Abstract: Water soluble catalysts, (M)meso-tetra(N-Methyl-4-Pyridyl)Porphinepentachloride (M=Fe, Co, Mn & Cu), have been incorporated into the polymer binder of oxygen reduction cathodes in membrane electrode assemblies used in PEM fuel cells and found to support encouragingly high current densities. The voltages achieved are low compared to commercial platinum catalysts but entirely consistent with the behavior observed in electroanalytical measurements of the homogeneous catalysts. A model of the dynamics of the electrode action has been developed and validated and this allows the MEA electrodes to be optimized for any chemistry that has been demonstrated in solution. It has been shown that improvements to the performance will come from modifications to the structure of the catalyst combined with optimization of the electrode structure and a well-founded pathway to practical non-platinum group metal catalysts exists.

Abstract: Water soluble catalysts, (M)meso-tetra(N-Methyl-4-Pyridyl)Porphinepentachloride (M=Fe, Co, Mn & Cu), have been incorporated into the polymer binder of oxygen reduction cathodes in membrane electrode assemblies used in PEM fuel cells and found to support encouragingly high current densities. The voltages achieved are low compared to commercial platinum catalysts but entirely consistent with the behavior observed in electroanalytical measurements of the homogeneous catalysts. A model of the dynamics of the electrode action has been developed and validated and this allows the MEA electrodes to be optimized for any chemistry that has been demonstrated in solution. It has been shown that improvements to the performance will come from modifications to the structure of the catalyst combined with optimization of the electrode structure and a well-founded pathway to practical non-platinum group metal catalysts exists.

Abstract: A computer network system containing a concentrator with a backplane that has a plurality of lines. The backplane contains data lines and control lines for managing and organizing the transfer of data between modules in the concentrator. The system contains intelligent devices that allow the selection of transmitting modules to occur at the same time as actual data transfer is going on between other modules. This is preferably done in a round robin arbitration process where, while data is being transferred by a first module, a bus arbitration device is placing addresses of modules which sequentially follow the transmitting module onto the control lines. Modules will see their address on the control lines, and if they have a packet to transmit, they then reserve the right to transmit after the presently transmitting module is finished. In this way the selection of the next module to transmit is performed in parallel, and does not slow down, the transfer of data between modules.