Patents by Inventor Patrick Rey

Patrick Rey has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11365169
    Abstract: A method for preparing a compound of formula (I) in which R1 is selected from H and alkyls, R2 is selected from H, alkyls, OR? where R? is selected from alkyls, silyls, CO-alkyl, R3 is selected from the acyl groups of the CO(R?) type, and the CO(OR?), CO(NR?R??), PO(OR?)(OR??), PO(OR?)(R??) groups where R? and R??, independently of each other, are selected from H and alkyls, R represents a C(R4)?C(R5)(R6) group where R4, R5 and R6, independently of each other, are selected from H, linear or cyclic alkyls and alkenyls, aryls, alkylaryls, or R4 and R5 together form a saturated or unsaturated, substituted or unsubstituted ring, from a compound of formula (II) or a compound of formula (III) in which, R, R1, R2 and R3 have the above definition.
    Type: Grant
    Filed: August 19, 2019
    Date of Patent: June 21, 2022
    Inventors: Patrick Rey, Robert Huet, Jean-Michel Joerger, Vivien Henryon
  • Patent number: 11220474
    Abstract: A method for preparing dehydro-cyclofarnesal from dehydro-farnesal by cyclization in the presence of an acid may include the dehydro-farnesal being obtained from the farnesal by dehydrogenation and may further includes the cyclization being carried out in the presence of an acid selected from Lewis acids, Bronstedt acids, and zeolites. The synthesis of vitamin A using this method further includes the conversion of dehydro-cyclofarnesal into vitamin A.
    Type: Grant
    Filed: August 19, 2019
    Date of Patent: January 11, 2022
    Assignee: ADISSEO FRANCE S.A.S.
    Inventors: Patrick Rey, Robert Huet, Sylvain Aubry, Vivien Henryon
  • Publication number: 20210309596
    Abstract: A method for preparing dehydro-cyclofarnesal from dehydro-farnesal by cyclization in the presence of an acid may include the dehydro-farnesal being obtained from the farnesal by dehydrogenation and may further includes the cyclization being carried out in the presence of an acid selected from Lewis acids, Bronstedt acids, and zeolites. The synthesis of vitamin A using this method further includes the conversion of dehydro-cyclofarnesal into vitamin A.
    Type: Application
    Filed: August 19, 2019
    Publication date: October 7, 2021
    Inventors: Patrick REY, Robert HUET, Sylvain AUBRY, Vivien HENRYON
  • Publication number: 20210309597
    Abstract: A method for preparing a compound of formula (I) in which R1 is selected from H and alkyls, R2 is selected from H, alkyls, OR? where R? is selected from alkyls, silyls, CO-alkyl, R3 is selected from the acyl groups of the CO(R?) type, and the CO(OR?), CO(NR?R??), PO(OR?)(OR??), PO(OR?)(R??) groups where R? and R??, independently of each other, are selected from H and alkyls, R represents a C(R4)?C(R5)(R6) group where R4, R5 and R6, independently of each other, are selected from H, linear or cyclic alkyls and alkenyls, aryls, alkylaryls, or R4 and R5 together form a saturated or unsaturated, substituted or unsubstituted ring, from a compound of formula (II) or a compound of formula (ill) in which, R, R1, R2 and R3 have the above definition.
    Type: Application
    Filed: August 19, 2019
    Publication date: October 7, 2021
    Inventors: Patrick REY, Robert HUET, Jean-Michel JOERGER, Vivien HENRYON
  • Publication number: 20200283387
    Abstract: The invention relates to a method for preparing a compound (I) or one of the salts thereof, and the uses of said method, R1OOC—C(?X)—CHR2R3(I), wherein X is selected among O; N—R?, wherein R? is H or a C1-C6 alkyl; and N—OR? wherein R? is H, or a C1-C6 alkyl or an alkylaryl; R1 is H or a C1-C6 alkyl group; R2 is H, a C1-C6 alkyl, or an alkylaryl; and R3 is CH2SR4 or CH2SeR4, where R4 is H or a C1-C6 alkyl from a compound (II), or one of the salts thereof, R1OOC—C(?X)—CHR2R5 and R5 is H or COOR6, where R6 is H or a C1-C6 alkyl, said method being carried out in the presence of a compound (III) CH2(Y)(Z).
