Patents by Inventor Paul R. Howard
Paul R. Howard has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9334438Abstract: This invention relates to compositions and methods for treating subterranean formations, in particular, oilfield stimulation compositions and methods using water-in-water polymer emulsions to uniformly dissolve a rheologically active polymer, such as a thickener or friction reducer, in the treatment fluid. The emulsions have a low viscosity and are easily pumped for mixing into a treatment fluid, where upon dilution with an aqueous medium, the polymer is easily hydrated without forming fish-eyes. The partitioning agent in the water-in-water emulsion does not generally affect the rheology of the treatment fluid. The invention also relates to further processing of the emulsion by wet grinding, high shear mixing and/or heating to enhance the hydration rate in the preparation of the well treatment fluid.Type: GrantFiled: September 6, 2011Date of Patent: May 10, 2016Assignee: Schlumberger Technology CorporationInventors: Philip F. Sullivan, Gary John Tustin, Yenny Christanti, Gregory Kubala, Bruno Drochon, Yiyan Chen, Marie Noelle Dessinges, Paul R. Howard
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Patent number: 8658574Abstract: The invention discloses method of treatment and reuse of oilfield produced water. The method comprises: providing an aqueous medium comprised at least in part of oilfield produced water; contacting the aqueous medium with a zirconium compound; whereby the fluid viscosity and/or fluid drag reduction ability of the combination of the aqueous medium and zirconium compound is improved compared to the aqueous medium alone; introducing the combination in to the well; and allowing the combination to contact the formation. In another embodiment, the aqueous medium is further contacted by a friction-reduction additive. Still in another embodiment, the aqueous medium is further contacted by a gelling additive. Still in another embodiment, the fluid is energized with a gas.Type: GrantFiled: March 24, 2009Date of Patent: February 25, 2014Assignee: Schlumberger Technology CorporationInventors: Leiming Li, Lijun Lin, Chucks I. Ezeokonkwo, Curtis L. Boney, Paul R. Howard, Sudhir Shenoy, Baudel William Quintero, Ksenia Eliseeva
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Patent number: 8575073Abstract: A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore is carried out by forming treatment fluid comprising water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. The treatment fluid is introduced into the formation through the wellbore at a pressure above the fracture pressure of the formation.Type: GrantFiled: June 20, 2008Date of Patent: November 5, 2013Assignee: Schlumberger Technology CorporationInventors: Syed Ali, Leiming Li, Lijun Lin, Paul R. Howard, Curtis L. Boney, Carlos Abad
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Patent number: 8247355Abstract: The invention discloses method of treating a subterranean formation of a well bore, the method comprising: providing a treatment fluid comprising: an aqueous base fluid; a viscosity enhancer; and a viscoelastic surfactant, wherein the enhancer is acid in the aqueous base fluid and co-operates with the viscoelastic surfactant to enhance viscosity compared to viscoelastic surfactant alone in the aqueous base fluid; and introducing the treatment fluid into the well bore.Type: GrantFiled: June 25, 2009Date of Patent: August 21, 2012Assignee: Schlumberger Technology CorporationInventors: Leiming Li, Lijun Lin, Mathew M. Samuel, Syed Ali, Paul R. Howard
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Patent number: 8211835Abstract: The invention provides an environmentally friendly composition including a friction reducer, a biocide, a scale inhibitor, and optionally a clay stabilizer.Type: GrantFiled: September 21, 2010Date of Patent: July 3, 2012Assignee: Schlumberger Technology CorporationInventors: Paul R. Howard, Curtis L. Boney, Shawn McCleskey Rimassa, Syed A. Ali
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Patent number: 8205673Abstract: A method of removing a partial amount of water in a well, comprises deploying a differential filter downhole; and performing a downhole operation, wherein the differential filter comprises a swellable polymer that swells after contacting water such that permeability of the differential filter is reduced by removing said partial amount of water, the swellable polymer being non-soluble in the water and/or hydrocarbon and wherein the swellable polymer comprises at least one selected from the group consisting of polyacrylic acid, polyacrylate, polymethacrylic acid, poly maleic anhydride, polyacrylamide, polyvinyl alcohol, latex, polyamide, polyester, and a co-polymer thereof.Type: GrantFiled: December 21, 2009Date of Patent: June 26, 2012Assignee: Schlumberger Technology CorporationInventors: Leiming Li, Curtis L. Boney, Paul R. Howard
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Publication number: 20120157354Abstract: Disclosed herein is a composition comprising from about 0.1 wt % to about 50 wt % of a plant based product comprising mucilage. Methods of making the composition, a well treatment fluid comprising the composition, and methods of using the composition are also disclosed.Type: ApplicationFiled: December 12, 2011Publication date: June 21, 2012Inventors: Leiming Li, Lijun Lin, Baudel William Quintero, Paul R. Howard
