Abstract: The disclosure features systems and methods for detecting organic compounds that include: (a) a transfer line; (b) a probe connected to a first end of the transfer line, the probe including an inlet port and a membrane positioned across an opening in the inlet port; (c) an analysis unit connected to a second end of the transfer line; and (d) an electronic controller. The analysis unit can include a valve featuring multiple ports, a first detection unit configured to measure a photoionization current, and a second detection unit configured to identify chemical compounds, and a trap configured to condense chemical compounds from a vapor phase to a liquid phase. The electronic controller is connected to the valve, the first and second detection units, and the trap.