Abstract: Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, a method of producing crosslinked polymers using said curable compositions, crosslinked polymers thus produced, and orthodontic appliances comprising the crosslinked polymers.

Abstract: This disclosure provides low-viscosity resins for producing polymers with properties suitable for use in various mechanical appliances, such as orthodontic appliances (e.g., aligners). The low-viscosity resins may be photo-curable and can be used with direct fabrication methods and equipment. In various embodiments, the polymeric materials produced from the low-viscosity resins described herein have high toughness while remaining resistant to stress relaxation. Low-viscosity, photo-curable resins described herein have reduced hydrogen bonding in comparison to traditional materials (e.g., materials having high urethane content) used in orthodontic appliances.

Abstract: The present disclosure provides a range of printed materials comprising discrete layers or segment with distinct compositions, and which can collectively lend to high levels of strength, toughness, and break resistance, and these printed materials may contain thin, ductile layers interspersed between thicker, harder layers, thus in printing such materials, the present disclosure further provides a range of compositions and methods, including low viscosity, air stable, and rapidly solutions amenable to thin layer inkjet printing.

Abstract: Disclosed herein are dental attachment placement devices generated from curable compositions by additive manufacturing. The curable compositions contain a high crosslinker content, and after curing, yield tough and color neutral materials suitable for dental attachment placement devices.

Abstract: Disclosed herein are curable compositions containing an initiator and two or more crosslinkers for additive manufacturing. The curable compositions comprise high-crosslinker content, and yield tough, lightweight polymeric materials suitable for dental appliances, including but not limited to aligners, attachment placement devices, incremental palatal expanders, dentures, crowns, etc.

Abstract: Disclosed herein are methods for manufacturing medical devices, such as implants, joint replacements, graft materials, augmentation materials, prosthetic materials, etc., from solid material reinforced curable resins. Methods of repositioning a patient's teeth using such medical devices are also provided.

Abstract: Disclosed herein are curable compositions containing a plurality of polymerizable monomers comprising at least 80 wt % of a crosslinker for additive manufacturing. The curable compositions comprise high-crosslinker content, and yield tough, lightweight polymeric materials suitable for dental appliances, including but not limited to aligners, attachment placement devices, incremental palatal expanders, dentures, crowns, etc.

Abstract: Disclosed herein are curable resins comprising solid reinforcement materials and solid material reinforced polymeric materials formed by curing the curable resins using additive manufacturing. In various implements, the solid material reinforced polymeric materials may be used in medical devices such as implants, joint replacements, graft materials, augmentation materials, prosthetic materials, etc. to treat a patient.

Abstract: Provided herein are systems and processes to control multiple temperatures in additive manufacturing. Such temperature control adjusts polymer properties and facilitates processing of materials to form 3D objects. The systems and processed disclosed herein also facilitate the processing of typically difficult-to-process materials and deliver such materials to a photocuring zone configured to photopolymerize materials into 3 dimensional objects with a layer-by-layer process. Such processes can include the steps of heating a resin to a flowable temperature, applying the resin to a carrier, cooling the film to increase viscosity or to solidify the resin, and applying the film containing the resin onto an area being printed, then photocuring the film. Also provided herein are resins and related polymer materials having properties that are tunable with exposure to more than one temperature zone. The formed polymers can include multiple regions of polymer material, each independently having distinct properties.

Abstract: Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, a method of producing crosslinked polymers using said curable compositions, crosslinked polymers thus produced, and orthodontic appliances comprising the crosslinked polymers.

Abstract: The present disclosure provides multi-material orthodontic appliances useful for expanding a palate or arch of a patient, and, in some case, moving one or more teeth of the patient from a first to a second location according to a treatment plan. Further provided herein are methods for producing and using such multi-material orthodontic appliances on an individualized basis where each appliance is tailored to the specific treatment requirements of a patient.

Abstract: The present disclosure provides methods, systems, devices, and kits for creating composite materials from a single resin, the composite materials having multiple continuous phases. The disclosure includes a process to three-dimensionally print objects (e.g., orthodontic appliances) with composite properties. In some aspects, the composite properties are formed from a single formulation with components that, when processed, have hard and soft continuous phases. In some aspects, the composite properties are formed by separately processing the hard phase components and the soft phase components. In some aspects, the composite materials and devices are three-dimensionally printed using the processed material.

Abstract: Dental apparatuses, such as palatal expanders, and methods of forming them. The dental apparatuses may have multiple regions having different physical characteristics for performing different functions when worn by a patient as part of a dental treatment. The different regions may be made of different materials, or different combinations of materials, based on rigidity, flexibility and/or other physical characteristics. For palatal expanders, the different regions can include a tooth engagement region adapted to engage with the patient's teeth and a palatal region adapted to exert an expansion force across the patient's palate. The different regions may be joined together by a junction or a transition region configured to sufficiently hold adjacent regions together during use.

Abstract: Dental apparatuses, such as palatal expanders and aligners, and methods of forming them. The dental apparatuses may formed by printing different regions of the device with different properties, including hybrid regions formed between adjacent regions having different physical characteristics for performing different functions when worn by a patient as part of a dental treatment. The different regions may be joined together by a transition region configured to hold adjacent regions together during use and provide advantageous properties.

Abstract: Dental apparatuses, such as palatal expanders, attachment templates, mandibular repositioning aligners, and a variable property aligners, and methods of forming them. The dental apparatuses may have multiple regions having different physical characteristics for performing different functions when worn by a patient as part of a dental treatment. The different regions may be made of different materials, or different combinations of materials, based on rigidity, flexibility and/or other physical characteristics. The different regions may be joined together by a junction region configured to sufficiently hold adjacent regions together during use.

Abstract: Provided herein are systems and processes to control multiple temperatures in additive manufacturing. Such temperature control adjusts polymer properties and facilitates processing of materials to form 3D objects. The systems and processed disclosed herein also facilitate the processing of typically difficult-to-process materials and deliver such materials to a photocuring zone configured to photopolymerize materials into 3 dimensional objects with a layer-by-layer process. Such processes can include the steps of heating a resin to a flowable temperature, applying the resin to a carrier, cooling the film to increase viscosity or to solidify the resin, and applying the film containing the resin onto an area being printed, then photocuring the film. Also provided herein are resins and related polymer materials having properties that are tunable with exposure to more than one temperature zone. The formed polymers can include multiple regions of polymer material, each independently having distinct properties.

Abstract: This disclosure provides low-viscosity resins for producing polymers with properties suitable for use in various mechanical appliances, such as orthodontic appliances (e.g., aligners). The low-viscosity resins may be photo-curable and can be used with direct fabrication methods and equipment. In various embodiments, the polymeric materials produced from the low-viscosity resins described herein have high toughness while remaining resistant to stress relaxation. Low-viscosity, photo-curable resins described herein have reduced hydrogen bonding in comparison to traditional materials (e.g., materials having high urethane content) used in orthodontic appliances.

Abstract: Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, a method of producing crosslinked polymers using said curable compositions, crosslinked polymers thus produced, and orthodontic appliances comprising the crosslinked polymers.

Abstract: Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, a method of producing crosslinked polymers using said curable compositions, crosslinked polymers thus produced, and orthodontic appliances comprising the crosslinked polymers.