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Publication number: 20110319301Abstract: This invention relates to compositions and methods for treating subterranean formations, in particular, oilfield stimulation compositions and methods using water-in-water polymer emulsions to uniformly dissolve a rheologically active polymer, such as a thickener or friction reducer, in the treatment fluid. The emulsions have a low viscosity and are easily pumped for mixing into a treatment fluid, where upon dilution with an aqueous medium, the polymer is easily hydrated without forming fish-eyes. The partitioning agent in the water-in-water emulsion does not generally affect the rheology of the treatment fluid. The invention also relates to further processing of the emulsion by wet grinding, high shear mixing and/or heating to enhance the hydration rate in the preparation of the well treatment fluid.Type: ApplicationFiled: September 6, 2011Publication date: December 29, 2011Inventors: Philip F. Sullivan, Gary John Tustin, Yenny Christanti, Gregory Kubala, Bruno Drochon, Yiyan Chen, Marie Noelle Dessinges, Paul R. Howard
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Patent number: 8044000Abstract: This invention relates to compositions and methods for treating subterranean formations, in particular, oilfield stimulation compositions and methods using water-in-water polymer emulsions to uniformly dissolve a rheologically active polymer, such as a thickener or friction reducer, in the treatment fluid. The emulsions have a low viscosity and are easily pumped for mixing into a treatment fluid, where upon dilution with an aqueous medium, the polymer is easily hydrated without forming fish-eyes. The partitioning agent in the water-in-water emulsion does not generally affect the rheology of the treatment fluid. The invention also relates to further processing of the emulsion by wet grinding, high shear mixing and/or heating to enhance the hydration rate in the preparation of the well treatment fluid.Type: GrantFiled: July 2, 2008Date of Patent: October 25, 2011Assignee: Schlumberger Technology CorporationInventors: Philip F. Sullivan, Gary John Tustin, Yenny Christanti, Gregory Kubala, Bruno Drochon, Yiyan Chen, Marie Noelle Dessinges, Paul R. Howard
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Patent number: 8003577Abstract: A method of treating a subterranean formation penetrated by a wellbore utilizes a treating fluid formed from an aqueous solution of a water-soluble polymer. The treating fluid further contains a crosslinking agent and an optional delayed release alkaline additive. The delayed release alkaline additive may be at least one of urea, a urea derivative, a solid alkaline earth metal carbonate, a solid alkaline earth metal oxide and combinations of these. The treating fluid further includes an acidic pH adjusting agent used in an amount to provide the treating fluid with a pH of less than about 5. The treating fluid is then introduced into the formation.Type: GrantFiled: March 22, 2007Date of Patent: August 23, 2011Assignee: Schlumberger Technology CorporatonInventors: Leiming Li, Paul R. Howard, Carlos Abad, Michael D. Parris, Lijun Lin, Andrey Mirakyan, Richard D. Hutchins, Baudel William Quintero
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Publication number: 20110166050Abstract: The invention discloses treatment and reuse of oilfield produced water. A method of inhibiting enzymes/bacteria in an aqueous medium for viscosification comprises contacting the aqueous medium with a denaturant and/or a bactericide and thereafter mixing a gelling agent in the aqueous medium. The viscosified fluid can be used as a well treating fluid for fracturing and other applications. A well treatment fluid comprises a metal denaturant and/or a bactericide and a gelling agent in an amount effective to viscosify the fluid. Also disclosed is oilfield produced water denatured with from 1 to 2000 ppm by weight of a zirconium compound.Type: ApplicationFiled: March 14, 2011Publication date: July 7, 2011Inventors: Leiming Li, Paul R. Howard, Michael D. Parris, Bernhard Lungwitz, Curtis L. Boney, Kevin W. England, Richard D. Hutchins, Jack Li
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Publication number: 20110071058Abstract: The invention provides an environmentally friendly composition including a friction reducer, a biocide, a scale inhibitor, and optionally a clay stabilizer.Type: ApplicationFiled: September 21, 2010Publication date: March 24, 2011Inventors: Paul R. Howard, Curtis L. Boney, Shawn McCleskey Rimassa, Syed A. Ali
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Patent number: 7893010Abstract: A well treatment microemulsion for use in a subterranean formation is disclosed, the microemulsion comprises a solvent blend comprising a solvent and a co-solvent; a surfactant blend comprising a surfactant, wherein the surfactant blend is able to give formation intermediate wettability properties; an alcohol; and a carrier fluid; wherein the alcohol, the solvent and surfactant blends are combined with the carrier fluid to produce the well treatment microemulsion. By intermediate wettability it is meant that the water has an advancing contact angle on the surface between 62 and 133 degrees. The associate method of treating a subterranean formation of a well with the microemulsion and the associate method of modifying the wettability of the formation with the microemulsion are also disclosed.Type: GrantFiled: April 30, 2009Date of Patent: February 22, 2011Assignee: Schlumberger Technology CorporationInventors: Syed Ali, Leiming Li, Paul R. Howard, Sumitra Mukhopadhyay
