Abstract: Provided are new compositions of matter for host materials in OLEDs by incorporating deuterated moieties in the organic molecules. Also provided are formulations comprising these deuterated compounds. Further provided are OLEDs and related consumer products that utilize these deuterated compounds.

Abstract: Provided are compounds having Formula I: wherein rings A, B, C, D, E, and F are each independently a single or fused ring system, consisting of one or more 5-membered or 6-membered carbocyclic or heterocyclic rings; L1, L2, L3, L4, L5, and L6 are each independently optionally present or is selected from the group consisting of O, S, Se, BR, BRR?, NR, C?R, CRR?, SiRR?, P(O)R, and GeRR?; a, b, c, d, e and f are each O for not present or 1 for present; each of R, R?, R1, R2, R3, R4, R5, and R6 is independently a hydrogen or a substituent; and any two of adjacent R, R?, R1, R2, R3, R4, R5, and R6 can be joined or fused to form a ring. Also provided are formulations comprising these compounds. Further provided are OLEDs and related consumer products that utilize these compounds.

Abstract: Provided are organometallic compounds. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

Abstract: A compound of Formula I, is provided. In Formula I; ring A is a 5-membered or 6-membered aromatic ring; wherein Y1 is absent or a linking group; each of X1 to X3 is N or CR, and at least one of X1 to X3 is N; each of A1 to A5 is C or N; each R1, R2, R3, and R4 is independently selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof, and each R, R?, RA, RB, and RC is hydrogen or a General Substituent; and the compound is partially or fully deuterated.

Abstract: Provided are organometallic compounds that include a ligand LA of that are useful as emitters in OLEDs. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

Abstract: Tetradentate platinum complexes including an imidazole/benzimidazole carbene having a structure of Formula I is disclosed. In Formula I, M is Pd or Pt. These platinum carbenes with the specific substituents disclosed herein are novel and provides phosphorescent emissive compounds that exhibit physical properties that can be tuned, such as sublimation temperature, emission color, and device stability.

Abstract: Provided are boron-containing compounds. Also provided are formulations comprising these boron-containing compounds. Further provided are OLEDs and related consumer products that utilize these boron-containing compounds.

Abstract: A compound comprising a first ligand LA comprising a structure of Formula I, ?is provided. In Formula I, moieties A, B, C, and D are each independently a monocyclic ring or a multicyclic fused ring system; each of X1 to X8 is C or N; each independently represents a single bond or a double bond; each of L1, L2, L3, and L4 is independently a direct bond or a linking group; each R, R?, R?, RA, RB, RC, and RD is a hydrogen or a General Substituent; any two adjacent R, R?, R?, RA, RB, RC, and RD may be joined or fused to form a ring; and LA is coordinated to a transition metal M. Formulations, OLEDs, and consumer products containing the compound are also provided.

Abstract: Provided are new compositions of matter for host materials in OLEDs by incorporating deuterated moieties in the organic molecules. Also provided are formulations comprising these deuterated compounds. Further provided are OLEDs and related consumer products that utilize these deuterated compounds.

Abstract: A compound of Formula I wherein X1 to X8 are independently selected from C or N, and Y is selected from the group consisting of NR2, O, S, Se, CR3R4, SiR3R4, and GeR3R4. RA and RB represent mono to the maximum allowable substitution, or no substitution. The compounds of Formula I will also have at least one of RA, RB, R1, R2, R3, or R4 that comprises a structure selected from the group consisting of formula A, formula B, and formula C as described herein. In n the structures of formula A, formula B, or formula C, Z is selected from the group consisting of NR5, O, S, Se, CR6R7, SiR6R7, and GeR6R7; wherein R5 is a substituent selected from the group consisting of deuterium, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof; or optionally, R5 is an aromatic linker that connects the structure of formula A to Formula I, or the structure of formula C to Formula I.

Abstract: Provided are boron-containing compounds. Also provided are formulations comprising these boron-containing compounds. Further provided are OLEDs and related consumer products that utilize these boron-containing compounds.

Abstract: Provided are organic polycyclic compounds comprising a fused ring system of at least three rings which are fused together, of which at least one ring is a 6-membered aromatic ring. Also provided are formulations comprising these organic polycyclic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organic polycyclic compounds.

Abstract: The subject application relates to organic electroluminescent materials and devices. A compound is provided that has a structure including Formula I, In Formula I, ring A is a 5-membered or 6-membered ring; each of moiety B and C is a monocyclic ring or a polycyclic fused ring system; metal M is Pt or Pd; each of Z1, Z2, and X1 to X14 is C or N; each of K1, K2, and K3 is a direct bond or a linker; each of L1, L2, and L3 is a direct bond or a linker; each R substituent is hydrogen or a General Substituent defined herein; each of R1 and RF is a General Substituent defined herein; and any two substituents can be joined or fused to form a ring. Formulations, OLEDs, and consumer products containing the compound are also provided.

Abstract: A compound comprising a ligand LA comprising a moiety L having a structure of Formula I is provided. In Formula I, LA coordinated to a metal M; A1 is selected from B, N, P, P?O, P?S, Al, Ga, SiR?, GeR?, and SnR?; where rings A, B, and C are 5- or 6-membered rings; Y1, Y2, and Y3 are selected from direct bonds, the metal M, and a variety of linkers; a+b+c=2 or 3; and one of a number of specific conditions is met. OLED devices, consumer products, and formulations including the compound are also provided.

Abstract: A compound comprising a ligand LA comprising a moiety L having a structure of Formula I is provided. In Formula I, LA coordinated to a Ir atom; A1 is selected from B, N, P, P?O, P?S, Al, Ga, SiR?, GeR?, and SnR?; where rings A, B, and C are 5- or 6-membered rings; Y1, Y2, and Y3 are selected from direct bonds, the Ir atom, and a variety of linkers; a+b+c=2 or 3; and one of a number of specific conditions is met. OLED devices, consumer products, and formulations including the compound are also provided.

Abstract: A compound having a structure of Formula I, is provided. In Formula I, Z1 to Z16 are each CR or N; three consecutive ones of Z1 to Z16 within the same ring cannot be N; each R is independently a hydrogen or a substituent selected from a variety of substituents; at least one R includes and electron donor substituent; at least one R includes an electron acceptor substituent; and any two Rs on the same ring can be joined or fused together to form a ring. Organic light emitting devices, consumer products, formulations, and chemical structures containing the compounds are also disclosed.

Abstract: Provided are compounds comprising a ligand LA of Formula I where the ligand LA is coordinated to Pt.

Abstract: A compound comprising a ligand LA comprising a moiety L having a structure of Formula I is provided. In Formula I, LA coordinated to a metal M; A1 is selected from B, N, P, P?O, P?S, Al, Ga, SiR?, GeR?, and SnR?; where rings A, B, and C are 5- or 6-membered rings; Y1, Y2, and Y3 are selected from direct bonds, the metal M, and a variety of linkers; a+b+c=2 or 3; and one of a number of specific conditions is met. OLED devices, consumer products, and formulations including the compound are also provided.

Abstract: Provided are organic compounds comprising a central 7-membered or 8-membered ring comprising at least one boron atom and to which at least three 5-membered to 10-membered carbocyclic or heterocyclic rings are fused. Also provided are formulations comprising these organic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organic compounds.

Abstract: Provided are novel compounds having a structure of Formula II that are useful as emitters in OLEDs.