Abstract: The present invention concerns a two-part curable composition comprising: ?a first part (component A) comprising: —at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s); —a transition metal complex; and —an antioxidant; ?a second part (component B) comprising: —a per-compound; —at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof; provided that the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG1-CH2-EWG2- wherein EWG2 and EWG1 are independently of each other an electron withdrawing group.

Abstract: The present invention belongs to the field of three-dimensional printing methods. It relates to a method for printing a three-dimensional article made of polycyanoacrylate. It also relates to a method for recycling a three-dimensional article made of polycyanoacrylate.

Abstract: The present invention refers to a curable two-part adhesive composition comprising a first part comprising one or more cyanoacrylate monomer(s), one or more (metha)acrylate monomer(s), a per-compound and, optionally, additives to control viscosity and rheology; and a second part comprising: a non-reactive diluent and a transition metal catalyst, and optionally an electron rich initiator for cyanoacrylates. It also relates to a syringe or a cartridge comprising said two-part curable composition, to the use of such composition for bonding substrates, to the use of such composition filling depressions, cracks or holes in a substrate or between substrates to a method for bonding substrates using said composition, and to a repair method for filling depressions, cracks or holes in a substrate or between substrates using said composition.

Abstract: The present invention belongs to the field of three-dimensional printing methods. It relates to a method for printing a three-dimensional article, to a system thereof, to the use thereof and to a three-dimensional printed article manufactured therewith. The present invention relies on the use of a liquid resin comprising cyanoacrylate-based monomers and on the use of acidic inhibitors.

Abstract: The present invention concerns a two-part curable composition comprising: •a first part (component A) comprising: —at least 51% by weight based on the total weight of the first part, of one or more cyanoacrylate monomer(s); —a transition metal complex; and—an antioxidant; •a second part (component B) comprising: —a per-compound; —at least one Michael acceptor M selected from the group consisting of (meth)acrylic monomers, (meth)acrylic functionalized oligomers, (meth)acrylic functionalized resins, and mixtures thereof; provided that the composition comprises (in the first part and/or in the second part) at least one compound C comprising a radical -EWG1-CH2-EWG2- wherein EWG2 and EWG1 are independently of each other an electron withdrawing group.

Abstract: The present invention relates to compositions (self-thermally) curable on demand under the triggering action of UV-visible to near-infrared irradiation of moderate intensity, method of using same for accelerated photopolyaddition of cyclic ether-amine resins or ultrafast dark curing of cyclic ether-amine resins, and articles obtained by such method. The invention also relates to a resin casting, film or coated substrate, and an adhesive layer or bonding agent, comprising acyclic ether-amine resin obtained by an accelerated curing process according to the invention. The invention additionally relates to the use of a composition of the invention for increasing the delamination strength of laminated composite materials.