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Publication number: 20100331223Abstract: The invention discloses method of treating a subterranean formation of a well bore, the method comprising: providing a treatment fluid comprising: an aqueous base fluid; a viscosity enhancer; and a viscoelastic surfactant, wherein the enhancer is acid in the aqueous base fluid and co-operates with the viscoelastic surfactant to enhance viscosity compared to viscoelastic surfactant alone in the aqueous base fluid; and introducing the treatment fluid into the well bore.Type: ApplicationFiled: June 25, 2009Publication date: December 30, 2010Inventors: Leiming Li, Lijun Lin, Mathew M. Samuel, Syed Ali, Paul R. Howard
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Publication number: 20100307757Abstract: Methods and apparatus of embodiments of the invention relate to a system for treating a subterranean formation including mixing equipment to form a fluid comprising sodium hypochlorite and sodium diacetate; and pumps and a tubular to introduce the fluid into the subterranean formation, wherein a surface of the subterranean formation contains at least 15 percent less microorganisms than if no sodium hypochlorite were in the fluid. Methods and apparatus of embodiments of the invention relate to a method of producing a petroleum product from a wellbore including using a well treatment system comprising mixing equipment, pumps, and a tubular, forming a fluid comprising sodium hypochlorite and sodium diacetate; and introducing the fluid to the well treatment system to achieve a reduced population of microorganisms in the system.Type: ApplicationFiled: June 3, 2010Publication date: December 9, 2010Inventors: Kristel A. Blow, Syed A. Ali, Paul R. Howard, Curtis L. Boney, Shawn McCleskey Rimassa, Bruce A. MacKay, Leiming Li, Noel Coffman, Richard D. Hutchins
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Patent number: 7806182Abstract: A subterranean formation stimulation method utilizes a treatment fluid comprising residual drilling fluid injected into the formation, and producing the stimulated formation. In one embodiment, a tight gas formation is fractured and the fracture has a higher conductivity than the formation.Type: GrantFiled: October 17, 2008Date of Patent: October 5, 2010Assignee: Schlumberger Technology CorporationInventors: George Waters, Paul R. Howard, Don Williamson, John W. Still
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Publication number: 20100248997Abstract: The invention discloses method of treatment and reuse of oilfield produced water. The method comprises: providing an aqueous medium comprised at least in part of oilfield produced water; contacting the aqueous medium with a zirconium compound; whereby the fluid viscosity and/or fluid drag reduction ability of the combination of the aqueous medium and zirconium compound is improved compared to the aqueous medium alone; introducing the combination in to the well; and allowing the combination to contact the formation. In another embodiment, the aqueous medium is further contacted by a friction-reduction additive. Still in another embodiment, the aqueous medium is further contacted by a gelling additive. Still in another embodiment, the fluid is energized with a gas.Type: ApplicationFiled: March 24, 2009Publication date: September 30, 2010Inventors: Leiming Li, Lijun Lin, Chucks I. Ezeokonkwo, Curtis L. Bonney, Paul R. Howard, Sudhir Shenoy, Baudel William Quintero, Ksenia Eliseeva
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Publication number: 20100093891Abstract: The invention provides a method. The method injects into a wellbore, a fluid comprising at least one of an acrylamide polymer and an acrylamide copolymer, and at least one of an oxidizing agent and a radical initiator; and allows viscosity of the fluid to increase for a first period of time; and subsequently, allows viscosity of the fluid to decrease for a second period of time. In a further aspect the invention provides a fluid for use in a well within a subterranean formation penetrated by a wellbore. The fluid is in a first embodiment, made of an acrylamide polymer and/or copolymer and an oxidizing agent or radical initiator, wherein concentration of the oxidizing agent or radical initiator is such that the fluid increases its viscosity for a period of time and after said period of time decreases its viscosity.Type: ApplicationFiled: October 13, 2009Publication date: April 15, 2010Inventors: Leiming Li, Syed Ali, Richard D. Hutchins, Lijun Lin, Curtis L. Boney, Carlos Abad, Javier Sanchez Reyes, Paul R. Howard
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Publication number: 20090318313Abstract: A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore is carried out by forming treatment fluid comprising water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. The treatment fluid is introduced into the formation through the wellbore at a pressure above the fracture pressure of the formation.Type: ApplicationFiled: June 20, 2008Publication date: December 24, 2009Inventors: Syed Ali, Leiming Li, Lijun Lin, Paul R. Howard, Curtis L. Boney, Carlos Abad
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Publication number: 20090305914Abstract: A method of forming a gelled organic-based fluid is disclosed. The method comprises combining an organic solvent, a viscoelastic surfactant, and a metal carboxylate crosslinker; and forming the gelled organic-based fluid. In a further aspect, the method is used to treat a subterranean formation of a well, for example for a stimulation job as fracturing or the like.Type: ApplicationFiled: April 30, 2009Publication date: December 10, 2009Inventors: Leiming Li, Syed Ali, Lijun Lin, Mathew M. Samuel, Curtis L. Boney, Francois M. Auzerais, Richard Marcinew, Paul R. Howard