Abstract: Disclosed herein are polysaccharide-elastomer masterbatch compositions and processes for preparing the masterbatch compositions. One method comprises a step of a) mixing i) an aqueous polysaccharide dispersion, or ii) a basic aqueous polysaccharide solution, with a rubber latex solution containing a rubber component to form a mixture. The method further comprises the steps of: b) coagulating the mixture obtained in step a) to produce a coagulated mass; and c) drying the coagulated mass obtained in step b). The masterbatch compositions are useful in preparing rubber-containing articles.

Abstract: Disclosed herein are coated articles comprising a substrate having at least one surface, and a coating composition disposed in a substantially continuous layer on at least one surface of the substrate, wherein the coating composition is present in an amount sufficient to increase the oxygen barrier property of the substrate, and the coating composition comprises a polysaccharide derivative. The polysaccharide derivative can comprise a poly alpha-1,3-glucan ether compound, such as a quaternary ammonium alpha-1,3-glucan ether. Also disclosed is packaging comprising the coated article.

Abstract: Compositions are disclosed herein comprising a cellulose substrate, wherein at least a portion of the cellulose substrate is coated with a layer of a coating composition that comprises at least (i) rubber or other diene-based elastomer, and (ii) an insoluble alpha-glucan, wherein at least about 50% of the glycosidic linkages of the alpha-glucan are alpha-1,3 linkages.

Abstract: Disclosed herein are polysaccharide-elastomer masterbatch compositions and processes for preparing the masterbatch compositions. One method comprises a step of a) mixing i) an aqueous polysaccharide dispersion, or ii) a basic aqueous polysaccharide solution, with a rubber latex solution containing a rubber component to form a mixture. The method further comprises the steps of: b) coagulating the mixture obtained in step a) to produce a coagulated mass; and c) drying the coagulated mass obtained in step b). The masterbatch compositions are useful in preparing rubber-containing articles.

Abstract: Disclosed herein are polyurethane polymers comprising at least one polyisocyanate, a polysaccharide comprising: poly alpha-1,3-glucan; a poly alpha-1,3-glucan ester compound as disclosed herein; poly alpha-1,3-1,6-glucan; water-insoluble alpha-(1,3-glucan) polymer having 90% or greater alpha-1,3-glycosidic linkages, less than 1% by weight of alpha-1,3,6-glycosidic branch points, and a number average degree of polymerization in the range of from 55 to 10,000; dextran; or a poly alpha-1,3-glucan ether compound as disclosed herein; and optionally, at least one polyol. Also disclosed are polyurethane compositions comprising the polyurethane polymer and a solvent, as well as polyurethane foams, adhesives, coatings, films, and coated fibrous substrates comprising the polyurethane polymer.

Abstract: A process is disclosed herein comprising the steps: a) contacting an esterifying agent and a polysaccharide in the presence of a first solvent and suitable reaction conditions for a reaction time sufficient to form a product comprising a polysaccharide ester composition, the polysaccharide ester composition comprising a polysaccharide ester having a degree of substitution of about 0.001 to about 3; wherein the esterifying agent comprises an acyl halide, a phosphoryl halide, a carboxylic acid anhydride, a haloformic acid ester, a carbonic acid ester, or a vinyl ester; and the ratio of esterifying agent to polysaccharide is in the range of about 0.001:1 to about 3:1 on a molar equivalent basis; b) combining the product obtained in step a) with polyacrylonitrile; and c) spinning fibers.

Abstract: Disclosed herein are nonwoven webs comprising a nonwoven substrate and a binder comprising a polysaccharide. In one embodiment, the polysaccharide can comprise poly alpha-1,3-glucan, a poly alpha-1,3-glucan ether compound as disclosed herein, a poly alpha-1,3-glucan ester compound as disclosed herein, a graft copolymer comprising a backbone comprising dextran and poly alpha-1,3-glucan side chains, a crosslinked graft copolymer comprising a backbone comprising dextran and poly alpha-1,3-glucan chains, or a mixture thereof. Also disclosed are articles comprising the nonwoven webs, and methods of making the nonwoven webs.

