Patents by Inventor Paul Mercando

Paul Mercando has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10683469
    Abstract: A phosphorus-free automatic dishwashing detergent composition comprising 2.5 to 8 wt % of a first polymer comprising polymerized units of: (i) 55 to 85 wt % of a C3-C6 monoethylenically unsaturated carboxylic acid, (ii) 2 to 30 wt % of a C3-C6 monoethylenically unsaturated dicarboxylic acid and (iii) 2 to 15 wt % of a C5-C12 monoethylenically unsaturated tertiary amine; and having Mw from 2,000 to 100,000.
    Type: Grant
    Filed: September 27, 2016
    Date of Patent: June 16, 2020
    Assignees: Rohm and Haas Company, Union Carbide Corporation
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Publication number: 20200017803
    Abstract: An automatic dishwashing composition is provided including a dispersant polymer blend, comprising: an acrylic acid homopolymer; and a copolymer of acrylic acid and a sulfonated monomer; wherein the blend ratio of the acrylic acid homopolymer to the copolymer of 3:1 to 1:3; and a surfactant, wherein the surfactant is a fatty alcohol alkoxylate of formula I: wherein R1 is a linear or branched, saturated C8-24 alkyl group; R2 is a linear saturated C2-8 alkyl group; m has an average value of 22 to 42; n has an average value of 4 to 12; wherein m+n is an average value of 26 to 54; wherein the fatty alcohol alkoxylate has an average ethyleneoxy unit concentration per molecule, X, of >45 wt %; and, wherein the fatty alcohol alkoxylate has a ratio, Z, equal to X divided by n, wherein the ratio, Z, is <9.5.
    Type: Application
    Filed: March 19, 2019
    Publication date: January 16, 2020
    Inventors: Sara B. Klamo, Edward D. Daugs, Scott Backer, Severine Ferrieux, Paul Mercando, Eric Wasserman
  • Patent number: 10479959
    Abstract: A surfactant for use in an automatic dishwashing composition is provided, wherein the surfactant is a glycidyl ether-capped ethoxylated alcohol as noted in formula I. Wherein R1 is a linear, saturated C8-24 alkyl group, R2 is a linear or branched saturated C6-20 alkyl group, m has an average value of 10 to 50, and n has an average value of >1 to 2. Also provided are automatic dishwashing compositions comprising said surfactant.
    Type: Grant
    Filed: March 20, 2017
    Date of Patent: November 19, 2019
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Marianne P. Creamer, Edward D. Daugs, Severine Ferrieux, Sara B. Klamo, Paul Mercando, Eric P. Wasserman
  • Publication number: 20190292491
    Abstract: An automatic dishwashing detergent composition comprising: (a) 0.5 to 8 wt % of a polymer comprising polymerized units of: (i) 5 to 75 wt % itaconic acid, (ii) 10 to 60 wt % of vinyl acetate; and (iii) 10 to 50 wt % (meth)acrylic acid; and having Mw from 5,000 to 100,000; (b) 2 to 50 wt % of an aminocarboxylate builder; (c) 1 to 10 wt % of a nonionic surfactant; (d) 20 to 75 wt % of carbonate, citrate, silicate or a combination thereof; and (e) 5 to 25 wt % of a bleaching agent.
    Type: Application
    Filed: November 27, 2017
    Publication date: September 26, 2019
    Inventors: Scott Backer, Marianne P. Creamer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Patent number: 10400114
    Abstract: A composition comprising an ethylene (meth)acrylic acid copolymer and an anti-fouling agent is provided. The composition selectively disintegrates in media of different ionic strengths. Also provided is a method of preventing fouling using the composition.
    Type: Grant
    Filed: September 25, 2014
    Date of Patent: September 3, 2019
    Assignee: Rohm and Haas Company
    Inventors: Scott Backer, Afia S. Karikari, Paul Mercando
  • Patent number: 10392585
    Abstract: Provided is a detergent composition and method for reducing filming and spotting in automatic dishwashing systems. The composition comprises: aspartic acid diacetic acid or salt thereof; a dispersant polymer comprising a (meth)acrylic polymer with a Mw from 2000 to 100,000; a builder; and a surfactant.
    Type: Grant
    Filed: February 22, 2016
    Date of Patent: August 27, 2019
    Assignee: Rohm and Haas Company
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando
  • Publication number: 20190218477
    Abstract: An automatic dishwashing composition is provided including a dispersant polymer; a builder; and a surfactant, wherein the surfactant is a fatty alcohol alkoxylate of formula I: wherein R1 is a linear or branched, saturated C8-24 alkyl group; R2 is a linear saturated C2-8 alkyl group; m has an average value of 22 to 42; n has an average value of 4 to 12; wherein m+n is an average value of 26 to 54; wherein the fatty alcohol alkoxylate has an average ethyleneoxy unit concentration per molecule, X, of >45 wt %; and, wherein the fatty alcohol alkoxylate has a ratio, Z, equal to X divided by n, wherein the ratio, Z, is <9.5.