    Type: Application
    Filed: January 17, 2017
    Publication date: September 10, 2020
    Inventors: Robert HUET, Vivien HENRYON, Jérôme MONBRUN, Etienne AIRIAU, Sylvain AUBRY, Patrick REY
  • Patent number: 10494335
    Abstract: The invention concerns a continuous process for manufacturing methionine by alkaline hydrolysis of methionine hydantoin in aqueous phase, removing NH3 and CO2 of the hydrolysis medium, and neutralizing the obtained methioninate salt, according to which, after removal of NH3 and CO2, the hydrolysis reaction medium is concentrated to precipitate Na2CO3, said Na2CO3 being separated then recycled for alkaline hydrolysis, the latter being carried out in the presence of NaOH and Na2CO3.
    Type: Grant
    Filed: April 15, 2016
    Date of Patent: December 3, 2019
    Assignee: ADISSEO FRANCE S.A.S.
    Inventors: Nicolas Capelle, Patrick Rey
  • Patent number: 10442760
    Abstract: The invention concerns a synthesis process of a compound of the following formula (I) or one of the salts thereof, wherein R represents a COOH, CH2OH or CHO group, comprising the step according to which the but-3-ene-1,2-diol (BDO) is subjected to an oxidation in the presence of a catalyst, said catalyst comprising an active phase based on at least one noble metal selected from palladium, gold, silver, platinum, rhodium, osmium, ruthenium and iridium, and a support containing alkaline sites. The invention also concerns the application of this reaction to the preparation of bioavailable compounds of methionine used, in particular, in animal nutrition.
    Type: Grant
    Filed: December 7, 2015
    Date of Patent: October 15, 2019
    Assignee: ADISSEO FRANCE S.A.S.
    Inventors: Patrick Rey, Virginie Belliere-Baca, Franck Dumeignil, Fabien Grasset
  • Patent number: 10071937
    Abstract: The invention relates to a method for preparing an olefine, a diene or a polyene, by catalytic conversion of at least one alcohol having a carbon chain of at least three carbon atoms and different from propan-2-ol, in the presence of at least one catalyst based of at least one phosphate of a metal or several metals M, M being chosen from among the 15 lanthanides (Lanthanum, Cerium, Praseodymium, Neodymium, Promethium, Samarium, Europium, Gadolinium, Terbium, Dysprosium, Holmium, Erbium, Thulium, Ytterbium, Lutetium), Yttrium, Scandium and Boron, and the applications of this method.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: September 11, 2018
    Assignees: ADISSEO FRANCE S.A.S, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE CLAUDE BERNARD
    Inventors: Jean-Marc Millet, Virginie Belliere-Baca, Thi Tuyet Nhung Nguyen, Robert Huet, Patrick Rey, Pavel Afanasiev
  • Publication number: 20180111899
    Abstract: The invention concerns a continuous process for manufacturing methionine by alkaline hydrolysis of methionine hydantoin in aqueous phase, removing NH3 and CO2 of the hydrolysis medium, and neutralizing the obtained methioninate salt, according to which, after removal of NH3 and CO2, the hydrolysis reaction medium is concentrated to precipitate Na2CO3, said Na2CO3 being separated then recycled for alkaline hydrolysis, the latter being carried out in the presence of NaOH and Na2CO3.
    Type: Application
    Filed: April 15, 2016
    Publication date: April 26, 2018
    Inventors: Nicolas CAPELLE, Patrick REY
  • Publication number: 20170342029
    Abstract: The invention concerns a synthesis process of a compound of the following formula (I) or one of the salts thereof, wherein R represents a COOH, CH2OH or CHO group, comprising the step according to which the but-3-ene-1,2-diol (BDO) is subjected to an oxidation in the presence of a catalyst, said catalyst comprising an active phase based on at least one noble metal selected from palladium, gold, silver, platinum, rhodium, osmium, ruthenium and iridium, and a support containing alkaline sites. The invention also concerns the application of this reaction to the preparation of bioavailable compounds of methionine used, in particular, in animal nutrition.
