Abstract: This invention relates to the use of certain amine promoters in processes for surface-treating colloidal silica nanoparticles with selected aromatic aminosilanes, aromatic aminoalkylsilanes, and secondary and tertiary aliphatic aminosilanes. This process provides surface-modified nanoparticle colloidal silica without causing the silica nanoparticles to gel, agglomerate, or aggregate.

Abstract: This invention relates to compositions comprising blends of acrylic add polymers and/or ethylene acrylic add copolymers and colloidal silica modified with certain aromatic aminosilanes, aromatic aminoalkylsilanes, alkenyl aminoalkylsilanes, secondary or tertiary aliphatic aminosilanes. These compositions can provide improved properties such loss modulus, storage modulus, creep resistance, and wear resistance, without sacrificing optical clarity.

Abstract: A fluoropolymer composite comprising at least one fluoropolymer and particulate filler material is formed using a slurry process, in which the particulate filler material is first dispersed in a polar organic liquid, which is then combined with a suitable particulate fluoropolymer. The combination is dried to form a composite powder material. The composite powder material, with optional addition of another fluoropolymer, is processed to form a fluoropolymer composite body. The process can be carried out with either melt-processible or non-melt-processible fluoropolymers.

Abstract: This invention relates to compositions comprising blends of acrylic add polymers and/or ethylene acrylic add copolymers and colloidal silica modified with certain aromatic aminosilanes, aromatic aminoalkylsilanes, alkenyl aminoalkylsilanes, secondary or tertiary aliphatic aminosilanes. These compositions can provide improved properties such loss modulus, storage modulus, creep resistance, and wear resistance, without sacrificing optical clarity.

Abstract: This invention relates to the use of certain amine promoters in processes for surface-treating colloidal silica nanoparticles with selected aromatic aminosilanes, aromatic aminoalkylsilanes, and secondary and tertiary aliphatic aminosilanes. This process provides surface-modified nanoparticle colloidal silica without causing the silica nanoparticles to gel, agglomerate, or aggregate.

Abstract: This invention relates to processes in which certain aminosilanes are used to surface-modify colloidal silica nanoparticles, while reducing or virtually eliminating the propensity of the silica nanoparticles to gel, agglomerate, or aggregate. The surface-modified colloidal silica nanoparticles can be readily dispersed in polymers to provide nanocomposites with one or more enhanced, desirable properties.

Abstract: For a continuous process for preparing rare-earth doped Group 2 or Group 3 metal fluoride nanoparticles comprising a confluence of feed streams of reagents, a method is provided for controlling particle size by adjustment in the flow rate of the streams.

Abstract: A low refractive index composition is provided comprising the reaction product of: (i) a fluoroelastomer having at least one cure site; (ii) a multiolefinic crosslinker; (iii) a free radical polymerization initiator; (iv) a nanosilica composite comprising: (iv-a) a plurality of nanosilica particles, and (iv-b) at least one of a hydrolysis and condensation product of an oxysilane having a carbon-carbon double bond, wherein the at least one of a hydrolysis and condensation product is formed by contacting, in the presence of an organic acid and a lower alkyl alcohol, the oxysilane with from about 3 to about 9 moles of water per mole of hydrolyzable functional group bonded to the silicon of the oxysilane. The present invention further provides abrasion resistant anti-reflective coatings formed from these low refractive index compositions and methods for forming abrasion resistant anti-reflective coatings for optical display substrates from these low refractive index compositions.

Abstract: A method wherein an aqueous solution of a fluoride, an aqueous solution of a Group 2 or Group 3 metal salt, and an aqueous solution of a rare-earth metal dopant are combined in a plurality of continuous feed streams to form a series of precipitates of a rare-earth doped Group 2 or Group 3 metal fluoride, and wherein the member of the series differ by the concentration of the associated rare-earth dopant cation in the feed stream, and wherein the series so prepared defines the threshold concentration range above which operation of the process results in a minimization of the particle size variability caused by small perturbations in the concentration of the rare-earth dopant.

Abstract: A method wherein an aqueous solution of a fluoride, an aqueous solution of a Group 2 or Group 3 metal salt, and an aqueous solution of a rare-earth metal dopant are combined to form a precipitate of a rare-earth doped Group 2 or Group 3 metal fluoride, and wherein increasing the concentration of the rare-earth dopant cation increases the resulting particle size, and wherein decreasing the concentration of the rare-earth dopant cation decreases the particle size.

Abstract: This invention is directed to fluorinated acrylate compositions, which are suitable for use as low shrinkage, low absorbance refractive index matching adhesives for use in “pig-tailing” polymeric integrated waveguides to optical fiber bundles.

Abstract: Optical articles, such as displays, optical lenses, windows, optical polarizers and transparent films are made as a composite structure comprising a substrate and an anti-reflective coating applied to the substrate. The anti-reflective coating comprises: A) a fluoroelastomer having cures sites selected from the group consisting of bromine atoms, chlorine atoms, iodine atoms, non-conjugated dienes, and mixtures of two or more thereof; and B) a non-fluorinated multiolefinic cross linking agent. The surface of the substrate may be treated by simultaneously bombarding the surface with an ionized inert gas, and etching the surface with an ionized reactive gas, so as to improve the adhesion of the coating to the substrate.

Abstract: This invention is directed to fluorinated acrylate compositions, which are suitable for use as low shrinkage, low absorbance refractive index matching adhesives for use in “pig-tailing” polymeric integrated waveguides to optical fiber bundles.

Abstract: This invention is directed to fluorinated acrylate compositions, which are suitable for use as low shrinkage, low absorbance refractive index matching adhesives for use in “pig-tailing” polymeric integrated waveguides to optical fiber bundles.

Abstract: This invention concerns a method for forming ionomers by treatment with ammonium carbonate of copolymers having a substantially fluorinated, but not perfluorinated, polyethylene backbone having pendant groups of fluoroalkoxy sulfonyl fluoride. Ionomers derived therefrom by ion exchange are useful in electrochemical applications such as batteries, fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.

Abstract: This invention concerns a method for forming ionomers by treatment with ammonium carbonate of copolymers having a substantially fluorinated, but not perfluorinated, polyethylene backbone having pendant groups of fluoroalkoxy sulfonyl fluoride. Ionomers derived therefrom by ion exchange are useful in electrochemical applications such as batteries, fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.

Abstract: This invention concerns functional fluorine-containing copolymers compositions and ionomers derived therefrom. The ionomers formed are useful in electrochemical applications such as batteries, fuel cells, in exchange membranes, sensors and the like.

Abstract: This invention concerns functional fluorine-containing copolymers compositions and ionomers derived therefrom. The ionomers formed are useful in electrochemical applications such as batteries, fuel cells, in exchange membranes, sensors and the like.

Abstract: This invention relates to electrolyte solution compositions useful in lithium-ion batteries. These electrolytes feature lower volatility than solutions known in the art while retaining excellent battery performance using graphite based negative electrode active materials.

Abstract: This invention concerns a method for forming ionomers by treatment with ammonium carbonate of copolymers having a substantially fluorinated, but not perfluorinated, polyethylene backbone having pendant groups of fluoroalkoxy sulfonyl fluoride. Ionomers derived therefrom by ion exchange are useful in electrochemical applications such as batteries, fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.