Abstract: Disclosed herein are polysaccharide-elastomer masterbatch compositions and processes for preparing the masterbatch compositions. One method comprises a step of a) mixing i) an aqueous polysaccharide dispersion, or ii) a basic aqueous polysaccharide solution, with a rubber latex solution containing a rubber component to form a mixture. The method further comprises the steps of: b) coagulating the mixture obtained in step a) to produce a coagulated mass; and c) drying the coagulated mass obtained in step b). The masterbatch compositions are useful in preparing rubber-containing articles.

Abstract: Compositions are disclosed herein comprising a rubber component and a polysaccharide, wherein the polysaccharide comprises i) poly alpha-1,3-glucan; ii) poly alpha-1,3-1,6-glucan; iii) water insoluble alpha-(1,3-glucan) polymer having 90% or greater ?-1,3-glycosidic linkages, less than 1% by weight of alpha-1,3,6-glycosidic branch points, and a number average degree of polymerization in the range of from 55 to 10,000; iv) dextran; v) a composition comprising poly alpha-1,3-glucan ester compounds as disclosed herein; or vi) water-insoluble cellulose having a weight-average degree of polymerization (DPw) of about 10 to about 1000 and a cellulose II crystal structure. The compositions can be used in articles such as a tire, a belt, a seal, footwear, a coating, a film, or an adhesive.

Abstract: Disclosed herein are aqueous latex compositions comprising polysaccharide particles and a polymer dispersion or polymer emulsion. In one embodiment the polysaccharide particles comprise poly alpha-1,3-glucan. Also disclosed are an adhesive, film, coating, or binder comprising the latex composition in a dry form, as well as articles comprising the adhesive, film, coating, or binder.

Abstract: Disclosed herein are coated articles comprising a substrate having at least one surface, and a coating composition disposed in a substantially continuous layer on at least one surface of the substrate, wherein the coating composition is present in an amount sufficient to increase the oxygen barrier property of the substrate, and the coating composition comprises a polysaccharide derivative. The polysaccharide derivative can comprise a poly alpha-1,3-glucan ether compound, such as a quaternary ammonium alpha-1,3-glucan ether. Also disclosed is packaging comprising the coated article.

Abstract: Disclosed herein are polysaccharide-elastomer masterbatch compositions and processes for preparing the masterbatch compositions. One method comprises a step of a) mixing i) an aqueous polysaccharide dispersion, or ii) a basic aqueous polysaccharide solution, with a rubber latex solution containing a rubber component to form a mixture. The method further comprises the steps of: b) coagulating the mixture obtained in step a) to produce a coagulated mass; and c) drying the coagulated mass obtained in step b). The masterbatch compositions are useful in preparing rubber-containing articles.

Abstract: Disclosed herein are nonwoven webs comprising a nonwoven substrate and a binder comprising a polysaccharide. In one embodiment, the polysaccharide can comprise poly alpha-1,3-glucan, a poly alpha-1,3-glucan ether compound as disclosed herein, a poly alpha-1,3-glucan ester compound as disclosed herein, a graft copolymer comprising a backbone comprising dextran and poly alpha-1,3-glucan side chains, a crosslinked graft copolymer comprising a backbone comprising dextran and poly alpha-1,3-glucan chains, or a mixture thereof. Also disclosed are articles comprising the nonwoven webs, and methods of making the nonwoven webs.

