Abstract: The introduction of dielectric material of enhanced mechanical stability, such as silicon dioxide or fluorine-doped silicon dioxide, into the via level of a low-k interconnect structure provides an increased overall mechanical stability, especially during the packaging of the device. Consequently, cracking and delamination, as frequently observed in high end low-k interconnect structures, may significantly be reduced, even if organic package substrates are used.

Abstract: In a dual stress liner approach, an intermediate etch stop material may be provided on the basis of a plasma-assisted oxidation process rather than by deposition so the corresponding thickness of the etch stop material may be reduced. Consequently, the resulting aspect ratio may be less pronounced compared to conventional strategies, thereby reducing deposition-related irregularities which may translate into a significant reduction of yield loss, in particular for highly scaled semiconductor devices.

Abstract: An alloy forming dopant material is deposited prior to the formation of a copper line, for instance by incorporating the dopant material into the barrier layer, which is then driven into the vicinity of a weak interface by means of a heat treatment. As indicated by corresponding investigations, the dopant material is substantially transported to the weak interface through grain boundary regions rather than through the bulk copper material (copper grains), thereby enabling moderately high alloy concentrations in the vicinity of the interface while maintaining a relatively low overall concentration within the grains. The alloy at the interface reduces electromigration along the interface.

Abstract: In a dual stress liner approach, an intermediate etch stop material may be provided on the basis of a plasma-assisted oxidation process rather than by deposition so the corresponding thickness of the etch stop material may be reduced. Consequently, the resulting aspect ratio may be less pronounced compared to conventional strategies, thereby reducing deposition-related irregularities which may translate into a significant reduction of yield loss, in particular for highly scaled semiconductor devices.

Abstract: By using a non-metallic hard mask for patterning low-k dielectric materials of advanced semiconductor devices, an enhanced degree of etch fidelity is obtained. The present invention may readily be applied to via first-trench last, trench first-via last schemes.

Abstract: During the formation of a metallization layer of a semiconductor device, a cap layer is formed above a metal line and subsequently an implantation process is performed so as to modify the metal in the vicinity of the interface between the cap layer and the metal line. Consequently, an improved behavior in view of electromigration of the metal line may be obtained, thereby increasing device reliability.

Abstract: By providing a stiffening layer at three sidewalls of a trench to be filled with a copper-containing metal, the reduced thermomechanical confinement of a low-k material may be compensated for, at least to a certain degree, thereby reducing electromigration effects and hence increasing lifetime of sophisticated semiconductor devices having metallization layers including low-k dielectric materials in combination with copper-based metal lines.

Abstract: In a method of forming a semiconductor structure, an opening is formed in a layer of a dielectric material provided over an electrically conductive feature. An etching process is performed in order to form a recess in the electrically conductive feature. The bottom of the recess may have a rounded shape. The recess and the opening are filled with an electrically conductive material. Due to the provision of the recess, electromigration, stress migration and a local heating of the semiconductor structure, which may adversely affect the functionality of the semiconductor structure, can be reduced.

Abstract: By using a non-metallic hard mask for patterning low-k dielectric materials of advanced semiconductor devices, an enhanced degree of etch fidelity is obtained. The present invention may readily be applied to via first-trench last, trench first-via last schemes.

Abstract: A cleaning process for cleaning the surface of a substrate is disclosed, wherein the surface comprises portions of a dielectric material and portions of a conductive material. According to the method disclosed, the temperature at the surface of the substrate is kept below a predefined value during the actual cleaning step in a reactive and/or inert plasma ambient, such as an argon gas ambient, wherein the predefined value corresponds to the surface temperature at which agglomeration of the conductive material occurs.

Abstract: The invention provides a technique of monitoring the void formation in a damascene interconnection process. According to the invention, a test structure is provided that includes at least two damascene structures that have at least one different cross-sectional geometric parameter. To monitor the void formation, the test structure is cut to expose a cross-sectional view to the damascene structures. The cross-sectional view is then inspected and the void formation is investigated in each of the damascene structures. The invention is particularly applicable to multi-level copper-based dual-damascene interconnection processes to monitor the voiding at the interface between barrier layers and bottom metal trenches. The invention allows monitoring of the void formation by locating only one structure on the chip and performing only one cut.

Abstract: The introduction of dielectric material of enhanced mechanical stability, such as silicon dioxide or fluorine-doped silicon dioxide, into the via level of a low-k interconnect structure provides an increased overall mechanical stability, especially during the packaging of the device. Consequently, cracking and delamination, as frequently observed in high end low-k interconnect structures, may significantly be reduced, even if organic package substrates are used.

Abstract: A cleaning process for cleaning the surface of a substrate is disclosed, wherein the surface comprises portions of a dielectric material and portions of a conductive material. According to the method disclosed, the temperature at the surface of the substrate is kept below a predefined value during the actual cleaning step in a reactive and/or inert plasma ambient, such as an argon gas ambient, wherein the predefined value corresponds to the surface temperature at which agglomeration of the conductive material occurs.

Abstract: An alloy forming dopant material is deposited prior to the formation of a copper line, for instance by incorporating the dopant material into the barrier layer, which is then driven into the vicinity of a weak interface by means of a heat treatment. As indicated by corresponding investigations, the dopant material is substantially transported to the weak interface through grain boundary regions rather than through the bulk copper material (copper grains), thereby enabling moderately high alloy concentrations in the vicinity of the interface while maintaining a relatively low overall concentration within the grains. The alloy at the interface reduces electromigration along the interface.

Abstract: During the formation of a metallization layer of a semiconductor device, a cap layer is formed above a metal line and subsequently an implantation process is performed so as to modify the metal in the vicinity of the interface between the cap layer and the metal line. Consequently, an improved behavior in view of electromigration of the metal line may be obtained, thereby increasing device reliability.

Abstract: A copper line that is formed in a patterned dielectric layer has a copper/silicon film formed on a surface thereof to substantially suppress an electromigration path through this surface. In an in situ process, the exposed copper surface is first cleaned by a reactive plasma ambient including nitrogen and ammonia and after a certain clean period, a gaseous compound comprising silicon, for example silane, is added to the reactive plasma ambient to form the copper/silicon film. Additionally, a capping layer may be deposited, wherein due to the copper/silicon film, any deposition technique or even spin-coating may be used.

Abstract: For determining the quality of interconnections in integrated circuits, especially in damascene applications, a method of monitoring voids is disclosed, wherein a barrier metal layer is directly deposited on a planarized metal to provide a large-area surface that is not required to be destroyed for further analysis of the interface between the metal and the barrier metal layer. The analysis may be carried out by employing an electron microscope operated in a back-scatter mode.

Abstract: In an in situ damascene metallization process employing a barrier layer between the metal and the dielectric, the generation of voids, especially at the bottom of vias, can be significantly reduced or even completely avoided by maintaining the surface temperature below a critical temperature during deposition of the barrier material.

Abstract: In a method of removing oxidized and discolored portions from a copper surface, a mixture of a reactive gas, such as NH3, and of a purge gas, such as N2, is used with a relatively low high-frequency power to substantially remove all of the copper oxide from the surface. Preferably, a silicon-containing capping layer is subsequently formed on the copper surface, wherein the deposition process can be performed immediately after the surface treatment step without any additional transition step, since the process conditions within the reaction chamber, required for the deposition, are already established.