    Type: Application
    Filed: June 5, 2017
    Publication date: July 18, 2019
    Applicants: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Sara B. Klamo, Edward D. Daugs, Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Patent number: 10273398
    Abstract: A wellbore fluid including a peroxide degradable polymer and an encapsulated peroxide source. The peroxide degradable polymer may be a polysaccharide. The peroxide source may include an inorganic peroxide, including zinc and alkaline earth metal peroxides, such as magnesium peroxide. The encapsulating material may be a polymer, including a metal crosslinked acrylic polymer. The release of peroxide, from peroxide sources generally, can be controlled by means of pH such that peroxide source can be activated, and peroxide released, by a change in pH. In a wellbore, this pH change can be effected by using produced fluids to lower the pH of a more basic wellbore fluid.
    Type: Grant
    Filed: July 31, 2014
    Date of Patent: April 30, 2019
    Assignees: Dow Global Technologies LLC
    Inventors: Chun Liu, Carol E. Mohler, Theodore Tysak, Paul Mercando, Kacee B. Ender, Disha Jain
  • Patent number: 10253280
    Abstract: A phosphorus-free automatic dishwashing detergent composition comprising: (a) 0.5 to 10 wt % of a polymer comprising polymerized units of: (i) 65 to 75 wt % (meth)acrylic acid, (ii) 15 to 25 wt % of a monoethylenically unsaturated dicarboxylic acid and (iii) 7 to 13 wt % 2-acrylamido-2-methylpropanesulfonic acid (AMPS); and having Mw from 5,000 to 100,000; (b) 15 to 50 wt % carbonate, (c) 0 to 50 wt % citrate and (d) 10 to 40 wt % of a bleaching agent.
    Type: Grant
    Filed: October 5, 2015
    Date of Patent: April 9, 2019
    Assignees: Rohn and Haas Company, Union Carbide Chemical & Plastics Technology LLC
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Publication number: 20190016993
    Abstract: A surfactant for use in an automatic dishwashing composition is provided, wherein the surfactant is a glycidyl ether-capped ethoxylated alcohol as noted in formula I. Wherein R1 is a linear, saturated C8-24 alkyl group, R2 is a linear or branched saturated C6-20 alkyl group, m has an average value of 10 to 50, and n has an average value of >1 to 2. Also provided are automatic dishwashing compositions comprising said surfactant.
    Type: Application
    Filed: March 20, 2017
    Publication date: January 17, 2019
    Inventors: Marianne P Creamer, Edward D. Daugs, Severine Ferrieux, Sara B. Klamo, Paul Mercando, Eric P. Wasserman
  • Patent number: 10144906
    Abstract: A phosphorus-free automatic dishwashing detergent composition comprising: (a) 0.5 to 8 wt % of a first polymer comprising polymerized units of: (i) 60 to 82 wt % (meth)acrylic acid, (ii) 10 to 30 wt % of a monoethylenically unsaturated dicarboxylic acid and (iii) 8 to 25 wt % 2-acrylamido-2-methylpropanesulfonic acid (AMPS); and having Mw from 5,000 to 100,000; (b) 0.5 to 8 wt % of a second polymer comprising polymerized units of: (i) 60 to 95 wt % (meth)acrylic acid, (ii) 5 to 40 wt % 2-acrylamido-2-methylpropanesulfonic acid (AMPS); and having Mw from 5,000 to 100,000; (c) 15 to 50 wt % carbonate, (d) 5 to 50 wt % citrate and (e) 10 to 30 wt % of a bleaching agent.
    Type: Grant
    Filed: October 7, 2015
    Date of Patent: December 4, 2018
    Assignees: Rohm and Haas Company, Union Carbide Chemicals & Plastics Technology LLC
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Publication number: 20180291313
    Abstract: A phosphorus-free automatic dishwashing detergent composition comprising 2.5 to 8 wt % of a first polymer comprising polymerized units of: (i) 55 to 85 wt % of a C3-C6 monoethylenically unsaturated carboxylic acid, (ii) 2 to 30 wt % of a C3-C6 monoethylenically unsaturated dicarboxylic acid and (iii) 2 to 15 wt % of a C5-C12 monoethylenically unsaturated tertiary amine; and having Mw from 2,000 to 100,000.
    Type: Application
    Filed: September 27, 2016
    Publication date: October 11, 2018
    Applicants: Rohm and Haas Company, Union Carbide Chemicals & Plastics Technology LLC
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Publication number: 20180265814
    Abstract: Provided is a detergent composition and method for reducing filming and spotting in automatic dishwashing systems. The composition comprises: aspartic acid diacetic acid or salt thereof; a dispersant polymer comprising a (meth)acrylic polymer with a Mw from 2000 to 100,000; a builder; and a surfactant.
    Type: Application
    Filed: February 22, 2016
    Publication date: September 20, 2018
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando
  • Patent number: 10047329
    Abstract: A composition comprising an ethylene (mem)acrylic acid copolymer and a crosslinking agent is provided. The composition is able to form a film composition, which selectively disintegrates in media with high water content, depending on the ionic strength of the media.
