Patents by Inventor Philibert Leflaive

Philibert Leflaive has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10125064
    Abstract: The invention relates to a method for separating meta-xylene from C8 aromatic fractions, using a zeolitic adsorbent based on sodium-exchanged or sodium-and-lithium-exchanged agglomerated crystals of zeolite Y, with a large external surface area.
    Type: Grant
    Filed: August 4, 2015
    Date of Patent: November 13, 2018
    Assignees: IFP ENERGIES NOUVELLES, ARKEMA FRANCE
    Inventors: Catherine Laroche, Philibert Leflaive, Arnaud Baudot, Ludivine Bouvier, Cecile Lutz, Serge Nicolas
  • Patent number: 10112182
    Abstract: A catalytic adsorbent, comprising at least cobalt and molybdenum deposited on a porous substrate in which the content of cobalt, expressed in terms of CoO oxide, is between 11 and 30% by weight relative to the total weight of said adsorbent and the content of molybdenum, expressed in terms of MoO3 oxide, is between 3 and 30% by weight relative to the total weight of said adsorbent, is described. This invention also relates to a process for hydrotreatment using said catalytic adsorbent.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: October 30, 2018
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Philibert Leflaive, Marie Claire Marion, Antoine Daudin
  • Patent number: 10072220
    Abstract: The invention of the current application is a process for eliminating arsenic from a hydrocarbon feed which is at least partially liquid, including steps a and b. Step a includes bringing the hydrocarbon feed and hydrogen into contact with a first capture mass including a support and at least one metal M1 from group VIB and at least two metals M2 and M3 from group VIII. Step b includes bringing the hydrocarbon feed and hydrogen into contact with a second capture mass in the sulphide form including a support and nickel, the quantity of nickel being at least 5% by weight of NiO with respect to the total weight of the second capture mass. Step a) is either carried out before step b) or carried out simultaneously with step b).
    Type: Grant
    Filed: June 17, 2014
    Date of Patent: September 11, 2018
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Marie-Claire Marion, Philibert Leflaive, Annick Pucci
  • Patent number: 10035739
    Abstract: The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units.
    Type: Grant
    Filed: June 10, 2015
    Date of Patent: July 31, 2018
    Assignee: IFP Energies nouvelles
    Inventors: Heloise Dreux, Philibert Leflaive, Damien Leinekugel Le Cocq
  • Patent number: 10029958
    Abstract: The present invention describes a process for the production of high-purity paraxylene from a xylenes cut containing xylenes and ethylbenzene, a process using two simulated moving bed separation units and two isomerization units.
    Type: Grant
    Filed: June 10, 2015
    Date of Patent: July 24, 2018
    Assignee: IFP Energies nouvelles
    Inventors: Heloise Dreux, Philibert Leflaive, Damien Leinekugel Le Cocq
  • Patent number: 10000430
    Abstract: A process for separating propylene mixed with propane by adsorption in a simulated moving bed is described. The process operates in the gaseous phase or in the liquid phase, and it uses a 13X faujasite-type zeolite as adsorbent solid and butene-1 or isobutane or any mixture of these 2 components as desorbent.
    Type: Grant
    Filed: May 27, 2015
    Date of Patent: June 19, 2018
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Philibert Leflaive, Luc Wolff, Damien Leinekugel Le Cocq, Nabil Lamia, Alirio Rodrigues, Carlos Grande
  • Publication number: 20180161754
    Abstract: The present invention relates to zeolitic adsorbents based on agglomerated crystals of FAU zeolite containing barium and/or potassium, with large external surface area, combining optimum properties in terms of selectivity and mechanical strength. These adsorbents find applications in the separation of cuts of C8-aromatic isomers and notably of xylenes, in the separation of isomers of substituted toluene such as nitrotoluene, diethyltoluene, toluenediamine, in the separation of cresols, and in the separation of polyhydric alcohols such as sugars.
    Type: Application
    Filed: January 25, 2018
    Publication date: June 14, 2018
    Applicants: Arkema France, IFP Energies Nouvelles
    Inventors: Catherine Laroche, Philibert LEFLAIVE, Ludivine BOUVIER, Serge NICOLAS, Cecile LUTZ, Marie-Laurence LABEDE
  • Publication number: 20180148658
    Abstract: A process reducing sulfides R1-S—R2, with R1 and R2 methyl or ethyl, in a gasoline containing diolefins, mono-olefins and sulphur: A) contacting gasoline in mixture with a light gasoline cut recycled from C) and hydrogen in a reactor with catalyst A at least one VIb metal and at least one non noble group VIII metal on a support, producing effluent having diolefins and sulfides R1-S—R2, with R1 and R2 methyl or ethyl radicals lower than that that of the starting gasoline; B) the effluent from A) is sent into a fractionating column separating at the top a light gasoline cut containing hydrocarbons having less than 6 carbon atoms per molecule and at the bottom a heavy gasoline cut containing hydrocarbons having 6 and more than 6 carbon atoms per molecule; C) recycling a part of the light gasoline from B) to the reactor of A) with a recycle ratio 0.1 to 0.7.
