Patents by Inventor Paul F. Schubert

Paul F. Schubert has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6989403
    Abstract: A process for regenerating a slurry Fischer-Tropsch catalyst, which needs regeneration, involves de-waxing and drying the catalyst sufficiently to produce a free-flowing catalyst powder that is fluidizable; fluidizing the catalyst powder; treating the catalyst powder with an oxygen treatment; reducing the catalyst powder with a reducing gas to form a reduced catalyst powder; and mixing the reduced catalyst powder with hydrocarbons to form a regenerated, slurry catalyst. The oxidation and reduction steps may be repeated. An oxygen treatment includes using a fixed O2 level with ramped temperatures, fixed temperatures with increased O2 levels, or a combination.
    Type: Grant
    Filed: April 23, 2004
    Date of Patent: January 24, 2006
    Assignee: Syntroleum Corporation
    Inventors: Jui-Hsin R. Huang, Kym Arcuri, Kenneth Agee, Paul F. Schubert
  • Publication number: 20040259963
    Abstract: A process for regenerating a slurry Fischer-Tropsch catalyst, which needs regeneration, involves de-waxing and drying the catalyst sufficiently to produce a free-flowing catalyst powder that is fluidizable; fluidizing the catalyst powder; treating the catalyst powder with an oxygen treatment; reducing the catalyst powder with a reducing gas to form a reduced catalyst powder; and mixing the reduced catalyst powder with hydrocarbons to form a regenerated, slurry catalyst. The oxidation and reduction steps may be repeated. An oxygen treatment includes using a fixed O2 level with ramped temperatures, fixed temperatures with increased O2 levels, or a combination.
    Type: Application
    Filed: April 23, 2004
    Publication date: December 23, 2004
    Inventors: Jui-Hsin R. Huang, Kym Arcuri, Kenneth Agee, Paul F. Schubert
  • Patent number: 6812179
    Abstract: A process for regenerating a slurry Fischer-Tropsch catalyst, which needs regeneration, involves de-waxing and drying the catalyst sufficiently to produce a free-flowing catalyst powder that is fluidizable; fluidizing the catalyst powder; treating the catalyst powder with an oxygen treatment; reducing the catalyst powder with a reducing gas to form a reduced catalyst powder; and mixing the reduced catalyst powder with hydrocarbons to form a regenerated, slurry catalyst. The oxidation and reduction steps may be repeated. An oxygen treatment includes using a fixed O2 level with ramped temperatures, fixed temperatures with increased O2 levels, or a combination.
    Type: Grant
    Filed: April 12, 2002
    Date of Patent: November 2, 2004
    Assignee: Syntroleum Corporation
    Inventors: Jui-Hsin R. Huang, Kenneth L. Agee, Kym B. Arcuri, Paul F. Schubert
  • Publication number: 20020183403
    Abstract: A process for regenerating a slurry Fischer-Tropsch catalyst, which needs regeneration, involves de-waxing and drying the catalyst sufficiently to produce a free-flowing catalyst powder that is fluidizable; fluidizing the catalyst powder; treating the catalyst powder with an oxygen treatment; reducing the catalyst powder with a reducing gas to form a reduced catalyst powder; and mixing the reduced catalyst powder with hydrocarbons to form a regenerated, slurry catalyst. The oxidation and reduction steps may be repeated. An oxygen treatment includes using a fixed O2 level with ramped temperatures, fixed temperatures with increased O2 levels, or a combination.
    Type: Application
    Filed: April 12, 2002
    Publication date: December 5, 2002
    Inventors: Jui-Hsin R. Huang, Kenneth L. Agee, Kym B. Arcuri, Paul F. Schubert
  • Patent number: 5366949
    Abstract: This invention is a catalyst and a process using that catalyst for oxidizing hydrogen bromide to form elemental bromine. The inventive catalyst composition comprises cerium bromide on certain zirconia containing supports. The zirconia support, preferably largely in the baddeleyite phase, stabilizes the cerium bromide catalyst against cerium oxide formation at operating temperatures and gives the catalyst excellent activity at lower temperatures.
