Abstract: This invention relates to polymeric organosilicon compounds containing aryl radicals and to a method for improving the gliding or slipping properties of organic fibers treated therewith. The polymeric organosilicon compounds are represented by the formulaM.sub.a R.sub.b Si{[(OSiR.sub.2).sub.n D].sub.m (OSiR.sub.2).sub.n OSiR.sub.3-d M.sub.d }.sub.4-a-bin which R is hydrocarbon or substituted hydrocarbon radical, D represents radicals of the formula--X.sub.a A--X.sub.a (A--X.sub.a).sub.c --,X represents the groups: ##STR1## --NR'--, --O--, --S--, --SO.sub.2 --, --R"--, --NR'R", ##STR2## --OR"--, --SR"--, --SO.sub.2 R", where R' is hydrogen or R, R" is a bivalent aliphatic hydrocarbon radical, A is a bivalent or substituted bivalent aromatic hydrocarbon radical, M represents radicals of the formula--X.sub.a --A--X.sub.a (A--X.sub.a).sub.c H,a is 0 or 1, b is 0, 1 or 2, c is 0 or a number of from 1 to 5, m is 0 or a number of from 1 to 20, n is a number of from 1 to 1,000 with the proviso that at least one OSiP.

Abstract: This invention relates to polymeric organosilicon compounds containing aryl radicals and to a method for improving the gliding or slipping properties of organic fibers treated therewith. The polymeric organosilicon compounds are represented by the formulaM.sub.a R.sub.b Si{[(OSiR.sub.2).sub.n D].sub.m (OSiR.sub.2).sub.n OSiR.sub.3-d M.sub.d }4-a-bin which R is hydrocarbon or substituted hydrocarbon radical, D represents radicals of the formula--X.sub.a A--X.sub.a (A--X.sub.a).sub.c --,X represents the groups: ##STR1## where R' is hydrogen or R, R" is a bivalent aliphatic hydrocarbon radical, A is a bivalent or substituted bivalent aromatic hydrocarbon radical, M represents radicals of the formula--X.sub.a --A--X.sub.a (A--X.sub.a).sub.c H,a is 0 or 1, b is 0, 1 or 2, c is 0 or a number of from 1 to 5, d is 0 or 1, m is 0 or a number of from 1 to 20, n is a number of from 1 to 1,000 with the proviso that at least one OSiR.sub.2 -- unit and at least one X.sub.a --A--X.sub.

Abstract: This invention relates to polymeric organosilicon compounds containing aryl radicals and to a method for improving the gliding or slipping properties of organic fibers treated therewith. The polymeric organosilicon compounds are represented by the formulaM.sub.a R.sub.b Si{[(OSiR.sub.2).sub.n D].sub.m (OSiR.sub.2).sub.n OSiR.sub.3-a M.sub.a }.sub.4-a-bin which R is hydrocarbon or substituted hydrocarbon radical, D represents radicals of the formula--X.sub.a A--X.sub.a (A--X.sub.a).sub.c --,X represents the groups: ##STR1## --NR'--, --O--, --S--, --SO.sub.2 --, --R"--, --NR'R", ##STR2## --OR"--, --SR"--, --SO.sub.2 R", where R' is hydrogen or R, R" is a bivalent aliphatic hydrocarbon radical, A is a bivalent or substituted bivalent aromatic hydrocarbon radical, M represents radicals of the formula--X.sub.a --A--X.sub.a (A--X.sub.a).sub.c H,a is 0 or 1, b is 0, 1 or 2, c is 0 or a number of from 1 to 5, m is 0 or a number of from 1 to 20, n is a number of from 1 to 1,000 with the proviso that at least one OSiR.

Abstract: A process for preparing organopolysiloxane resins containing Si-bonded vinyl groups which comprises heating to a temperature of from about 85.degree. to 95.degree. C. a mixture containing (A) an organopolysiloxane having at least 0.1 percent by weight of Si-bonded hydroxyl groups and at least 50 mol percent of monoorganosiloxane units (RSiO.sub.3/2), (B) an organosiloxane containing from 2 to 10 silicon atoms per molecule, in which substantially all the silicon valences which are not satisfied by siloxane oxygen atoms, are satisfied by SiC-bonded hydrocarbon radicals, and having on the average at least two such hydrocarbon radicals for each silicon atom and at least one of the siloxanes (A) and/or (B) has an average of at least one SiC-bonded vinyl group, and (C) an acid activated bleaching clay; wherein the water released during the heating step by the condensation of Si-bonded hydroxyl groups is retained in the reactive mixture.

