Patents by Inventor Paul E. McDaniel

Paul E. McDaniel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9234093
    Abstract: A process for preparing a thermoplastic vulcanizate, the process comprising: charging a reactor with an olefinic copolymer rubber, where the olefinic copolymer rubber is characterized by a multimodal molecular weight, an average branching index of greater than 0.8, includes less than 10 parts by weight oil per 100 parts by weight rubber, includes less than 1 parts by weight non-rubber particulate, per 100 parts by weight rubber, and is in the form of granules having a particle size less than 8 mm; charging the reactor, contemporaneously or sequentially with respect to the rubber, with a thermoplastic resin, an oil, and a cure system; melt mixing the rubber, the thermoplastic resin, the oil, and the cure system; and dynamically vulcanizing the rubber.
    Type: Grant
    Filed: March 31, 2008
    Date of Patent: January 12, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria Dolores Ellul, Periagaram S. Ravishankar, Paul E. McDaniel
  • Patent number: 8653197
    Abstract: The disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene. A method of producing the thermoplastic vulcanizate is also disclosed.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: February 18, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
  • Publication number: 20130102721
    Abstract: The disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene. A method of producing the thermoplastic vulcanizate is also disclosed.
    Type: Application
    Filed: April 13, 2012
    Publication date: April 25, 2013
    Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
  • Patent number: 8178625
    Abstract: The instant disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene, wherein the polymer fractions have been polymerized using a Ziegler-Natta catalyst system, wherein the first polymer fraction has a Mooney viscosity of greater than or equal to about 150 ML(1+4@125° C.), and the second polymer fraction has a Mooney viscosity of about 20 ML to about 120 ML; and about 10 phr to about 50 phr of an extender oil.
    Type: Grant
    Filed: August 1, 2006
    Date of Patent: May 15, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
  • Publication number: 20080033089
    Abstract: The instant disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt% of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene, wherein the polymer fractions have been polymerized using a Ziegler-Natta catalyst system, wherein the first polymer fraction has a Mooney viscosity of greater than or equal to about 150 ML(1+4@125° C.), and the second polymer fraction has a Mooney viscosity of about 20 ML to about 120 ML; and about 10 phr to about 50 phr of an extender oil.
    Type: Application
    Filed: August 1, 2006
    Publication date: February 7, 2008
    Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
  • Patent number: 6451915
    Abstract: A thermoplastic elastomer formed by a process comprising the steps of dynamically vulcanizing a rubber within a mixture that includes the rubber, from about 10 to about 80 percent by weight of a thermoplastic resin based upon the total weight of the rubber and the thermoplastic combined, and from about 1 to about 25 percent by weight of a polymeric processing additive based upon the total weight of the rubber and the thermoplastic combined, where the polymeric processing additive is a linear polyolefin resin that has an melt flow rate that is greater than about 1,000 dg/min, a diene-modified polyolefin polymer that has an melt flow rate that is greater than about 1,000 dg/min, from about 0.005 to about 2.00 mole percent polymeric units deriving from dienes, and a viscosity average branching index that is from about 0.4 to about 0.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: September 17, 2002
    Assignees: Advanced Elastomer Systems, L.P., ExxonMobil Chemical Patents, Inc.
    Inventors: Maria D. Ellul, Paul E. McDaniel, Thomas L. Peltier, Jianya Cheng, Patrick Brant, Armenag H. Dekmezian
  • Publication number: 20020128390
    Abstract: A thermoplastic elastomer formed by a process comprising the steps of dynamically vulcanizing a rubber within a mixture that includes the rubber, from about 10 to about 80 percent by weight of a thermoplastic resin based upon the total weight of the rubber and the thermoplastic combined, and from about 1 to about 25 percent by weight of a polymeric processing additive based upon the total weight of the rubber and the thermoplastic combined, where the polymeric processing additive is a linear polyolefin resin that has an melt flow rate that is greater than about 1,000 dg/min, a diene-modified polyolefin polymer that has an melt flow rate that is greater than about 1,000 dg/min, from about 0.005 to about 2.00 mole percent polymeric units deriving from dienes, and a viscosity average branching index that is from about 0.4 to about 0.
    Type: Application
    Filed: December 29, 2000
    Publication date: September 12, 2002
    Inventors: Maria D. Ellul, Paul E. McDaniel, Thomas L. Peltier, Jianya Cheng, Patrick Brant, Armenag H. Dekmezian