Abstract: A method for forming a coating on aluminum by contacting the aluminum with water, at least one multifunctional polymeric organic acid, a monomer of an intrinsically conductive polymer (ICP) and polymerizing the ICP monomer and forming aluminum oxide by imposing an electrical potential between the aluminum surface as the anode and a cathode. The intrinsically conductive polymer salt and aluminum oxide coating that is formed resists corrosion and is resistant to de-doping during immersion in hot water.

Abstract: A process for preparing fibers containing intrinsically conductive polymers comprises extruding two or more filaments, applying a coating formulation containing a salt of an intrinsically conductive polymer to at least one of the filaments to form a coated filament, combining the filaments to form a filament bundle, and processing the bundle into a fiber. A filament coated with an intrinsically conductive polymer and a fiber comprising at least one coated filament are also provided which are useful in preparing textiles and other materials which exhibit conductivity.

Abstract: A fiber containing an organic acid salt of an intrinsically conductive polymer distributed throughout a matrix polymer is provided along with a method for producing such fibers by spinning a solution which includes an organic acid salt of an intrinsically conductive polymer, a matrix polymer and a spinning solvent into a coagulation bath comprising a nonsolvent for both the organic acid salt of an intrinsically conductive polymer and the matrix polymer. The intrinsically conductive polymer-containing fibers typically have electrical conductivities below about 10.sup.-5 S/cm.

Abstract: A fiber containing an organic acid salt of an intrinsically conductive polymer distributed throughout a matrix polymer along with a method for providing such fibers by spinning a solution which includes an organic acid salt of an intrinsically conductive polymer, a matrix polymer and a spinning solvent into a coagulation bath including a nonsolvent for both the organic acid salt of an intrinsically conductive polymer and the matrix polymer. The intrinsically conductive polymer-containing fibers typically have electrical conductivities below about 10.sup.-5 S/cm.

Abstract: Organically soluble intrinsically conductive polymer compositions having enhanced electrical conductivity are produced by adding a hygroscopic, water-insoluble plasticizer to an organically soluble intrinsically conductive polymer salt. Polymer blends containing such compositions are also produced by blending a matrix polymer with the plasticizer/ICP salt compositions. Methods for enhancing the electrical conductivity of an organically soluble intrinsically conductive polymer salt provide for the addition of a hygroscopic, water-insoluble plasticizer to an organically soluble intrinsically conductive polymer salt.

Abstract: Emulsion-polymerization of electrically conductive polyaniline salts is disclosed. The process comprises combining water, a water-solubilizing organic solvent, an organic acid that is soluble in the organic solvent, an aniline monomer, and a radical initiator. An organic phase forms which contains the polyaniline salt of the organic acid wherein the organic phase is separable from an aqueous phase. The polyaniline salt so formed is soluble in organic carrier solvents at a concentration of 25 w/w % or greater.

Abstract: A method for increasing the conductivity of polyaniline is disclosed. The method comprises contacting the polyaniline with an ionic surfactant whereupon the conductivity of the polyaniline is increased by a factor of at least about 2. Also provided are coating compositions which can be prepared by the method.

Abstract: Electrically-conductive polyaniline salts that are soluble in xylene and an emulsion-polymerization process for producing the salts is disclosed. The process comprises the steps of combining water, a water soluble organic solvent, a hydrophobic organic acid, an aniline monomer, and a radical initiator and allowing the mixture to form the electrically-conductive polyaniline salt of the acid.

Abstract: A method for forming a coating on an electrically conductive surface is discloses. The method comprises the steps of immersing the surface in a bath comprising an electrodepositable mixture of an intrinsically insulative polymer and an organic acid salt of an intrinsically conductive polymer, applying a voltage between an electrode and the surface in the bath to deposit a polymeric coating of the mixture on the surface, and curing the polymeric coating. The polymeric coating can be made electrically conductive by the additional step of immersing the polymeric coating in an organic acid after the deposition and before curing. A multilayered coating can be provided after curing the electrically conductive polymeric coating, by depositing a second or subsequent coating of an electrodepositable organic resin from an aqueous bath containing the resin on application of a voltage between an electrode and the electrically conductive polymeric subcoating in the bath.

