Patents by Inventor Peter Ackermann
Peter Ackermann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5420301Abstract: The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being Cl or Br, or is --COOR.sup.2, --SiR.sub.3.sup.2 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkyl-phenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.Type: GrantFiled: November 5, 1993Date of Patent: May 30, 1995Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Hans-Ruedi Kanel, Bruno Schaub
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Patent number: 5374639Abstract: Benzotriazolesulfonic acid derivatives of formula I ##STR1## wherein R.sub.3 =R.sub.4 X and R.sub.4 is an unsaturated 6-membered heterocycle having a maximum of 2 nitrogen atoms, it being possible for the heterocycle to be substituted, and X is oxygen or sulfur, while R.sub.1 and R.sub.2 are as defined herein, are valuable microbicides. They can be used in plant protection in the form of suitable compositions, for example for controlling fungal diseases.Type: GrantFiled: December 16, 1992Date of Patent: December 20, 1994Assignee: Ciba-Geigy CorporationInventors: Marius Sutter, Urs Muller, Bernhard Hostettler, Peter Ackermann, Yasuchika Yamaguchi
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Patent number: 5322853Abstract: Novel benzotriazolesulfonic acid derivatives of formula ##STR1## wherein: R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy having at least two identical or different halogen atoms, CF.sub.3, nitro or the group N(R')R", wherein R' and R" are each independently of the other C.sub.1 -C.sub.4 alkyl;R.sub.2 is phenoxy or phenylthio each of which is unsubstituted or mono- to tri-substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy having at least two identical or different halogen atoms, cyano, nitro, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, phenyl, 2-phenylethynyl or by a further phenoxy radical that is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl and/or by C.sub.1 -C.sub.4 alkoxy; or R.sub.2 is the radical O--CH.sub.2 --O;R.sub.3 is alkyl, aryl or aralkyl having a maximum of 14 carbon atoms, these radicals can be substituted by halogen, C.sub.1 -C.sub.Type: GrantFiled: April 23, 1993Date of Patent: June 21, 1994Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Max Schellenbaum
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Patent number: 5281718Abstract: The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being Cl or Br, or is --COOR.sup.2, --SiR.sub.3.sup.2 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.Type: GrantFiled: December 4, 1992Date of Patent: January 25, 1994Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Hans-Ruedi Kanel, Bruno Schaub
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Patent number: 5194628Abstract: The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 l in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 l is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being Cl or Br, or is --COOR.sup.2, --SiR.sub.3.sup.2 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkyl-phenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.Type: GrantFiled: September 14, 1990Date of Patent: March 16, 1993Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Hans-Ruedi Kanel, Bruno Schaub
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Patent number: 5116872Abstract: 1-Aminocyclohexanecarboxylic acid derivatives of the formula I ##STR1## or their acid addition salts or a metal complex can be employed for protecting plants from microorganisms. In the formula I, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, benzyl, or an ammonium radical which is unsubstituted or substituted by hydrocarbon radicals having not more than 20 C atoms, or a metal ion equivalent.Compounds of the formula I can be employed in the form of crop protection agents using suitable carrier materials.Type: GrantFiled: January 22, 1991Date of Patent: May 26, 1992Assignees: Ciba-Geigy Corporation, Degussa AktiengesellschaftInventors: Peter Ackermann, Hanspeter Fischer, Rolf Vogel, Karlheinz Drauz, Hans-Albrecht Hasseberg, Hans-Jochen Hasselbach, Gunter Knaup, Hans-Peter Krimmer, Matthias Schafer
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Patent number: 5068359Abstract: Novel benzothiophene and benzofuran derivatives of the general formula I ##STR1## wherein X is oxygen or sulfur, R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or halogen and R is a 4-cyano-3-pyrrole radical of which the N atom carries one of the following substituents:A: hydrogen or CO--R.sub.4 in which R.sub.4 is unsubstituted C.sub.1 C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, unsubstituted C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkoxy substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 cycloalkyl or tetrahydrofur2-yl;B: S-R.sub.5 in which R.sub.5 is C.sub.1 -C.sub.3 haloalkyl;C: CH(Y)R.sub.6 in which R.sub.6 is hydrogen or C.sub.1 -C.sub.8 haloalkyl and Y is hydroxy, halogen or OC(O)R.sub.Type: GrantFiled: June 12, 1990Date of Patent: November 26, 1991Assignee: Ciba-Geigy CorporationInventors: Alica Huxley, Walter Kunz, Peter Ackermann, Marius Sutter