    Type: Grant
    Filed: September 25, 2014
    Date of Patent: August 14, 2018
    Assignee: Rohm and Haas Chemicals LLC
    Inventors: Scott Backer, Afia S. Karikari, Paul Mercando
  • Patent number: 9969904
    Abstract: An aqueous composition comprising: (a) an aromatic-acrylic polymer comprising from 3 to 11 wt % polymerized units of C3-C6 carboxylic acid monomers and from 0.2 to 3 wt % polymerized units of anti-agglomerating monomers; (b) a reactive polyfunctional thermosetting resin; (c) a polyvalent metal ion; and (d) a polyfunctional curing agent, wherein the curing agent is stored separately from the thermosetting resin.
    Type: Grant
    Filed: March 16, 2015
    Date of Patent: May 15, 2018
    Assignees: ROHM AND HAAS COMPANY, DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Afua Sarpong Karikari, Paul Mercando, Theodore Tysak, Caroline Woelfle-Gupta
  • Patent number: 9896647
    Abstract: Described are automatic dishwashing detergents, comprising a builder, a surfactant, a polymer having sulfonic acid moieties, and a polymer having chelating moieties, wherein the polymer having chelating moieties comprises units derived from at least one carboxylic acid monomer, their salts or esters, an aminocarboxylate selected from iminodiacetic acid (IDA) and ethylenediamine triacetic acid (ED3A), and at least one glycidyl monomer selected from AGE, GA, GMA.
    Type: Grant
    Filed: August 29, 2014
    Date of Patent: February 20, 2018
    Assignee: Rohm and Haas Company
    Inventors: Scott Backer, Paul Mercando
  • Publication number: 20170298299
    Abstract: A phosphorus-free automatic dishwashing detergent composition comprising: (a) 0.5 to 10 wt % of a polymer comprising polymerized units of: (i) 65 to 75 wt % (meth)acrylic acid, (ii) 15 to 25 wt % of a monoethylenically unsaturated dicarboxylic acid and (iii) 7 to 13 wt % 2-acrylamido-2-methylpropanesulfonic acid (AMPS); and having Mw from 5,000 to 100,000; (b) 15 to 50 wt % carbonate, (c) 0 to 50 wt % citrate and (d) 10 to 40 wt % of a bleaching agent.
    Type: Application
    Filed: October 5, 2015
    Publication date: October 19, 2017
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Publication number: 20170298300
    Abstract: A phosphorus-free automatic dishwashing detergent composition comprising: (a) 0.5 to 8 wt % of a first polymer comprising polymerized units of: (i) 60 to 82 wt % (meth)acrylic acid, (ii) 10 to 30 wt % of a monoethylenically unsaturated dicarboxylic acid and (iii) 8 to 25 wt % 2-acrylamido-2-methylpropanesulfonic acid (AMPS); and having Mw from 5,000 to 100,000; (b) 0.5 to 8 wt % of a second polymer comprising polymerized units of: (i) 60 to 95 wt % (meth)acrylic acid, (ii) 5 to 40 wt % 2-acrylamido-2-methylpropanesulfonic acid (AMPS); and having Mw from 5,000 to 100,000; (c) 15 to 50 wt % carbonate, (d) 5 to 50 wt % citrate and (e) 10 to 30 wt % of a bleaching agent.
    Type: Application
    Filed: October 7, 2015
    Publication date: October 19, 2017
    Inventors: Scott Backer, Severine Ferrieux, Paul Mercando, Eric P. Wasserman
  • Patent number: 9650591
    Abstract: Described are automatic dishwashing detergents, comprising a builder, a surfactant, and a polymer comprising units derived from at least one carboxylic acid monomer or its salt, at least one allyl glycidyl ether (AGE) and iminodiacetic acid (IDA), said polymer having Formula I: (Formula I) wherein m; n; R, R1, R2, and X are as defined herein. In some embodiments, an AGE and iminodiacetic acid (IDA) are first reacted to produce an ethylenically unsaturated aminocarboxylic acid monomer, which is then polymerized with at least one carboxylic acid monomer to produce the polymer having Formula I. Alternatively, an AGE is polymerized with at least one carboxylic acid monomer to produce a polymer, which is then reacted to graft IDA thereon to form the polymer having Formula I.
    Type: Grant
    Filed: September 3, 2014
    Date of Patent: May 16, 2017
    Inventors: Severine Ferrieux, Scott Backer, Paul Mercando, Eric P. Wasserman
  • Publication number: 20170015869
    Abstract: An aqueous composition comprising: (a) an aromatic-acrylic polymer comprising from 3 to 11 wt % polymerized units of C3-C6 carboxylic acid monomers and from 0.2 to 3 wt % polymerized units of anti-agglomerating monomers; (b) a reactive polyfunctional thermosetting resin; (c) a polyvalent metal ion; and (d) a polyfunctional curing agent, wherein the curing agent is stored separately from the thermosetting resin.
    Type: Application
    Filed: March 16, 2015
    Publication date: January 19, 2017
    Inventors: Afua Sarpong Karikari, Paul Mercando, Theodore Tysak, Caroline Woelfle-Gupta