metal oxide, and a second catalytic layer formed on the first catalytic layer comprising platinum impregnated on an oxygen storage component and rhodium impregnated on a zirconia-coated or yttria-coated alumina. The palladium component of the catalyst article is present in a higher proportion relative to the other platinum group metal components. The catalyst articles provide improved reductions in NOx in exhaust gases, particularly after lean-rich aging.

Abstract: The present invention is directed to a method for removal by oxidation of the excess ammonia (NH3) gas (“ammonia slip”) resulting from flue gases that have been subjected to selective catalytic reduction (SCR) for reduction of nitrogen oxides (NOx) with ammonia. More specifically, the inventive method uses an ammonia oxidation catalyst consisting of a zeolite, one or more precious metals, and a base metal compound, to catalyze the oxidation of both ammonia and carbon monoxide (CO), while minimizing the formation of nitrogen oxides (NOx). The present invention is useful in treating flue and exhaust gases.

Abstract: Catalysts, catalyst systems, and methods for removing ammonia and/or carbon monoxide in flue gases are provided where ammonia is used with a selective catalytic reduction catalyst for reducing oxides of nitrogen. An oxidation catalyst is utilized, which comprises particulate platinum or platinum/palladium dispersed on zirconia particles, the particulate platinum or platinum/palladium having an average particle size less than about 10 nm. The catalyst is effective to convert less than 20% of NO to NO2 passing through the oxidation catalyst.