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Patent number: 5036084Abstract: Pyridinyl derivatives of formula I ##STR1## wherein R.sub.1 to R.sub.5 are each independently hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 haloalkoxy, cyano, C.sub.1 -C.sub.6 alkoxycarbonyl or phenyl,R.sub.6 and R.sub.7 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl, or phenyl or benzyl, each of which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 haloalkoxy,R.sub.8 is ##STR2## and R.sub.9 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, or benzyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 haloalkoxy, or R.sub.9 is an acyl radical.Type: GrantFiled: December 21, 1989Date of Patent: July 30, 1991Assignee: Ciba-Geigy CorporationInventors: Hans Tobler, Peter Ackermann, Robert Nyfeler
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Patent number: 4975765Abstract: In a highly integrated circuit the semiconductor chip (8) is fastened on a substrate (17) which projects on all sides only a few millimeters beyond the semiconductor chip (8). For Full dynamic testing of the circuit before insertion, connections are provided which are arranged outside the projecting substrate edge (23) with a sufficiently large grid spacing.In a first embodiment (FIG. 2D) "lost" test connections (5) are used which are separated after testing.In a second embodiment (FIG. 3E), contact areas in the form of bumps (21) are used for testing which are arranged on the underside of the through-holes (18) lying in the chip mounting area.In this manner it is possible to realize a circuit with greatly reduced space requirement, which at the same time can be fully tested dynamically before insertion.Type: GrantFiled: July 7, 1989Date of Patent: December 4, 1990Assignee: Contraves AGInventors: Karl-Peter Ackermann, Gianni Berner
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Patent number: 4822806Abstract: The invention relates to .alpha.-methyl-(6-phenoxy)-2-picolyl cyclopropanecarboxylates of the formula ##STR1## wherein X.sub.1 is methyl or halogen,R.sub.1 is hydrogen or halogen, andR.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, nitro or cyano.The invention also relates to the preparation of these esters and to the use thereof in pest control.Type: GrantFiled: January 12, 1987Date of Patent: April 18, 1989Assignee: Ciba-Geigy CorporationInventor: Peter Ackermann
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Patent number: 4798912Abstract: Novel substituted phenoxybenzyldihalodimethyl-cyclopropylmethyl ethers of the formula ##STR1## in which X.sub.1 and X.sub.2 each independently of the other represents fluorine, chlorine or bromine;R.sub.1 represents hydrogen or flourine; andR.sub.2 represents hydrogen, fluorine, chlorine, bromine, methyl, trifluoromethyl or methoxy, and, if X.sub.1 and X.sub.2 have different meanings, the optical isomers of the compound of the formula I; processes for the manufacture of those compounds, and compositions containing them for use in pest control, especially for the control of insects, especially the larval stages thereof, that attack plants and animals, and of phytopathogenic fungi. The novel compounds exhibit good activity especially against insects that damage plants in rice crops.Type: GrantFiled: November 9, 1987Date of Patent: January 17, 1989Assignee: Ciba-Geigy CorporationInventors: Laurenz Gsell, Peter Ackermann
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Patent number: 4786654Abstract: There are disclosed novel unsubstituted or substituted phenoxyfluorobenzyltetramethylcyclopropylmethyl ethers of formula ##STR1## wherein Y is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkyl which is substituted by 1 to 9 halogen atoms, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkoxy which is substituted by 1 to 9 halogen atoms, C.sub.1 -C.sub.4 alkylthio or C.sub.1 -C.sub.4 alkylthio which is substituted by 1 to 9 halogen atoms, or is C.sub.2 -C.sub.4 alkenyl or C.sub.2 -C.sub.4 alkynyl and their benzyl ether intermediates of formula IV ##STR2## wherein X is halogen or p-tosyl. Also disclosed is a process for the preparation of these compounds and compositions containing them for use in pest control, especially for controlling insects that attack plants and animals, in particular their larval stages. The novel compounds are particularly effective against plant-destructive insects in rice crops.Type: GrantFiled: May 26, 1987Date of Patent: November 22, 1988Assignee: Ciba-Geigy CorporationInventors: Laurenz Gsell, Peter Ackermann
