Abstract: Novel metallic bodies are provided which present an essentially oxide-free surface protected by phosphate groups which directly and chemically bond to surface metal atoms. Metal surfaces such as Al or Fe can be protected by deposition of a phosphate film directly onto etched metal surfaces without intermediate naturally occurring oxides between the metal ions and protective phosphate groups. Preferably, metallic surfaces to be protected are first etched to remove oxides and other contaminants, followed by electrochemical treatment with a phosphate electrolyte to generate a protective film having a thickness of from about 20-100 .ANG. which is stable in ambient air.