Patents by Inventor Paul De Kok
Paul De Kok has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 11332638Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.Type: GrantFiled: December 1, 2020Date of Patent: May 17, 2022Assignee: COVESTRO (NETHERLANDS) B.V.Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul de Kok
-
Publication number: 20210087427Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.Type: ApplicationFiled: December 1, 2020Publication date: March 25, 2021Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul de KOK
-
Patent number: 10883015Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.Type: GrantFiled: August 15, 2019Date of Patent: January 5, 2021Assignee: DSM IP ASSETS B.V.Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul de Kok
-
Publication number: 20190367772Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.Type: ApplicationFiled: August 15, 2019Publication date: December 5, 2019Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul de KOK
-
Patent number: 10428237Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.Type: GrantFiled: December 22, 2015Date of Patent: October 1, 2019Assignee: DSM IP ASSETS B.V.Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul De Kok
-
Publication number: 20170362461Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.Type: ApplicationFiled: December 22, 2015Publication date: December 21, 2017Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul DE KOK
-
Patent number: 9631116Abstract: A radiation curable aqueous coating composition having a 85° gloss of ?60 upon drying comprising (A) 10 to 99 wt % of a polyurethane, (B) 1 to 90 wt % of a radiation curable component; (C) 0.1 to 10 wt % of an associative thickener; wherein at least 80 wt % of (A)+(B)+(C) has a particle size greater than 500 nm and wherein the C?C bond concentration of the composition is 0.2 to 5.0 mmol per g of (A)+(B)+(C).Type: GrantFiled: December 23, 2013Date of Patent: April 25, 2017Assignee: DSM IP ASSETS B.V.Inventors: Ilse Van Casteren, Roland Tennebroek, Mario Cornelis Schoondermark, Paul De Kok
-
Publication number: 20150079406Abstract: There is described a process for preparing a Schiff base crosslinkable aqueous dispersion of a polyurethane A (PUD) the process comprising (a) reacting components (1) to (4) as present to form an acidic isocyanate terminated prepolymer that comprises anionic or potentially anionic functional groups thereon; where: (1) component one comprises 10 to 80% by weight of at least one polyisocyanate optionally containing at least one anionic or potentially anionic dispersing group; (2) optional component two comprises up to 15% by weight of at least one isocyanate-reactive polyol containing at least one anionic or potentially anionic dispersing group; (3) component three comprises 15 to 85% by weight of at least one isocyanate reactive polyol other than component two if present, and having a weight average molecular weight greater than or equal to 500 Daltons optionally containing at least one anionic or potentially anionic dispersing group; and (4) optional component four comprises up to 20% by weight of at least onType: ApplicationFiled: April 10, 2013Publication date: March 19, 2015Inventors: Ronald Tennebroek, Roel Johannes Marinus Swaans, Paul De Kok
-
Publication number: 20140114010Abstract: A radiation curable aqueous coating composition having a 85° gloss of ?60 upon drying comprising (A) 10 to 99 wt % of a polyurethane, (B) 1 to 90 wt % of a radiation curable component; (C) 0.1 to 10 wt % of an associative thickener; wherein at least 80 wt % of (A)+(B)+(C) has a particle size greater than 500 nm and wherein the C?C bond concentration of the composition is 0.2 to 5.0 mmol per g of (A)+(B)+(C).Type: ApplicationFiled: December 23, 2013Publication date: April 24, 2014Applicant: DSM IP ASSETS B.V.Inventors: Ilse VAN CASTEREN, Roland TENNEBROEK, Mario Cornelis SCHOONDERMARK, Paul DE KOK
-
Publication number: 20130184396Abstract: A radiation curable aqueous coating composition having a 85° gloss of ?60 upon drying comprising (A) 10 to 99 wt % of a polyurethane, (B) 1 to 90 wt % of a radiation curable component; (C) 0.1 to 10 wt % of an associative thickener; wherein at least 80 wt % of (A)+(B)+(C) has a particle size greater than 500 nm and wherein the C?C bond concentration of the composition is 0.2 to 5.0 mmol per g of (A)+(B)+(C).Type: ApplicationFiled: March 7, 2013Publication date: July 18, 2013Applicant: DSM IP ASSETS B.V.Inventors: Ilse VAN CASTEREN, Roland TENNEBROEK, Mario Cornelis SCHOONDERMARK, Paul DE KOK
-
Publication number: 20120270990Abstract: A radiation curable aqueous coating composition having a 85° gloss of ?60 upon drying comprising (A) 10 to 99 wt % of a polyurethane, (B) 1 to 90 wt % of a radiation curable component; (C) 0.1 to 10 wt % of an associative thickener; wherein at least 80 wt % of (A)+(B)+(C) has a particle size greater than 500 nm and wherein the C?C bond concentration of the composition is 0.2 to 5.0 mmol per g of (A)+(B)+(C).Type: ApplicationFiled: July 3, 2012Publication date: October 25, 2012Applicant: DSM IP Assets B.V.Inventors: Ilse VAN CASTEREN, Roland Tennebroek, Mario Cornelis Schoondermark, Paul De Kok
-
Publication number: 20100144915Abstract: A radiation curable aqueous coating composition having a 85° gloss of ?60 upon drying comprising (A) 10 to 99 wt % of a polyurethane, (B) 1 to 90 wt % of a radiation curable component; (C) 0.1 to 10 wt % of an associative thickener; wherein at least 80 wt % of (A)+(B)+(C) has a particle size greater than 500 nm and wherein the C?C bond concentration of the composition is 0.2 to 5.0 mmol per g of (A)+(B)+(C).Type: ApplicationFiled: February 19, 2008Publication date: June 10, 2010Inventors: Ilse Van Casteren, Roland Tennebroek, Mario Cornelis Schoondermark, Paul De Kok