    Type: Application
    Filed: December 7, 2015
    Publication date: November 30, 2017
    Inventors: Patrick REY, Virginie BELLIERE-BACA, Franck DUMEIGNIL, Fabien GRASSET
  • Publication number: 20150361007
    Abstract: The invention relates to a method for preparing an olefine, a diene or a polyene, by catalytic conversion of at least one alcohol having a carbon chain of at least three carbon atoms and different from propan-2-ol, in the presence of at least one catalyst based of at least one phosphate of a metal or several metals M, M being chosen from among the 15 lanthanides (Lanthanum, Cerium, Praseodymium, Neodymium, Promethium, Samarium, Europium, Gadolinium, Terbium, Dysprosium, Holmium, Erbium, Thulium, Ytterbium, Lutetium), Yttrium, Scandium and Boron, and the applications of this method.
    Type: Application
    Filed: February 4, 2014
    Publication date: December 17, 2015
    Inventors: Jean-Marc MILLET, Virginie BELLIERE-BACA, Thi Tuyet Nhung NGUYEN, Robert HUET, Patrick REY, Pavel AFANASIEV
  • Patent number: 9187395
    Abstract: The disclosure concerns a method for preparing acrolein from glycerol, according to which a dehydration of the glycerol is carried out in the presence of a catalyst MWOA, wherein MWO represents a mixture of simple oxides and/or mixed oxides of tungsten and at least one metal M selected among zirconium, silicon, titanium, aluminium and yttrium, and A represents one or several Lewis base(s), one said Lewis base being of the formula B(R1)p(R2)q(R3)r, wherein B is an element selected among C, S, P, O, N and halides, R1, R2 and R3 represent, independently of each other, H, a C1-C6 alkyl group, O, OH or OR wherein R represents a C1-C6 alkyl group, and the sum of p, q and r varies from 0 to 4.
    Type: Grant
    Filed: October 29, 2013
    Date of Patent: November 17, 2015
    Assignees: ADISSEO FRANCE S.A.S., CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE CLAUDE BERNARD
    Inventors: Raja Znaiguia, Jean-Marc Millet, Stéphane Loridant, Patrick Rey
  • Publication number: 20150239815
    Abstract: The disclosure concerns a method for preparing acrolein from glycerol, according to which a dehydration of the glycerol is carried out in the presence of a catalyst MWOA, wherein MWO represents a mixture of simple oxides and/or mixed oxides of tungsten and at least one metal M selected among zirconium, silicon, titanium, aluminium and yttrium, and A represents one or several Lewis base(s), one said Lewis base being of the formula B(R1)p(R2)q(R3)r, wherein B is an element selected among C, S, P, O, N and halides, R1, R2 and R3 represent, independently of each other, H, a C1-C6 alkyl group, O, OH or OR wherein R represents a C1-C6 alkyl group, and the sum of p, q and r varies from 0 to 4.
    Type: Application
    Filed: October 29, 2013
    Publication date: August 27, 2015
    Inventors: Raja Znaiguia, Jean-Marc Millet, Stéphane Loridant, Patrick Rey
  • Patent number: 8962884
    Abstract: The invention concerns a method for preparing a complex of an acid chosen from among methionine, 2-hydroxy-4-methylthiobutanoic acid (HMTBA) and lactic acid, and of at least one metal, starting from said acid and a mineral metal source, wherein the acid is caused to react with the mineral metal source in an extruder.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: February 24, 2015
    Assignee: Adisseo Ireland Limited
    Inventors: Jean-Claude Le Thiesse, Patrick Rey, Vivien Henryon
  • Publication number: 20130172617
    Abstract: The invention concerns a method for preparing a complex of an acid chosen from among methionine, 2-hydroxy-4-methylthiobutanoic acid (HMTBA) and lactic acid, and of at least one metal, starting from said acid and a mineral metal source, wherein the acid is caused to react with the mineral metal source in an extruder.
