Abstract: A chemical looping system that contains an oxidizer and a reducer is in fluid communication with a gas purification unit. The gas purification unit has at least one compressor, at least one dryer; and at least one distillation purification system; where the gas purification unit is operative to separate carbon dioxide from other contaminants present in the flue gas stream; and where the gas purification unit is operative to recycle the contaminants to the chemical looping system in the form of a vent gas that provides lift for reactants in the reducer.

Abstract: A flow control grid includes a plurality of channel assemblies connected to one another. Each of the plurality of channel assemblies defines a flow straightening section and a flow turning section. The flow turning section has an arcuate segment and a first substantially flat segment. The first substantially flat segment is positioned in the flow straightening section. The arcuate segment extends outwardly from the flow straightening section.

Abstract: A method and an arrangement 22 for supplying and mixing a reducing agent into a flue gas FG flowing through a gas duct 14 and into a selective catalytic reduction (SCR) reactor 18 arranged downstream of the arrangement 22. The subject arrangement 22 is useful in both high and low dust environments to mitigate ash and like particulate accumulation on reducing agent nozzles 42 and to provide more uniform reducing agent flow distribution upstream of the SCR reactor 18.

Abstract: A chemical looping system that contains an oxidizer and a reducer is in fluid communication with a gas purification unit. The gas purification unit has at least one compressor, at least one dryer; and at least one distillation purification system; where the gas purification unit is operative to separate carbon dioxide from other contaminants present in the flue gas stream; and where the gas purification unit is operative to recycle the contaminants to the chemical looping system in the form of a vent gas that provides lift for reactants in the reducer.

Abstract: A flow control grid includes a plurality of channel assemblies connected to one another. Each of the plurality of channel assemblies defines a flow straightening section and a flow turning section. The flow turning section has an arcuate segment and a first substantially flat segment. The first substantially flat segment is positioned in the flow straightening section. The arcuate segment extends outwardly from the flow straightening section.

Abstract: A hot solids process selectively operable for purposes of generating at least one predetermined output based on what the specific nature of the primary purpose of the hot solids process is for which the at least one predetermined output that is selected from a multiplicity of predetermined outputs, such as H2 and CO2, is being produced, and wherein such primary purpose of the hot solids process is designed to be pre-selected from a group of primary purposes of the hot solids process that includes at least two of the generation of H2 for electric power purposes, the generation of SynGas for electric power production as well as for other industrial uses, the production of steam for electric power generation as well as for other uses, the production of process heat, the production of CO2 for agricultural purposes, and the generation of a feedstock such as H2 for use for the production of liquid hydrocarbons.

Abstract: In a retrofit system for hot solids combustion and gasification, a chemical looping system includes an endothermic reducer reactor 12 having at least one materials inlet 22 for introducing carbonaceous fuel and CaCO3 therein and a CaS/gas outlet 26. A first CaS inlet 40 and a first CaSO4 inlet 64 are also defined by the reducer reactor 12. An oxidizer reactor 14 is provided and includes an air inlet 68, a CaSO4/gas outlet 46, a second CaS inlet 44, and a second CaSO4 inlet 66. A first separator 30 is in fluid communication with the CaS/gas outlet 26 and includes a product gas and a CaS/gas outlet 32 and 34 from which CaS is introduced into said first and second CaS inlets. A second separator 50 is in fluid communication with the CaSO4/gas outlet 46 and has an outlet 52 for discharging gas therefrom, and a CaSO4 outlet from which CaSO4 is introduced into the first and second CaSO4 inlets 62, 66.

Abstract: A hot solids process operable selectively for combustion purposes and gasification purposes wherein a pre-identified product is selected from a group of products to be generated through the use of the hot solids process. Based on the nature of the pre-identified product, which is to be generated through the use of the hot solids process, a specific fuel from which the pre-identified product is capable of being derived is selected from a group of fuels. Then, from a group of reactors there is selected a first reactor, which is operable for generating in the first reactor the pre-identified product as an output from the first reactor. Thereafter, from a group of reactors, there is selected a second reactor, which is operable for effecting in the second reactor the conversion of air and of a predetermined carrier selected from a group of carriers to produce a predefined output from the second reactor.

Abstract: A hot solids process wherein a predetermined output, which is designed to be suitable for use as an input to a petrochemical process, is capable of being generated through the use of the hot solids process. The mode of operation of such a hot solids process is designed to be such that preferably a portion of the otherwise normally unusable product output, which is produced from a petrochemical process, is designed to be utilized as an input to the hot solids process for purposes of generating from the hot solids process the predetermined output that is suitable for use as an input to a petrochemical process.

