Abstract: Described herein is an aqueous basecoat material including at least one aqueous polyurethane-polyurea dispersion (PD) with polyurethane-polyurea particles present in the dispersion and having an average particle size of 40 to 2000 nm and a gel fraction of at least 50%, and also including at least one aqueous dispersion (wD) which includes a polymer prepared by a successive radical emulsion polymerization of three different mixtures (A), (B), and (C), of olefinically unsaturated monomers. Also described herein are multicoat paint systems produced using the basecoat materials.

Abstract: A method is disclosed for producing a multicoat paint system on a metallic substrate by producing a basecoat or a plurality of directly successive basecoats directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat. At least one basecoat material used for producing the basecoats includes at least one predispersed mixture including at least one polyamide having an acid number of less than 20 mg KOH/g, at least one polymeric resin different from the polyamide, and also water and at least one organic solvent.

Abstract: Provided herein is a method for producing a multicoat paint system on a metallic substrate by producing a basecoat or a plurality of directly successive basecoats directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat, wherein at least one basecoat material used for producing the basecoats includes at least one aqueous dispersion which includes a polymer whose preparation includes successive radical emulsion polymerization of three mixtures of olefinically unsaturated monomers.

Abstract: Provided herein is a method for producing a multicoat paint system on a metallic substrate by producing a basecoat or a plurality of directly successive basecoats directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat, wherein at least one basecoat material used for producing the basecoats includes at least one aqueous dispersion which includes a polymer whose preparation includes successive radical emulsion polymerization of three mixtures of olefinically unsaturated monomers.

Abstract: Described herein are an aqueous effect pigment paste including at least one effect pigment (a) and at least one polymer (b) which is preparable by successive radical emulsion polymerization of three monomer mixtures (A), (B) and (C) of olefinically unsaturated monomers in water, an aqueous basecoat material which is preparable by admixing the effect pigment paste to at least one aqueous binder-containing component suitable for preparing the basecoat material, a method for producing a multicoat paint system using this basecoat material, and use of the polymer (b) for dispersing effect pigments within an aqueous effect pigment paste.

Abstract: The invention relates to aqueous dispersions comprising multistage-prepared polymers, and also to coating material compositions comprising them, preparable by multistage polymerization of olefinically unsaturated monomers, using an emulsifier and a water-soluble initiator, under conditions of starved feed polymerization, and using particular monomer mixtures in the individual stages. The invention also relates to a pigmented aqueous basecoat material comprising the aqueous dispersion of the invention, to the use of the aqueous dispersion of the invention in aqueous basecoat materials for improving adhesion, to a process for producing a multicoat paint system on a substrate, and to a multicoat paint system produced in accordance with the stated process.

Abstract: Provided herein is a method for producing a multicoat paint system on a metallic substrate by producing a basecoat or a plurality of directly successive basecoats directly on a metallic substrate coated with a cured electrocoat system, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat, wherein at least one basecoat material used for producing the basecoats includes at least one aqueous dispersion which includes a polymer whose preparation includes successive radical emulsion polymerization of three mixtures of olefinically unsaturated monomers.

Abstract: The present invention relates to an aqueous coating composition comprising at least one mixture (M) of at least one polymeric resin (P1) and at least one polymeric resin (P2), different therefrom, where (P1) is a polyamide and (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24-monocarboxylic acid with at least one diol and/or polyol, at least one binder (A) comprising at least one polymeric resin (A1), which is different from the polymeric resins (P1) and (P2), at least one pigment (B), where the polyamide used as polymeric resin (P1) has an acid number <10 mg of KOH per g of polyamide and the mixture (M) is obtainable by dispersing of the polymeric resin (P1) in water or an aqueous medium in the presence of the polymeric resin (P2), to a method for at least partly coating a substrate with a basecoat film by means of the aqueous coating composition, and to a use of the mixture (M) as a rheological assistant in aqueous coating compositions.

Abstract: The present invention relates to an aqueous dispersion (P) comprising at least one polymeric resin (P1) and at least one polymeric resin (P2) different therefrom, where the polymeric resin (P1) is a polyamide and the polymeric resin (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24 monocarboxylic acid with at least one diol and/or polyol, (P) being obtainable by dispersing of (P1) in water or an aqueous medium in the presence of (P2), and where (P1) has an acid number <10 mg of KOH per g of polyamide, and (P) contains at most 25 wt %, based on the total weight of (P), of one or more organic solvents, and also to an aqueous coating composition comprising (P), at least one binder (A) comprising at least one polymeric resin (A1), which is different from the polymeric resins (P1) and (P2), and at least one pigment (B) for at least partly coating a substrate with a basecoat film.

Abstract: The invention relates to aqueous dispersions comprising multistage-prepared polymers, and also to coating material compositions comprising them, preparable by multistage polymerization of olefinically unsaturated monomers, using an emulsifier and a water-soluble initiator, under conditions of starved feed polymerization, and using particular monomer mixtures in the individual stages. The invention also relates to a pigmented aqueous basecoat material comprising the aqueous dispersion of the invention, to the use of the aqueous dispersion of the invention in aqueous basecoat materials for improving adhesion, to a process for producing a multicoat paint system on a substrate, and to a multicoat paint system produced in accordance with the stated process.

Abstract: The present invention relates to an aqueous coating composition comprising at least one mixture (M) of at least one polymeric resin (P1) and at least one polymeric resin (P2), different therefrom, where (P1) is a polyamide and (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24-monocarboxylic acid with at least one diol and/or polyol, at least one binder (A) comprising at least one polymeric resin (A1), which is different from the polymeric resins (P1) and (P2), at least one pigment (B), where the polyamide used as polymeric resin (P1) has an acid number <10 mg of KOH per g of polyamide and the mixture (M) is obtainable by dispersing of the polymeric resin (P1) in water or an aqueous medium in the presence of the polymeric resin (P2), to a method for at least partly coating a substrate with a basecoat film by means of the aqueous coating composition, and to a use of the mixture (M) as a rheological assistant in aqueous coating compositions.

Abstract: The present invention relates to an aqueous dispersion (P) comprising at least one polymeric resin (P1) and at least one polymeric resin (P2) different therefrom, where the polymeric resin (P1) is a polyamide and the polymeric resin (P2) is a polyester which is at least obtainable by reaction of at least one polymerized aliphatic C12-C24 monocarboxylic acid with at least one diol and/or polyol, (P) being obtainable by dispersing of (P1) in water or an aqueous medium in the presence of (P2), and where (P1) has an acid number <10 mg of KOH per g of polyamide, and (P) contains at most 25 wt %, based on the total weight of (P), of one or more organic solvents, and also to an aqueous coating composition comprising (P), at least one binder (A) comprising at least one polymeric resin (A1), which is different from the polymeric resins (P1) and (P2), and at least one pigment (B) for at least partly coating a substrate with a basecoat film.