Abstract: Molded articles are disclosed herein, the molded article comprising a polysaccharide, wherein the polysaccharide comprises i) poly alpha-1,3-glucan; ii) poly alpha-1,3-1,6-glucan; iii) a graft copolymer that comprises (A) a backbone comprising dextran with a weight-average molecular weight (Mw) of at least about 100000 Daltons, and (B) poly alpha-1,3-glucan side chains comprising at least about 95% alpha-1,3-glucosidic linkages; or iv) a composition comprising a poly alpha-1,3-glucan ester compound as disclosed herein. Optionally, the molded articles can further comprise a plasticizer and/or starch. The molded articles can be useful as a container, a handle, packaging, a tray, a bottle, a cup, a sheet, a disposable food packaging item, an automotive part, a casing for an electronic device, or a toy.

Abstract: Disclosed herein are coated articles comprising a substrate having at least one surface, and a coating composition disposed in a substantially continuous layer on at least one surface of the substrate, wherein the coating composition is present in an amount sufficient to increase the oxygen barrier property of the substrate, and the coating composition comprises a polysaccharide derivative. The polysaccharide derivative can comprise a poly alpha-1,3-glucan ether compound, such as a quaternary ammonium alpha-1,3-glucan ether. Also disclosed is packaging comprising the coated article.

Abstract: Compositions are disclosed herein comprising a rubber component and a polysaccharide, wherein the polysaccharide comprises i) poly alpha-1,3-glucan; ii) poly alpha-1,3-1,6-glucan; iii) water insoluble alpha-(1,3-glucan) polymer having 90% or greater ?-1,3-glycosidic linkages, less than 1% by weight of alpha-1,3,6-glycosidic branch points, and a number average degree of polymerization in the range of from 55 to 10,000; iv) dextran; v) a composition comprising poly alpha-1,3-glucan ester compounds as disclosed herein; or vi) water-insoluble cellulose having a weight-average degree of polymerization (DPw) of about 10 to about 1000 and a cellulose II crystal structure. The compositions can be used in articles such as a tire, a belt, a seal, footwear, a coating, a film, or an adhesive.

Abstract: A process is disclosed herein comprising the steps: a) contacting an esterifying agent and a polysaccharide in the presence of a first solvent and suitable reaction conditions for a reaction time sufficient to form a product comprising a polysaccharide ester composition, the polysaccharide ester composition comprising a polysaccharide ester having a degree of substitution of about 0.001 to about 3; wherein the esterifying agent comprises an acyl halide, a phosphoryl halide, a carboxylic acid anhydride, a haloformic acid ester, a carbonic acid ester, or a vinyl ester; and the ratio of esterifying agent to polysaccharide is in the range of about 0.001:1 to about 3:1 on a molar equivalent basis; b) combining the product obtained in step a) with polyacrylonitrile; and c) spinning fibers.

Abstract: Poly alpha-1,3-glucan ester compounds are disclosed herein with a degree of substitution of about 0.001 to about 3.0. Also disclosed are methods of producing poly alpha-1,3-glucan ester compounds using cyclic organic anhydrides.

Abstract: Disclosed herein are coated articles comprising a substrate having at least one surface, and a coating composition disposed in a substantially continuous layer on at least one surface of the substrate, wherein the coating composition is present in an amount sufficient to increase the oxygen barrier property of the substrate, and the coating composition comprises a polysaccharide derivative. The polysaccharide derivative can comprise a poly alpha-1,3-glucan ether compound, such as a quaternary ammonium alpha-1,3-glucan ether. Also disclosed is packaging comprising the coated article.

Abstract: Disclosed herein are nonwoven webs comprising a nonwoven substrate and a binder comprising a polysaccharide. In one embodiment, the polysaccharide can comprise poly alpha-1,3-glucan, a poly alpha-1,3-glucan ether compound as disclosed herein, a poly alpha-1,3-glucan ester compound as disclosed herein, a graft copolymer comprising a backbone comprising dextran and poly alpha-1,3-glucan side chains, a crosslinked graft copolymer comprising a backbone comprising dextran and poly alpha-1,3-glucan chains, or a mixture thereof. Also disclosed are articles comprising the nonwoven webs, and methods of making the nonwoven webs.