Abstract: Organopolysiloxane foams are prepared by heating a mixture containing (A) a diorganopolysiloxane, (B) silicon dioxide having a surface area of at least 50 m.sup.2 /g, (C) a peroxide compound, (D) at least one organosilicon compound containing at least 2 weight percent of Si-bonded hydroxyl groups and (E) at least one organopolysiloxane having Si-bonded hydrogen, to a temperature between 280.degree. and 320.degree. C. at a pressure which does not exceed the pressure of the surrounding atmosphere.

Abstract: Impression compositions containing (a) an organopolysiloxane having at least two alkenyl groups and containing at least 20 mol percent of monoorganosiloxane units, (b) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule, (c) a catalyst which promotes the addition of Si-bonded hydrogen atoms to alkenyl groups and (d) 30 to 90 percent by weight of a filler, based on the total weight of the composition. Impressions are obtained by applying a composition containing components (a), (b), (c) and (d) to a surface of which an impression is to be made, crosslinking said composition and thereafter removing the formed structure from the contacted surface.

Abstract: This invention relates to halogen platinum complexes of the formulaA.sub.2 PtX.sub.2 and/or C.sub.3 H.sub.6 PtB.sub.2 X.sub.2and a process for adding Si-bonded hydrogen to an aliphatic multiple bond in the presence of these halogen platinum complexes, in which A represents the same or different pyridine rings, which are substituted by one or two alkyl radicals having from 1 to 3 carbon atoms, B represents the same or different, 5- or 6-membered heterocyclics or linked 5- or 6-membered heterocyclics having 1 to 2 heteroatoms and X represents the same or different halogen atoms.

Abstract: Organosilanes containing aliphatic double bonds and a process for preparing the same which comprises reacting an organic compound having more than one aliphatic double bond with a silane having an Si-bonded hydrogen atom and at least one hydrolyzable group and/or at least one group capable of being hydrolyzed more readily than the Si-bonded hydrogen atom in the presence of a catalyst which promotes the addition of Si-bonded hydrogen atoms to aliphatic double bonds.These organosilanes are used as reinforcing agents for compositions containing organic polymers which are crosslinked by means of sulfur or free radicals.

Abstract: A process for preparing adhesive repellent coatings which comprises applying to the surface to be rendered adhesive repellent a mixture containing (1) a diorganopolysiloxane having an Si-bonded vinyl group in each of the terminal units, but is otherwise free of aliphatic unsaturation, (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule, (3) a vinylsiloxane platinum complex and (4) an organic or organosilicon compound which retards or delays the addition of Si-bonded hydrogen to aliphatic multiple bonds, said compound has a boiling point of at least 25.degree. C. at 760 mm Hg (absolute) and at least one aliphatic triple bond, and thereafter crosslinking the diorganopolysiloxane (1).

Abstract: A process for the addition of Si-bonded hydrogen to an aliphatic multiple bond in the presence of a platinum catalyst selected from the group consisting of______________________________________ I XPtY, II ##STR1## III APt(Y')X"and ______________________________________mixtures thereof, in which A is a halogen, X is a substituted or unsubstituted hydrocarbon radical having from 1 to 3 aliphatic double bonds which is bonded to the platinum atom via a PtC-sigma bond and a Pt-olefin-Pi-bond, X' is a hydrocarbon radical which is substituted with an alkoxy or acyloxy group and has from 1 to 3 double bonds and is bonded to the platinum atom via a PtC-sigma bond and a Pt-olefin-Pi-bond, X" is a substituted or unsubstituted hydrocarbon having an aliphatic double bond which is bonded to the platinum atom via a Pt-olefin-Pi-bond, Y is a chelate-like bonded beta-diketonate ligand or arylcarboxylate ligand, Y' is a beta-diketonate ligand and Z is a double link bridge ligand.