    Type: Application
    Filed: February 17, 2016
    Publication date: May 31, 2018
    Applicant: IFP Energies nouvelles
    Inventors: Philibert LEFLAIVE, Clementina LOPEZ GARCIA, Julien GORNAY, Annick PUCCI, Diamantis ASTERIS, Marie GODARD-PITHON
  • Patent number: 9957448
    Abstract: The present application concerns a process for the treatment of a gasoline containing sulphur-containing compounds and olefins, with the following steps: a) a step for hydrodesulphurization of said gasoline in order to produce an effluent which is depleted in sulphur by passing the gasoline mixed with hydrogen over at least one hydrodesulphurization catalyst; b) a step for separating the partially desulphurized gasoline from the hydrogen introduced in excess as well as the H2S formed during step a); c) a catalytic step for sweetening desulphurized gasoline obtained from step b), which converts residual mercaptans into thioethers via an addition reaction with the olefins.
    Type: Grant
    Filed: June 17, 2014
    Date of Patent: May 1, 2018
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Julien Gornay, Philibert LeFlaive, Annick Pucci, Olivier Touzalin
  • Publication number: 20180105756
    Abstract: A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins: a) fractionating the gasoline into at least: a light gasoline cut LCN; a primary intermediate gasoline cut, MCN; and a primary heavy gasoline cut HHCN; b) desulphurizing the primary intermediate gasoline cut MCN alone producing an at least partially desulphurized primary intermediate gasoline cut MCN; c) desulphurizing the primary heavy gasoline cut HHCN alone producing an at least partially desulphurized primary heavy gasoline cut HHCN; d) sending, as a mixture, the partially desulphurized primary intermediate gasoline cut MCN and the partially desulphurized primary heavy gasoline cut HHCN to a separation column separating a gaseous stream containing hydrogen and H2S, a secondary intermediate gasoline cut MCN with low sulphur and mercaptans contents and a secondary heavy gasoline cut HHCN containing sulphur-containing compounds including recombinant mercaptans; e) desulphurizing the secondary heavy g
    Type: Application
    Filed: October 19, 2017
    Publication date: April 19, 2018
    Applicant: IFP Energies nouvelles
    Inventors: Adrien GOMEZ, Philibert LEFLAIVE, Clementina LOPEZ GARCIA, Annick PUCCI, Marie GODARD-PITHON, Jean-Luc NOCCA, Guobing ZHANG
  • Publication number: 20180086989
    Abstract: The present invention concerns a process for the desulphurization of a gasoline cut containing sulphur-containing compounds, olefins and diolefins, comprising at least the following steps: a) fractionating the gasoline in order to recover a light gasoline cut LCN and a first heavy gasoline cut HCN; b) carrying out a first step for desulphurization of the first heavy gasoline cut HCN; c) partially condensing the first desulphurization effluent obtained from step b) in a manner such as to produce a gaseous phase essentially constituted by hydrogen and H2S and a liquid hydrocarbon phase HCN comprising dissolved H2S; d) separating the liquid hydrocarbon phase HCN into an intermediate gasoline cut MCN and a second heavy gasoline cut HHCN; e) carrying out a second step for desulphurization of the second heavy gasoline cut
    Type: Application
    Filed: September 26, 2017
    Publication date: March 29, 2018
    Applicant: IFP Energies nouvelles
    Inventors: Adrien GOMEZ, Clementina LOPEZ GARCIA, Philibert LEFLAIVE, Annick PUCCI, Marie GODARD-PITHON
  • Patent number: 9914109
    Abstract: The present invention relates to zeolitic adsorbents based on agglomerated crystals of FAU zeolite comprising barium and/or potassium, with large external surface area, combining optimum properties in terms of selectivity and mechanical strength. These adsorbents find applications in the separation of cuts of C8-aromatic isomers and notably of xylenes, in the separation of isomers of substituted toluene such as nitrotoluene, diethyltoluene, toluenediamine, in the separation of cresols, and polyhydric alcohols, such as sugars.
    Type: Grant
    Filed: September 5, 2014
    Date of Patent: March 13, 2018
    Assignees: IFP ENERGIES NOUVELLES, ARKEMA FRANCE
    Inventors: Catherine Laroche, Philibert Leflaive, Ludivine Bouvier, Serge Nicolas, Cecile Lutz, Marie-Laurence Labede
  • Publication number: 20180023010
    Abstract: This invention relates to a method for reducing the content of sulfide-type compounds of formula R1-S—R2, with R1 and R2 selected from among the methyl (CH3) and ethyl (C2H5) radicals, of a gasoline that contains diolefins, monoolefins, and sulfur. The method implements a first catalytic step for selective hydrogenation of diolefins at a temperature of between 60° C. and 150° C. and then a step for heating the effluent that is obtained from the first step with a temperature difference ?T of between 10° C. and 100° C. and a second catalytic step on the effluent that is heated in such a way as to produce an effluent that has a content of sulfide-type compounds of formula R1-S—R2, with R1 and R2 selected from among the methyl (CH3) and ethyl (C2H5) radicals, lower than that of the starting gasoline.