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Patent number: 4782087Abstract: Prop-1-ynyl-3-phenoxybenzyl-2,2-dimethyl-3-(2',2'-dihalovinyl)-cyclopropane -1-carboxylates of the formula ##STR1## in which X.sub.1 if fluorine, chlorine or bromine, and their use in combating pests.Type: GrantFiled: June 6, 1983Date of Patent: November 1, 1988Assignee: Ciba-Geigy CorporationInventors: Saleem Farooq, Peter Ackermann, Jozef Drabek, Laurenz Gsell, Odd Kristiansen, Rudolf Wehrli
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Patent number: 4778895Abstract: The invention relates to enantiomers of 1-(6-phenoxy-2-pyridyl)ethanols of the formula ##STR1## wherein * is (+) or (-) and X and Y are each independently of the other hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.5 alkynyl.The invention also relates to the preparation of these enantiomers and to their use for the preparation of biocidal compounds.Type: GrantFiled: April 6, 1987Date of Patent: October 18, 1988Assignee: Ciba-Geigy CorporationInventors: Eric Francotte, Peter Ackermann
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Patent number: 4661497Abstract: The invention relates to .alpha.-methyl-(6-phenoxy)-2-picolyl cyclopropanecarboxylates of the formula ##STR1## wherein X.sub.1 is methyl or halogen,R.sub.1 is hydrogen or halogen, andR.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, nitro or cyano.The invention also relates to the preparation of these esters and to the use thereof in pest control.Type: GrantFiled: December 31, 1984Date of Patent: April 28, 1987Assignee: Ciba-Geigy CorporationInventor: Peter Ackermann
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Patent number: 4618615Abstract: .alpha.-Cyclopropyl-.alpha.-phenylacetate and salts thereof, corresponding to the formula ##STR1## wherein R.sub.1 is hydrogen, methyl, cyano or ethinyl,X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl or C.sub.1 -C.sub.5 -alkoxy,X.sub.2 is hydrogen, halogen or C.sub.1 -C.sub.5 -alkyl, or together with X.sub.1 is methylenedioxy, andX.sub.3 and X.sub.4 are hydrogen or halogen.Processes for producing these .alpha.-cyclopropyl-.alpha.-phenylacetates and their use for controlling pests are described.Type: GrantFiled: November 7, 1983Date of Patent: October 21, 1986Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Laurenz Gsell, Boris Kohler
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Patent number: 4611004Abstract: 3-Phenoxybenzyl-(2-phenyl-2,2-alkylene-ethyl) ethers and -thioethers of the formula ##STR1## wherein A is oxygen or sulfur,R.sub.1 is hydrogen, methyl, cyano or ethinyl,R.sub.2 and R.sub.3 are hydrogen, halogen or C.sub.1 -C.sub.5 -alkyl,n is 2 to 4,X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.5 -alkoxy or C.sub.1 -C.sub.5 -haloalkoxy,X.sub.2 is hydrogen, halogen or C.sub.1 -C.sub.5 -alkyl, or together with X.sub.1 in the adjacent position is methylenedioxy, andX.sub.3 and X.sub.4 are each hydrogen or halogen.A process for producing these compounds and their use for controlling pests are described.Type: GrantFiled: March 27, 1985Date of Patent: September 9, 1986Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Laurenz Gsell
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Patent number: 4587255Abstract: Novel isomers of the compound of the formula ##STR1## are described, and processes for producing these compounds and their use for controlling pests are given.Type: GrantFiled: December 8, 1983Date of Patent: May 6, 1986Assignee: Ciba-Geigy CorporationInventors: Peter Ackermann, Laurenz Gsell, Boris Kohler
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Patent number: 4486424Abstract: Triorganotin hydantoin compounds of the formula ##STR1## wherein R is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, phenyl or ##STR2## R.sub.1 and R.sub.2 are each hydrogen, C.sub.1 -C.sub.8 -alkyl, phenyl, hydroxyphenyl, or together they are C.sub.5 -C.sub.7 -alkylene or oxygen,X is oxygen or sulfur, andY is hydrogen or --Sn--(R).sub.3, as well as a process for producing these compounds, and the use thereof for combating pests are described.Type: GrantFiled: October 4, 1982Date of Patent: December 4, 1984Assignee: Ciga-Geigy CorporationInventors: Wolfgang Wehner, Peter Ackermann
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Patent number: 4472396Abstract: There are described triorganotin-isocyanuric compounds of the formula ##STR1## wherein R is C.sub.1 -C.sub.6 -alkyl, phenyl, C.sub.5 -C.sub.8 -cycloalkyl or ##STR2## X is oxygen or sulfur, and Y.sub.1 and Y.sub.2 are each hydrogen or --Sn--R).sub.3,as well as a process for producing this compound, and the use thereof for combating pests.Type: GrantFiled: October 4, 1982Date of Patent: September 18, 1984Assignee: Ciba-Geigy CorporationInventors: Wolfgang Wehner, Peter Ackermann