    Type: Grant
    Filed: June 4, 1993
    Date of Patent: November 22, 1994
    Assignee: Catalytica, Inc.
    Inventor: Paul F. Schubert
  • Patent number: 5360468
    Abstract: A sulfur absorbent composition having desirable physical properties and comprising zinc oxide and alumina having been treated with a phosphating agent is disclosed. At least a portion of the alumina component of the absorbent composition undergoes a phosphating treatment. The resulting composition is suitable for use in an H.sub.2 S absorption process.
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: November 1, 1994
    Assignee: Phillips Petroleum Company
    Inventor: Paul F. Schubert
  • Patent number: 5358921
    Abstract: Hydrogen sulfide is removed from a fluid stream containing hydrogen sulfide by contacting the fluid stream under suitable absorbing conditions with an absorbing composition consisting essentially of zinc oxide and silica. Additionally, the absorbing composition may contain binders and may be promoted, preferably with nickel oxide.
    Type: Grant
    Filed: May 3, 1993
    Date of Patent: October 25, 1994
    Assignee: Phillips Petroleum Company
    Inventors: Dennis R. Kidd, Gary A. Delzer, Donald H. Kubicek, Paul F. Schubert
  • Patent number: 5248489
    Abstract: Hydrogen sulfide is removed from a fluid stream containing hydrogen sulfide by contacting the fluid stream under suitable absorbing conditions with an absorbing composition consisting essentially of zinc oxide and silica. Additionally, the absorbing composition may contain binders and may be promoted, preferably with nickel oxide.
    Type: Grant
    Filed: April 24, 1992
    Date of Patent: September 28, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Dennis R. Kidd, Gary A. Delzer, Donald H. Kubicek, Paul F. Schubert
  • Patent number: 5237117
    Abstract: Catalyst supports, catalyst systems, methods for the preparation thereof, and dimerization process therewith are provided catalyst supports are extruded from a thick paste of potassium carbonate and water catalyst systems comprise at least one elemental alkali metal deposited on the catalyst support. Optionally, the catalyst system further comprises at least one promoter.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: August 17, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Paul F. Schubert, Ralph E. Bonnell, Norman L. Freeman, Jr., Denton C. Fentress, Kent E. Mitchell, Richard E. Lowery, Dodnald H. Kubicek
  • Patent number: 5206314
    Abstract: A polymerization catalyst useful for the polymerization of olefins is prepared by contacting a metal dihalide compound having a metal selected from Group 2 and Group 12 of the Periodic Table and a transition metal compound which is a hydrocarbyloxide of a transition metal selected from Group 4 and Group 5 to thereby form a first catalyst component; contacting the first catalyst component with at least one organoaluminum precipitating agent to form a solid product; and contacting the solid product with an ester and then an activating agent to form a catalyst. Other aspects of the invention include a catalyst produced by the above described process and a polymerization process employing the thus produced catalyst.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: April 27, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Kent E. Mitchell, Paul F. Schubert, Gil R. Hawley
  • Patent number: 5202298
    Abstract: Catalyst supports, catalyst systems, methods for the preparation thereof, and dimerization process therewith are provided catalyst supports are extruded from a thick paste of potassium carbonate and water catalyst systems comprise at least one elemental alkali metal deposited on the catalyst sypport. Optionally, the catalyst system further comprises at least one promoter.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: April 13, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Paul F. Schubert, Ralph E. Bonnell, Norman L. Freeman, Jr., Denton C. Fentress, Kent E. Mitchell, Richard E. Lowrey, Donald H. Kubicek, Warren M. Ewert
  • Patent number: 5177050
    Abstract: A sulfur absorbent composition having desirable physical properties and comprising zinc oxide and alumina having been treated with a phosphating agent is disclosed. At least a portion of the alumina component of the absorbent composition undergoes a phosphating treatment. The resulting composition is suitable for use in an H.sub.2 S absorption process.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: January 5, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Paul F. Schubert
  • Patent number: 5151401
    Abstract: Impregnated chloride ions are removed from a chloride containing, platinum on zinc aluminate catalyst support in a specific sequence of operations. In the dechlorination steps, the impregnated platinum is first anchored to the zinc aluminate support in a calcining step, and then the calcined catalyst support is washed with a wash medium to remove the corrosive chloride without removing the platinum catalyst.