    Type: Application
    Filed: December 4, 2015
    Publication date: January 25, 2018
    Applicant: IFP Energies nouvelles
    Inventors: Philibert LEFLAIVE, Clementina GARCIA-LOPEZ, Julien GORNAY, Annick PUCCI, Diamantis ASTERIS, Marie GODARD-PITHON
  • Publication number: 20170292080
    Abstract: A process for the treatment of a gasoline containing sulphur-containing compounds, olefins and diolefins, comprising the following steps: a) fractionating the gasoline in a manner such as to recover at least one intermediate gasoline cut, MCN, comprising hydrocarbons and wherein the temperature difference (?T) between the 5% and 95% by weight distillation points is less than 60° C.; b) desulphurizing the intermediate gasoline cut MCN alone and in the presence of a hydrodesulphurization catalyst and hydrogen in a manner such as to produce a partially desulphurized intermediate gasoline cut MCN; and c) fractionating, in a splitter, the at least partially desulphurized intermediate gasoline cut MCN which has not undergone catalytic treatment subsequent to step b), in a manner such as to recover an intermediate gasoline with low sulphur and mercaptans contents from the column head and a cut of hydrocarbons containing sulphur-containing compounds including mercaptans from the column bottom.
    Type: Application
    Filed: April 5, 2017
    Publication date: October 12, 2017
    Applicant: IFP Energies nouvelles
    Inventors: Clementina LOPEZ GARCIA, Philibert LEFLAIVE, Annick PUCCI, Jean-Luc NOCCA
  • Patent number: 9745524
    Abstract: This invention relates to a process for treatment of a gasoline that comprises diolefins, olefins and sulfur-containing compounds including mercaptans, consisting of a stage for treatment of the gasoline in a distillation column (2) comprising at least one reaction zone (3) including at least one catalyst that makes it possible to carry out the addition of mercaptans to the olefins that are contained in the gasoline that distills toward the top of the catalytic column.
    Type: Grant
    Filed: September 26, 2013
    Date of Patent: August 29, 2017
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Olivier Touzalin, Philibert Leflaive, Diamantis Asteris, Delphine Largeteau, Jean Luc Nocca
  • Patent number: 9731220
    Abstract: The present invention describes a novel configuration for simulated moving bed separation processes characterized by using two adsorbers each containing 12 beds, these two adsorbers functioning in parallel. This novel configuration can be used to optimize para-xylene production.
    Type: Grant
    Filed: June 13, 2012
    Date of Patent: August 15, 2017
    Assignee: IFP Energies nouvelles
    Inventors: Philibert Leflaive, Damien Leinekugel Le Cocq, Gerard Hotier, Luc Wolff
  • Publication number: 20170226031
    Abstract: The invention relates to a method for separating meta-xylene from C8 aromatic fractions, using a zeolitic adsorbent based on sodium-exchanged or sodium-and-lithium-exchanged agglomerated crystals of zeolite Y, with a large external surface area.
    Type: Application
    Filed: August 4, 2015
    Publication date: August 10, 2017
    Applicants: IFP ENERGIES NOUVELLES, CECA S.A.
    Inventors: Catherine LAROCHE, Philibert LEFLAIVE, Arnaud BAUDOT, Ludivine BOUVIER, Cecile LUTZ, Serge NICOLAS
  • Publication number: 20170210683
    Abstract: The present invention describes a process for the production of high-purity paraxylene from a xylenes cut containing xylenes and ethylbenzene, a process using two simulated moving bed separation units and two isomerization units.
    Type: Application
    Filed: June 10, 2015
    Publication date: July 27, 2017
    Applicant: IFP Energies nouvelles
    Inventors: Heloise DREUX, Philibert LEFLAIVE, Damien LEINEKUGEL LE COCQ
  • Publication number: 20170210682
    Abstract: The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units.
    Type: Application
    Filed: June 10, 2015
    Publication date: July 27, 2017
    Applicant: IFP Energies nouvelles
    Inventors: Heloise DREUX, Philibert LEFLAIVE, Damien LEINEKUGEL LE COCQ
  • Publication number: 20170204024
    Abstract: The present invention describes a process for the production of high-purity paraxylene based on a xylene cut, a process using one simulated mobile bed separation unit and two isomerization units, one in gas phase and the other in liquid phase.
    Type: Application
    Filed: June 10, 2015
    Publication date: July 20, 2017
    Applicant: IFP Energies Nouvelles
    Inventors: Heloise DREUX, Philibert LEFLAIVE, Damien LEINEKUGEL LE COCQ