Patents by Inventor Patrick Terence McGrail

Patrick Terence McGrail has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11492454
    Abstract: A material susceptible to dielectric heating has a base polymeric thermoplastic material (1) and a dielectric heating susceptor (2, 3) which increases susceptibility to heating by irradiation with electromagnetic, for example RF or microwave, radiation. The dielectric heating susceptor has a polymeric material (2) such as PVDF which is different from the base polymeric material and has a higher dielectric loss factor than the base polymeric material. The dielectric heating susceptor also comprises electrically polarisable entities such as carbon black dispersed within the base polymeric material without forming a conductive network. The two susceptor materials in combination with the base polymer are particularly effective together at improving susceptibility to electromagnetic radiation heating of the whole material.
    Type: Grant
    Filed: April 21, 2016
    Date of Patent: November 8, 2022
    Assignee: UNIVERSITY OF LIMERICK
    Inventors: Patrick Terence McGrail, Dipa Roy, Ananda Roy, Richard Hanly, Walter Stanley
  • Publication number: 20220195631
    Abstract: Carbon fibre precursors for use in the formation of carbon fibre materials. The carbon fibre precursors comprise fibres of polymeric material which have a coating layer thereon, the coating layer comprising a material susceptible to dielectric heating, for example carbon nanotubes. The carbon fibre precursors may be suitable for forming into carbon fibres using a dielectric heating step, despite the fibres of polymeric material not being susceptible to dielectric heating, without adversely affecting the structure and physical properties of the main body of the carbon fibre so formed. A method of preparing a carbon fibre precursor for a carbon fibre formation process and a method forming a carbon fibre are also disclosed.
    Type: Application
    Filed: May 15, 2021
    Publication date: June 23, 2022
    Inventors: Maurice N. COLLINS, Mario Culebras RUBIO, Patrick Terence MCGRAIL
  • Patent number: 10358534
    Abstract: A method for making engineered crosslinked thermoplastic particles, which are useful for interlaminar toughening of prepregs and composite materials.
    Type: Grant
    Filed: December 27, 2016
    Date of Patent: July 23, 2019
    Assignee: CYTEC TECHNOLOGY CORP.
    Inventors: Alexandre A. Baidak, Patrick Terence McGrail
  • Patent number: 9963563
    Abstract: The embodiments of the present disclosure present systems and methods for the reversible solubilization of (aryl ether ketones) (PAEKs). A thioacetalization process is employed to modify the PAEKs into poly (aryl ether thioacetals) which, unlike PAEKs, are substantially soluble in common solvents. This modification allowing selected analysis techniques to be more easily performed on PAEKs, such as gel permeation chromatography. The thioacetalization may be reversed through a deprotection reaction to recover the original PAEK without substantial degradation, allowing for non-destructive characterization of the PAEK. Advantageously, the thioacetalization process is generally applicable to a broad range of PAEKs, unlike presently known methods of solubilizing PAEKs. Solubilization of PAEKs further expands the utility of the PAEKs, opening up additional routes to chemical modification of PAEKs, as well as allowing for the possibility of processing PAEKs from solution.
    Type: Grant
    Filed: October 3, 2017
    Date of Patent: May 8, 2018
    Assignee: CYTEC TECHNOLOGY CORP.
    Inventors: Howard Matthew Colquhoun, Patrick Terence McGrail, Francois Pierre Vincent Paoloni, Philip Hodge, Ioannis Manolakis, Paul Mark Cross
  • Publication number: 20180030227
    Abstract: The embodiments of the present disclosure present systems and methods for the reversible solubilization of (aryl ether ketones) (PAEKs). A thioacetalization process is employed to modify the PAEKs into poly (aryl ether thioacetals) which, unlike PAEKs, are substantially soluble in common solvents. This modification allowing selected analysis techniques to be more easily performed on PAEKs, such as gel permeation chromatography. The thioacetalization may be reversed through a deprotection reaction to recover the original PAEK without substantial degradation, allowing for non-destructive characterization of the PAEK. Advantageously, the thioacetalization process is generally applicable to a broad range of PAEKs, unlike presently known methods of solubilizing PAEKs. Solubilization of PAEKs further expands the utility of the PAEKs, opening up additional routes to chemical modification of PAEKs, as well as allowing for the possibility of processing PAEKs from solution.
    Type: Application
    Filed: October 3, 2017
    Publication date: February 1, 2018
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Howard Matthew Colquhoun, Patrick Terence McGrail, Francois Pierre Vincent Paoloni, Philip Hodge, Ioannis Manolakis, Paul Mark Cross
  • Patent number: 9828478
    Abstract: A method of forming a polymer matrix composite using a soluble derivative of a poly (aryl ether ketone) (PAEK). The method includes mixing a starting PAEK polymer with a solvent and an acid, said solvent being selected from a group consisting of diethylether, tetrahydrofuran (THF), dioxin, and chlorinated solvents; reacting the PAEK mixture with a Lewis acid and a thiol compound in amounts effective to form a poly (aryl ether thioacetal) compound which comprises at least one thioacetal group; and impregnating a plurality of fibers in a solution comprising said poly (aryl ether thioacetal) compound.