    Type: Grant
    Filed: January 6, 1992
    Date of Patent: September 29, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Paul F. Schubert, Donald H. Kubicek, Dennis R. Kidd
  • Patent number: 5143706
    Abstract: A method of preparing a novel absorption composition comprising zinc oxide, silica and a fluorine-containing acid by mixing a fluorine-containing acid with zinc oxide and silica followed by an agglomeration step. The novel composition, which can be prepared by the novel method, is utilized by contacting a fluid stream with the novel compositin to remove sulfur from the fluid stream. A further embodiment of the method of preparation involves utilizing a technique for spraying a fluorine-containing acid upon a zinc oxide and slica mixture while mixing the mixture by an inclined rotating disk agglomerator.
    Type: Grant
    Filed: September 13, 1991
    Date of Patent: September 1, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Paul F. Schubert
  • Patent number: 5132483
    Abstract: A process is provided which comprises: (a) contacting at least one olefinic compound with an alkali metal/alkali metal carbonate catalyst system at a temperature below the dimerization temperature range of the dimerization reaction; followed by (b) heating said olefin compound and said alkali metal carbonate catalyst system to a temperature in said dimerization temperature range.
    Type: Grant
    Filed: September 26, 1991
    Date of Patent: July 21, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Paul F. Schubert
  • Patent number: 5108975
    Abstract: Described is a method for preparing a catalyst support material, comprising commercially available silica, by utilizing a fluorine-containing acid. The novel method is utilized to produce a novel composition that has unique physical properties different from those of typical commercially available silica materials. The novel support material has significantly improved values for crush strength and as good or better pore volume than comparable catalyst support materials. Due to these improved physical properties, the novel composition is more durable and longer lived. Furthermore, the greater pore volume of the novel composition provides for enhanced catalytic activity when the formed silica material is utilized as a catalyst support.
    Type: Grant
    Filed: January 28, 1991
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Paul F. Schubert, Donald H. Kubicek
  • Patent number: 5077261
    Abstract: A method of preparing a novel absorption composition comprising zinc oxide, silica and a fluorine-containing acid by mixing a fluorine-containing acid with zinc oxide and silica followed by an agglomeration step. The novel composition, which can be prepared by the novel method, is utilized by contacting a fluid stream with the novel composition to remove sulfur from the fluid stream. A further embodiment of the method of preparation involves utilizing a technique for spraying a fluorine-containing acid upon a zinc oxide and silica mixture while mixing the mixture by an inclined rotating disk agglomerator.
    Type: Grant
    Filed: June 25, 1990
    Date of Patent: December 31, 1991
    Assignee: Phillips Petroleum Company
    Inventor: Paul F. Schubert
  • Patent number: 4196285
    Abstract: Cephamycin C is concentrated and purified by subjecting a fermentation broth which contains Cephamycin C to the following sequence of steps: filtration at acidic pH, passage through a methylene sulfonic acid cation ion exchange resin, washing with an aqueous stream having a low concentration of Cephamycin C, and elution using the above aqueous stream from the previous step, recirculated and maintained at an elevated pH.
    Type: Grant
    Filed: June 28, 1978
    Date of Patent: April 1, 1980
    Assignee: Merck & Co., Inc.
    Inventor: Paul F. Schubert