    Type: Application
    Filed: September 21, 2011
    Publication date: July 4, 2013
    Applicant: ADISSEO IRELAND LIMITED
    Inventors: Jean-Claude Le Thiesse, Patrick Rey, Vivien Henryon
  • Publication number: 20100178380
    Abstract: The invention relates to a process for preparing 2-oxo-4-methylthiobutyric acid (I), its salts and its derivatives in which R represents a group chosen from COOH, COOR?, NH2, NHR? or NR?R?, where R? and R? are chosen, independently of one another, from the group of linear or branched alkyl radicals having from 1 to 12 carbon atoms and cycloalkyl radicals having from 3 to 12 carbon atoms, according to which process but-3-ene-1,2-diol (II) is catalytically and selectively oxidized to give 2-oxobut-3-enoic acid (III) and methyl mercaptan is selectively condensed with 2-oxobut-3-enoic acid (III). 2-Oxo-4-methylthiobutyric acid (I), its salts and its derivatives are used as food supplement, in particular in animal nutrition.
    Type: Application
    Filed: December 30, 2009
    Publication date: July 15, 2010
    Applicant: ADISSEO IRELAND LIMITED
    Inventors: Patrick Rey, Gilbert Blanchard
  • Patent number: 7662997
    Abstract: The invention relates to a process for preparing 2-oxo-4-methylthiobutyric acid (I), its salts and its derivatives in which R represents a group chosen from COOH, COOR?, NH2, NHR? or NR?R?, where R? and R? are chosen, independently of one another, from the group of linear or branched alkyl radicals having from 1 to 12 carbon atoms and cycloalkyl radicals having from 3 to 12 carbon atoms, according to which process but-3-ene-1,2-diol (II) is catalytically and selectively oxidized to give 2-oxobut-3-enoic acid (III) and methyl mercaptan is selectively condensed with 2-oxobut-3-enoic acid (III). 2-Oxo-4-methylthiobutyric acid (I), its salts and its derivatives are used as food supplement, in particular in animal nutrition.
    Type: Grant
    Filed: December 29, 2005
    Date of Patent: February 16, 2010
    Assignee: Adisseo Ireland Limited
    Inventors: Patrick Rey, Gilbert Blanchard
  • Patent number: 7531066
    Abstract: A process for purifying an aqueous solution to obtain purified gaseous acrolein by introducing the aqueous solution into a distillation column equipped at its base with at least one boiler and at its top with at least one condenser, withdrawing a liquid mixture essentially containing water at the base of the distillation column, withdrawing a gas essentially containing acrolein and water at the top of the distillation column, cooling the gas mixture withdrawn at the top of the distillation column in the condenser, to a temperature which makes it possible to obtain, on the one hand, an aqueous condensate and, on the other hand, an acrolein-rich gas mixture, and withdrawing the acrolein-rich gas mixture.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: May 12, 2009
    Assignee: Adisseo Ireland Ltd.
    Inventors: Georges Gros, Patrick Rey, Michel Garrait
  • Publication number: 20080069920
    Abstract: The invention relates to a process for preparing 2-oxo-4-methylthiobutyric acid (I), its salts and its derivatives in which R represents a group chosen from COOH, COOR?, NH2, NHR? or NR?R?, where R? and R? are chosen, independently of one another, from the group of linear or branched alkyl radicals having from 1 to 12 carbon atoms and cycloalkyl radicals having from 3 to 12 carbon atoms, according to which process but-3-ene-1,2-diol (II) is catalytically and selectively oxidized to give 2-oxobut-3-enoic acid (III) and methyl mercaptan is selectively condensed with 2-oxobut-3-enoic acid (III). 2-Oxo-4-methylthiobutyric acid (I), its salts and its derivatives are used as food supplement, in particular in animal nutrition.
    Type: Application
    Filed: December 29, 2005
    Publication date: March 20, 2008
    Applicant: ADISSEO IRELAND LIMITED
    Inventors: Patrick Rey, Gilbert Blanchard
  • Patent number: 7256315
    Abstract: Process for the Production of 3-methylthiopropanal. A process for the production of 3-methylthiopropanal which reacting reaction medium comprising methyl mercaptan and acrolein in the presence of a catalyst comprising an organic base characterised in that the organic base is a N-alkyl morpholine compound.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: August 14, 2007
    Assignee: Adisseo Ireland Ltd.
    Inventor: Patrick Rey