    Type: Grant
    Filed: October 8, 2015
    Date of Patent: November 28, 2017
    Assignee: CYTEC TECHNOLOGY CORP.
    Inventors: Howard Matthew Colquhoun, Patrick Terence McGrail, Francois Pierre Vincent Paoloni, Philip Hodge, Ioannis Manolakis, Paul Mark Cross
  • Publication number: 20170121470
    Abstract: A method for making engineered crosslinked thermoplastic particles, which are useful for interlaminar toughening of prepregs and composite materials.
    Type: Application
    Filed: December 27, 2016
    Publication date: May 4, 2017
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Alexandre A. BAIDAK, Patrick Terence MCGRAIL
  • Patent number: 9567426
    Abstract: Engineered crosslinked thermoplastic particles are useful for interlaminar toughening of pre-pregs and composite materials.
    Type: Grant
    Filed: May 26, 2010
    Date of Patent: February 14, 2017
    Assignee: Cytec Technology Corp.
    Inventors: Alexandre A. Baidak, Patrick Terence McGrail
  • Publication number: 20160075840
    Abstract: A method of forming a polymer matrix composite using a soluble derivative of a poly (aryl ether ketone) (PAEK). The method includes mixing a starting PAEK polymer with a solvent and an acid, said solvent being selected from a group consisting of diethylether, tetrahydrofuran (THF), dioxin, and chlorinated solvents; reacting the PAEK mixture with a Lewis acid and a thiol compound in amounts effective to form a poly (aryl ether thioacetal) compound which comprises at least one thioacetal group; and impregnating a plurality of fibers in a solution comprising said poly (aryl ether thioacetal) compound.
    Type: Application
    Filed: October 8, 2015
    Publication date: March 17, 2016
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Howard Matthew Colquhoun, Patrick Terence McGrail, Francois Pierre Vincent Paoloni, Philip Hodge, Manolakis Ioannis, Paul Mark Cross
  • Publication number: 20160002409
    Abstract: A thermoplastic polymer toughening material in the form of polymeric fibers produced by mixing at least one epoxy curing agent and a thermoplastic polyaromatic polymer to form an admixture, and producing polymeric fibers from the admixture, wherein the thermoplastic polymer toughening material does not include an epoxy resin, and is soluble in an epoxy resin at a temperature lower than a dissolving temperature required by the thermoplastic polymer toughening material without epoxy curing agent.
    Type: Application
    Filed: January 29, 2014
    Publication date: January 7, 2016
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Paul Mark Cross, Richard Thomas Price, Dominique Ponsolle, Patrick Terence McGrail
  • Patent number: 9228083
    Abstract: A thermoplastic polymer toughening material in the form of polymeric fibers produced by mixing at least one epoxy curing agent and a thermoplastic polyaromatic polymer to form an admixture, and producing polymeric fibers from the admixture, wherein the thermoplastic polymer toughening material does not include an epoxy resin, and is soluble in an epoxy resin at a temperature lower than a dissolving temperature required by the thermoplastic polymer toughening material without epoxy curing agent.
    Type: Grant
    Filed: January 29, 2014
    Date of Patent: January 5, 2016
    Assignee: Cytec Technology Corp.
    Inventors: Paul Mark Cross, Richard Thomas Price, Dominique Ponsolle, Patrick Terence McGrail
  • Patent number: 8927662
    Abstract: A resin binder composition for the production of a fiber preform comprising an amount of at least one polyarylether thermoplast resin component and an amount of at least one thermoset resin component in weight ratio 80/20-10/90, in substantial absence of a catalyst which is active at the prevailing preform production temperature, wherein the polyarylether thermoplast has number average molecular weight (Mn) in the range 2,000-20,000, and comprises ether linked phenyl units and ether linked arylsulphone units and reactive end groups, method for producing a fiber preform using the thermally stable binder resin composition, a perform obtained with use of the method and composition, a method for injecting or infusing the preform with curable matrix resin, the curable injected or infused preform resin, a method for curing thereof and a cured composite obtained with the method.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: January 6, 2015
    Assignee: Cytec Technology Corp.
    Inventors: Patrick Terence McGrail, Jeffrey Thomas Carter, Carmelo LoFaro
  • Patent number: 8685871
    Abstract: A toughening agent for use in making composites comprises an epoxy curing agent and a thermoplastic. Compositions, composites that comprise the toughening agent and associated methods of making and using the toughening agent are also disclosed.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: April 1, 2014
    Assignee: Cytec Technology Corp.
    Inventors: Paul Mark Cross, Richard Thomas Price, Dominique Ponsolle, Patrick Terence McGrail
  • Publication number: 20120115388
    Abstract: Embodiments of the invention are directed to carriers providing a primary toughening function and incorporating a secondary toughening agent therein. According to embodiments of the invention, the carrier/agent combination may be used in liquid resin infusion applications. The carrier may be any polymer-based material having a solubility characteristic in a thermosetting resin. The secondary toughening agent may be of a material such as a thermoplastic, a thermoset, a cross-linked thermoset, a rubber, a rubbery-like material or a combination thereof and may be in the form of a particle, a micro-fiber (fibril) or a fibrous network. In some embodiments, the carrier is soluble in the resin while the secondary toughening agent is insoluble in the resin when subjected to a cure cycle.