Abstract: A hot solids process selectively operable for purposes of generating at least one predetermined output based on what the specific nature of the primary purpose of the hot solids process is for which the at least one predetermined output that is selected from a multiplicity of predetermined outputs, such as H2 and CO2, is being produced, and wherein such primary purpose of the hot solids process is designed to be pre-selected from a group of primary purposes of the hot solids process that includes at least two of the generation of H2 for electric power purposes, the generation of SynGas for electric power production as well as for other industrial uses, the production of steam for electric power generation as well as for other uses, the production of process heat, the production of CO2 for agricultural purposes, and the generation of a feedstock such as H2 for use for the production of liquid hydrocarbons.

Abstract: A hot solids process selectively operable for purposes of generating a predetermined output based on the nature of the specific application for which the predetermined output is being produced, and wherein such specific application is designed to be pre-selected from a group of specific applications that includes a new steam generator application, a retrofit steam generator application, a CO2 capture ready Hot Solids Combustion application, a CO2 capture ready hot solids gasification application, a CO2 capture hot solids combustion application, a CO2 capture hot solids gasification application, a partial CO2 capture hot solids combustion application, and a partial CO2 capture hot solids gasification application.

Abstract: In a retrofit system for hot solids combustion and gasification, a chemical looping system includes an endothermic reducer reactor 12 having at least one materials inlet 22 for introducing carbonaceous fuel and CaCO3 therein and a CaS/gas outlet 26. A first CaS inlet 40 and a first CaSO4 inlet 64 are also defined by the reducer reactor 12. An oxidizer reactor 14 is provided and includes an air inlet 68, a CaSO4/gas outlet 46, a second CaS inlet 44, and a second CaSO4 inlet 66. A first separator 30 is in fluid communication with the CaS/gas outlet 26 and includes a product gas and a CaS/gas outlet 32 and 34 from which CaS is introduced into said first and second CaS inlets. A second separator 50 is in fluid communication with the CaSO4/gas outlet 46 and has an outlet 52 for discharging gas therefrom, and a CaSO4 outlet from which CaSO4 is introduced into the first and second CaSO4 inlets 62, 66.

Abstract: A recuperative and conductive heat transfer system (10, 10′) that is operative to effect therewith the heating within the second portion (20, 20′) of the heat transfer system (10, 10′) of a “working fluid” flowing through the heat s transfer surfaces (32, 32′) as a consequence of the transfer thereto by conduction of heat from a multiplicity of regenerative solids (24, 24′). The multiplicity of regenerative solids (24, 24′) derive their heat from a recuperation thereby within the first portion (12, 12′) of the heat transfer system (10, 10′) from either an internally generated or an externally generated source of heat (22, 22′).

Abstract: A recuperative and conductive heat transfer system (10, 10′) that is operative to effect therewith the heating within the second portion (20, 20′) of the heat transfer system (10, 10′) of a “working fluid” flowing through the heat transfer surfaces (32, 32′) as a consequence of the transfer thereto by conduction of heat from a multiplicity of regenerative solids (24, 24′). The multiplicity of regenerative solids (24, 24′) derive their heat from a recuperation thereby within the first portion (12, 12′) of the heat transfer system (10, 10′) from either an internally generated or an externally generated source of heat (22, 22′).

Abstract: A pressurized coal gasification system having double wall containment vessels (2,10) is disclosed. The gasification vessel (2) is provided with a gas tight water seal (36) for connecting the lower end of the inner water-cooled vessel (4) with the bottom supported slag tank (32). The seal (36) prevents gas leakage between the vessel interior and the pressurized annular volume (24) formed between the inner and outer gasification chambers (4,6). A flow of clean, particulate-free product gas (60) is routed into the contiguous annular volume (24,26,28) formed between the inner water-cooled gas directing members (4,20,12) and the outer, pressure containing members (6,22,16) to prevent either leakage of raw product gas into the annular volume or dilution of the product gas (46) by leakage of the sealing gas (60) into the hot product gas flowstream.

Abstract: A gasifier (10) having an associated boiler (26, 32, 42, 48), for converting coal to combustible gas, and also having a desulfurizer (20) downstream of the gasifier. In order to maintain the gas leaving the gasifier and flowing to the desulfurizer above a predetermined temperature, even when operating the unit at reduced loads, a temperature sensing device (56) continuously monitors the gas temperature upstream of the desulfurizer. If the temperature drops below a predetermined value, high temperature boiler water (62) is introduced to the economizer (26) rather than feed water (24), so that less heat is absorbed by the economizer from the gases under these conditions.