Abstract: The present disclosure includes an ionic liquid-immobilized titanium-silicon molecular sieve catalyst and a preparation method and use thereof, and a method for preparing poly(butylene succinate). The ionic liquid-immobilized titanium-silicon molecular sieve catalyst further includes a titanium-silicon molecular sieve along with an acidic ionic liquid bonded to the titanium-silicon molecular sieve.

Abstract: The invention relates to a self-healing copolymerized polycarbonate and a preparation method thereof. The method comprises the following steps: mixing a reducing sugar, an oxetane derivative and a first catalyst, heating and reacting at 50 to 80° C. for 0.5 to 2 h to obtain the first product; adding a diol, a diester and a second catalyst to the first product, and then heating to 180 to 220° C. for 2 to 4 h to obtain an oligomer; heating the oligomer to 230 to 270° C. and holding at the temperature and reacting for 1 to 3 h to obtain a self-healing copolymerized polycarbonate. The self-healing copolymerized polycarbonate material prepared by the method of the invention has self-healing property and biodegradability, which ensures the consistency and uniformity of the product. In addition, the block introduced into the main chain is green and environmentally friendly, and the original intention of clean production of polycarbonate has not been changed.

Abstract: The invention relates to a self-healing copolymerized polycarbonate and a preparation method thereof. The method comprises the following steps: mixing a reducing sugar, an oxetane derivative and a first catalyst, heating and reacting at 50 to 80° C. for 0.5 to 2 h to obtain the first product; adding a diol, a diester and a second catalyst to the first product, and then heating to 180 to 220° C. for 2 to 4 h to obtain an oligomer; heating the oligomer to 230 to 270° C. and holding at the temperature and reacting for 1 to 3 h to obtain a self-healing copolymerized polycarbonate. The self-healing copolymerized polycarbonate material prepared by the method of the invention has self-healing property and biodegradability, which ensures the consistency and uniformity of the product. In addition, the block introduced into the main chain is green and environmentally friendly, and the original intention of clean production of polycarbonate has not been changed.

Abstract: A disk reactor for production of polycarbonate includes a cylinder provided with an end cover at each end. The cylinder is provided with a material inlet, a product outlet and a gas phase port thereon. The cylinder is provided with a driving shaft therein. The driving shaft is provided with plural disks at different spaces thereon. Each disk has slope different from each other. Each disk is provided with plural transverse blades and plural transverse scrapers thereon. A scraper blade is arranged between two disks and fixed on the driving shaft. Compared with the prior disk reactors, the disk reactor fully considers the change of melt viscosity in the polymerization process, simultaneously increases the mass transfer area of the reactor, has good film forming and surface renew performance and high light component removal efficiency, and can produce polycarbonate with high molecular weight and uniform quality.

Abstract: A disk reactor for production of polycarbonate includes a cylinder provided with an end cover at each end. The cylinder is provided with a material inlet, a product outlet and a gas phase port thereon. The cylinder is provided with a driving shaft therein. The driving shaft is provided with plural disks at different spaces thereon. Each disk has slope different from each other. Each disk is provided with plural transverse blades and plural transverse scrapers thereon. A scraper blade is arranged between two disks and fixed on the driving shaft. Compared with the prior disk reactors, the disk reactor fully considers the change of melt viscosity in the polymerization process, simultaneously increases the mass transfer area of the reactor, has good film forming and surface renew performance and high light component removal efficiency, and can produce polycarbonate with high molecular weight and uniform quality.