    Type: Application
    Filed: November 4, 2011
    Publication date: May 10, 2012
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Alexandre A. Baidak, Patrick Terence McGrail, Dominique Ponsolle, Robert Blackburn
  • Publication number: 20110152469
    Abstract: A toughening agent for use in making composites comprises an epoxy curing agent and a thermoplastic. Compositions, composites that comprise the toughening agent and associated methods of making and using the toughening agent are also disclosed.
    Type: Application
    Filed: December 17, 2010
    Publication date: June 23, 2011
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Paul Mark Cross, Richard Thomas Price, Dominique Ponsolle, Patrick Terence McGrail
  • Publication number: 20110040045
    Abstract: The embodiments of the present disclosure present systems and methods for the reversible solubilization of (aryl ether ketones) (PAEKs). A thioacetalization process is employed to modify the PAEKs into poly (aryl ether thioacetals) which, unlike PAEKs, are substantially soluble in common solvents. This modification allowing selected analysis techniques to be more easily performed on PAEKs1 such as gel permeation chromatography. The thioacetalization may be reversed through a deprotection reaction to recover the original PAEK without substantial degradation, allowing for non-destructive characterization of the PAEK. Advantageously, the thioacetalization process is generally applicable to a broad range of PAEKs, unlike presently known methods of solubilizing PAEKs. Solubilization of PAEKs further expands the utility of the PAEKs, opening up additional routes to chemical modification of PAEKs, as well as allowing for the possibility of processing PAEKs from solution.
    Type: Application
    Filed: May 16, 2008
    Publication date: February 17, 2011
    Inventors: Howard Matthew Colquhoun, Francois Pierre Vincent Paoloni, Philip Hodge, Patrick Terence McGrail, Paul Mark Cross
  • Publication number: 20100304118
    Abstract: Engineered crosslinked thermoplastic particles are useful for interlaminar toughening of pre-pregs and composite materials.
    Type: Application
    Filed: May 26, 2010
    Publication date: December 2, 2010
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Alexandre A. BAIDAK, Patrick Terence McGRAIL
  • Publication number: 20090151860
    Abstract: A flexible polymer element for a curable composition wherein the flexible polymer element is in solid phase and adapted to undergo at least partial phase transition to fluid phase on contact with a component of the curable composition in which it is soluble at a temperature which is less than the temperature for substantial onset of gelling and/or curing of the curable composition; a method for the preparation thereof, a support structure or carrier for a curable composition comprising the at least one flexible polymer element together with reinforcing fibres, configurations of support structures and carriers, methods for preparation thereof, a curable composition comprising the at least one flexible polymer element or the support structure or carrier and a curable resin matrix, a kit of parts comprising the components thereof and a method for selection thereof, a method for preparation and curing thereof, and a cured composite or resin body obtained thereby, and known and novel uses thereof.
    Type: Application
    Filed: February 27, 2009
    Publication date: June 18, 2009
    Inventors: Jeffrey Thomas Carter, Carmelo Lo Faro, Robin Kelvin Maskell, Patrick Terence McGrail
  • Patent number: 7192634
    Abstract: A flexible polymer element for a curable composition wherein the flexible polymer element is in solid phase and adapted to undergo at least partial phase transition to fluid phase on contact with a component of the curable composition in which it is soluble at a temperature which is less than the temperature for substantial onset of gelling and/or curing of the curable composition; a method for the preparation thereof, a support structure or carrier for a curable composition comprising the at least one flexible polymer element together with reinforcing fibers, configurations of support structures and carriers, methods for preparation thereof, a curable composition comprising the at least one flexible polymer element or the support structure or carrier and a curable resin matrix, a kit of parts comprising the components thereof and a method for selection thereof, a method for preparation and curing thereof, and a cured composite or resin body obtained thereby, and known and novel uses thereof.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: March 20, 2007
    Assignee: Cytec Technology Corp.
    Inventors: Jeffrey Thomas Carter, Carmelo Lo Faro, Robin Kelvin Maskell, Patrick Terence McGrail
  • Patent number: 7084213
    Abstract: A polymer composition comprising chains of at least one aromatic polymer or a mixture thereof together with at least one chain linking component wherein the at least one aromatic polymer comprises polymer chains of number average molecular weight (Mn) in a first range and characterised by a polymer flow temperature, and having at least one reactive end group, and wherein the at least one chain linking component comprises at least two linking sites, characterised in that a plurality of the polymer chain end groups are adapted to react with the linking sites at chain linking temperature in excess of the polymer flow temperature to form linked polymer chains of number average molecular weight (Mn) in a second range which is in excess of the first range, substantially thermoplastic in nature; process for the preparation thereof; prepreg, composite or shaped product obtained therewith and the use thereof.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: August 1, 2006
    Assignee: Cytec Technology Crop.
    Inventors: Patrick Terence McGrail, Jeffrey Thomas Carter