Abstract: The invention relates to a process for the manufacture of thermally expandable thermoplastic microspheres. The process comprises, providing a mixture of monomeric materials suitable for polymerisation to form a thermoplastic polymer and at least one blowing agent, providing to the mixture a colloidal silica that is surface-modified with at least hydrophobic organosilane groups and forming an emulsion. A polymerisation is performed to form the thermally expandable thermoplastic microspheres. The invention further relates to thermally expandable thermoplastic micro spheres, expanded micro spheres and their use in the manufacture of products.

Abstract: The disclosure is directed to a method for preparing an adhesive composition, in which an aqueous phase comprising a modified colloidal silica is mixed with an organic phase comprising one or more monomers in the presence of an initiator, wherein conditions are maintained such that polymerisation of the one or more monomers occurs to form an aqueous polymeric dispersion, wherein; (i) the aqueous polymeric dispersion comprises polymer particles with protective colloid on their surface; (ii) the modified colloidal silica comprises colloidal silica particles with at least one surface-bound hydrophilic organosilane moiety and/or comprises colloidal silica particles with at least one additional element on its surface, the element being able formally to adopt a +3 or +4 oxidation state; and (iii) the initiator is at least partially soluble in water.

Abstract: A composition useful for subterranean water or gas shut off applications includes organosilane-modified colloidal silica and an accelerator. The accelerator includes one or more organic or inorganic salts. A method of using a composition, including an organosilane-modified colloidal silica and an accelerator, includes forming a fluid system that is flowed to a formation in a subterranean zone, such as through a wellbore, where the composition forms a gel to plug the formation and shut off water flow into the wellbore.

Abstract: The present disclosure relates to a method for preparing a coating composition, in which an aqueous phase comprising an organosilane-functionalised colloidal silica is mixed with an organic phase comprising one or more monomers in the presence of an initiator and a protective colloid, wherein conditions are maintained such that polymerisation of the one or more monomers occurs to form an aqueous polymeric dispersion, in which the aqueous polymeric dispersion comprises polymer particles with protective colloid on their surface; the organosilane-functionalised colloidal silica comprises colloidal silica particles with at least one surface-bound organosilane moiety; and the initiator is at least partially soluble in water.

Abstract: A composition useful for subterranean water or gas shut off applications includes organosilane-modified colloidal silica and an accelerator. The accelerator includes one or more organic or inorganic salts. A method of using a composition, including an organosilane-modified colloidal silica and an accelerator, includes forming a fluid system that is flowed to a formation in a subterranean zone, such as through a wellbore, where the composition forms a gel to plug the formation and shut off water flow into the wellbore.

Abstract: The disclosure is directed to a method for preparing an adhesive composition, in which an aqueous phase comprising a modified colloidal silica is mixed with an organic phase comprising one or more monomers in the presence of an initiator, wherein conditions are maintained such that polymerisation of the one or more monomers occurs to form an aqueous polymeric dispersion, wherein; (i) the aqueous polymeric dispersion comprises polymer particles with protective colloid on their surface; (ii) the modified colloidal silica comprises colloidal silica particles with at least one surface-bound hydrophilic organosilane moiety and/or comprises colloidal silica particles with at least one additional element on its surface, the element being able formally to adopt a +3 or +4 oxidation state; and (iii) the initiator is at least partially soluble in water.

Abstract: The invention relates to a process for the manufacture of thermally expandable thermoplastic microspheres. The process comprises, providing a mixture of monomeric materials suitable for polymerisation to form a thermoplastic polymer and at least one blowing agent, providing to the mixture a colloidal silica that is surface-modified with at least hydrophobic organosilane groups and forming an emulsion. A polymerisation is performed to form the thermally expandable thermoplastic microspheres. The invention further relates to thermally expandable thermoplastic micro spheres, expanded micro spheres and their use in the manufacture of products.

Abstract: A composition useful for subterranean water or gas shut off applications includes organosilane-modified colloidal silica and an accelerator. The accelerator includes one or more organic or inorganic salts. A method of using a composition, including an organosilane-modified colloidal silica and an accelerator, includes forming a fluid system that is flowed to a formation in a subterranean zone, such as through a wellbore, where the composition forms a gel to plug the formation and shut off water flow into the wellbore.

Abstract: The present invention relates to a water-soluble cationic acrylamide-based polymer having one or more acetoacetate groups. The invention also relates to a method for producing the water-soluble polymer which comprises polymerizing ethylenically unsaturated monomers in an aqueous phase, wherein the monomers comprise (a) (meth)acrylamide, (b) ethylenically unsaturated cationic monomer, (c) ethylenically unsaturated monomer having one or more acetoacetate groups, and (d) optionally other ethylenically unsaturated monomer. The invention further relates to the use of the water-soluble polymer as a strength agent in the production of paper and board. The invention further relates to a process for producing paper and board which comprises providing an aqueous cellulosic suspension, adding to the suspension water-soluble polymer having one or more ketone groups, and dewatering the obtained suspension.

Abstract: The present invention relates to a particle of modified silica which comprises a particle of silica which is covalently linked to at least one halohydrin moiety. Furthermore, the present invention relates to a method of preparing the particle of modified silica, a particle of modified silica obtained by such method, use of the particle of modified silica as a stationary phase for chromatography, as well as a separation column for chromatography comprising the particle of modified silica.

Abstract: Compounds according to formula (I) or formula (II) wherein R1 and R2, independently from each other, are chosen among hydrocarbons having from 1 carbon atom up to 30 carbon atoms, with the proviso that at least one of R1 and R2 are chosen among hydrocarbons having at least 8 carbon atoms, and A is a halogen. Use of compounds as hydrophobing agent, such as sizing agent.

Abstract: The present invention relates to a particle of modified silica which comprises a particle of silica which is covalently linked to at least one halohydrin moiety. Furthermore, the present invention relates to a method of preparing the particle of modified silica, a particle of modified silica obtained by such method, use of the particle of modified silica as a stationary phase for chromatography, as well as a separation column for chromatography comprising the particle of modified silica.

Abstract: The present invention relates to a water-soluble cationic acrylamide-based polymer having one or more acetoacetate groups. The invention also relates to a method for producing the water-soluble polymer which comprises polymerizing ethylenically unsaturated monomers in an aqueous phase, wherein the monomers comprise (a) (meth)acrylamide, (b) ethylenically unsaturated cationic monomer, (c) ethylenically unsaturated monomer having one or more acetoacetate groups, and (d) optionally other ethylenically unsaturated monomer. The invention further relates to the use of the water-soluble polymer as a strength agent in the production of paper and board. The invention further relates to a process for producing paper and board which comprises providing an aqueous cellulosic suspension, adding to the suspension water-soluble polymer having one or more ketone groups, and dewatering the obtained suspension.

Abstract: Compounds according to formula (I) or formula (II) wherein R1 and R2, independently from each other, are chosen among hydrocarbons having from 1 carbon atom up to 30 carbon atoms, with the proviso that at least one of R1 and R2 are chosen among hydrocarbons having at least 8 carbon atoms, and A is a halogen. Use of compounds as hydrophobing agent, such as sizing agent.