Abstract: A method for forming a coating on an electrically conductive surface is disclosed. The method comprises the steps of immersing the surface in a bath comprising an electrodepositable mixture of an intrinsically insulative polymer and an organic acid salt of an intrinsically conductive polymer, applying a voltage between an electrode and the surface in the bath to deposit a polymeric coating of the mixture on the surface, and curing the polymeric coating. The polymeric coating can be made electrically conductive by the additional step of immersing the polymeric coating in an organic acid after the deposition and before curing. A multilayered coating can be provided after curing the electrically conductive polymeric coating, by depositing a second or subsequent coating of an electrodepositable organic resin from an aqueous bath containing the resin on application of a voltage between an electrode and the electrically conductive polymeric subcoating in the bath.

Abstract: A corrosion inhibiting composition is provided. The composition comprises an intrinsically conductive polymer, e.g. polyaniline or polypyrrole, blended in a binder material, preferably a non-thermoplastic matrix, the blend being capable of adhering to a metal surface to provide enhanced corrosion resistance to the metal. The blend provides corrosion resistance in a variety of corrosive environments such as acidic, alkaline, and salt environments. A method for protecting metal surfaces from corrosive attack by applying the corrosion inhibiting composition is provided, as well as two component corrosion inhibiting coatings, corrosion inhibited thin films of metal adhered to an intrinsically conducting polymer containing substrate, and corrosion inhibited metal bilayers.

Abstract: Metal/polymer laminates prepared from essentially insoluble anionomeric polymer film layer with catalytic metal, e.g. palladium, exchanged into surface acid groups which can be reduced to provide catalytic metal clusters for catalyzing electroless deposition of metal which is resistant to removal by adhesive tape. Anionomeric polymer films are coated from solutions, emulsions or dispersions of sulfonated or carboxylated polyesters or sulfonated, phosphonated or carboxylated perfluorocarbon polymer, dried and heat treated, e.g. at 120.degree.-180.degree. C., to render the coating insoluble.

Abstract: A solid state pH sensor having an indicator electrode of metal/metal oxide and a reference electrode of metal/metal salt applied to inert, electrical conductors imbedded in an electrically non-conductive substrate, such as a ceramic substrate. The sensing portion of the sensor preferably has a coating of an annealed perfluorocarbon copolymer. Alternatively, the indicator or reference electrodes may be formed on separate electrically non-conductive substrates with each having an inert electrical conductor imbedded therein. These indicator or reference electrodes may be utilized with each other or with prior art electrodes.

Abstract: A sensor which may be immersed in a fluid to measure the pH and the ORP potential of the fluid is taught. The sensor has three solid state electrodes, a pH sensing electrode, a reference electrode and an ORP potential sensing electrode, which extend from a fluid-tight enclosure. The enclosure further contains a display means for indicating the pH measurement and the ORP potential measurement.

Abstract: A solid state pH sensor having an indicator electrode of metal/metal oxide and a reference electrode of metal/metal salt applied to electrically conductive conductors, such as electrically conductive cermet conductors and electrically conductive metal pins, imbedded in an electrically non-conductive substrate, such as electrically non-conductive ceramic substrates including S-glass substrates. The sensing portion of the sensor preferably has a coating of an annealed perfluorocarbon copolymer. Alternatively, the indicator or reference electrodes may be formed on separate electrically non-conductive substrates with each having an electrically conductive conductor imbedded therein. These indicator or reference electrodes may be utilized with each other or with prior art indicator or reference electrodes.

Abstract: A passive metal is coated with a perfluorocarbon copolymer cation-exchange polymer and subsequently annealed. The annealed polymer coating acts as a barrier to anions which attack and breakdown the passivity mechanism of such passive metals, thereby protecting the passive metals against localized corrosion, such as crevice or piting corrosion, caused by anionic attack.

Abstract: A solid state reference electrode comprising a metal/metal salt electrode, an immobilized electrolyte in contact with the metal salt, and a perfluorocarbon copolymer coating on the immobilized electrolyte to prevent migration of the electrolyte away from the electrode.

Abstract: A solid state reference electrode stable in the presence of oxygen having an electrically conductive material in contact with substituted ferrocene/ferrocenium ions.

Abstract: A junction-type metal/metal oxide solid state indicator electrode wherein the sensing portion of the electrode is coated with a perfluorocarbon copolymer, and a pH sensor made of the indicator electrode and a reference electrode.