Abstract: A process for the electrochemical deposition of a semiconductor material, which process comprises: (i) providing a non-aqueous solvent; (ii) providing at least one precursor salt which forms a source of the constituent elements within the semiconductor material to be deposited; and (iii) electrodepositing the semiconductor material onto an electrode substrate using the precursor salt in the non-aqueous solvent, characterized in that: (iv) the semiconductor material is a p-block or a post-transition metal semiconductor material containing at least one p-block element or post-transition metal; and (v) the non-aqueous solvent is a halocarbon non-aqueous solvent.

Abstract: A process for the electrochemical deposition of a semiconductor material, which process comprises: (i) providing a non-aqueous solvent; (ii) providing at least one precursor salt which forms a source of the constituent elements within the semiconductor material to be deposited; and (iii) electrodepositing the semiconductor material onto an electrode substrate using the precursor salt in the non-aqueous solvent, characterised in that: (iv) the semiconductor material is a p-block or a post-transition metal semiconductor material containing at least one p-block element or post-transition metal; and (v) the non-aqueous solvent is a halocarbon non-aqueous solvent.

Abstract: An electrochemical cell for testing the electrochemical behavior of a plurality of materials comprises: a first electrode; a counter-electrode bearing an electrochromic material having a visual or measurable property which changes in a manner proportional to the total charge passed through it; and an electrolyte between and in electrical contact with the first electrode and the counter-electrode; wherein one of the first electrode and the electrolyte comprises a plurality of regions, each region comprising a sample of material to be tested, the regions being, in the case of the first electrode, electrically connected to a common terminal. Such a cell can be used for a “combinatorial chemistry” approach to testing the properties of possible cell components.

Abstract: A nanoporous filter comprises a porous support having an essentially flat surface on which is deposited a nanoporous layer having a substantially regular pore structure and uniform pore size within the range from 1 to 50 nm.

Abstract: An electrochemical cell comprising a cathode, an anode and an electrolyte is provided, wherein: the cathode comprises mesoporous nickel having a periodic arrangement of substantially uniformly sized pores of cross-section of the order of 10?8 to 10?9 m; and the anode comprises a mesoporous material having a periodic arrangement of substantially uniformly sized pores of cross-section of the order of 10?8 to 10?9 m and selected from: carbon, cadmium, iron, a palladium/nickel alloy, an iron/titanium alloy, palladium or a mixed metal hydride.

Abstract: An electrochemical cell comprising a cathode, an anode and an electrolyte is provided, wherein: the cathode comprises mesoporous nickel having a periodic arrangement of substantially uniformly sized pores of cross-section of the order of 10?8 to 10?9 m; and the anode comprises a mesoporous material having a periodic arrangement of substantially uniformly sized pores of cross-section of the order of 10?8 to 10?9 m and selected from: carbon, cadmium, iron, a palladium/nickel alloy, an iron/titanium alloy, palladium or a mixed metal hydride.

Abstract: Metal nanovoids are grown on a stretchable plastic film. The fabrication proceeds by assembling the template of a single layer of close packed silica spheres on a conducting substrate. A conducting layer is then electrochemically grown on top to form a master. An elastomeric precursor is then coated on the master (e.g. by spinning) and is cured before removal. The resulting plastic film is then coated with a thin (e.g. 20 nm) layer of noble metal (e.g. Au, Ag or Cu), to produce a flexible film. Applications for such tuneable structural colour would be coating of injection moulded artefacts, such as mobile phone covers, car bodies to form an iridescent skin, wall and fascia decorations, loudspeaker coatings, architectural tent coverings, and clothing.

Abstract: A photovoltaic device and a method of making the photovoltaic device. The device includes a metallic surface defining a plurality of voids for confining surface plasmons. The metallic surface is coated with a semiconductor to form a Schottky region at an interface between the metallic surface and the semiconductor within each void.

Abstract: A nanoporous filter comprises a porous support having an essentially flat surface on which is deposited a nanoporous layer having a substantially regular pore structure and uniform pore size within the range from 1 to 50 nm.

Abstract: A method of preparing a porous film comprises electrodepositing material from a mixture onto a substrate, the mixture comprising: (I) a source of metal, inorganic oxide, non-oxide semiconductor/conductor or organic polymer, (II) a solvent such as water; and (III) a structure-directing agent such as octaethylene glycol monododecyl ether in an amount sufficient to form an homogeneous lyotropic liquid crystalline phase in the mixture. Electrodepositing the film from a lyotropic liquid phase in this manner provides a porous film having a substantially regular structure and substantially uniform pore size. Following deposition, the porous film may be treated to remove the structure-directing agent.

Abstract: A method of manufacturing a pellistor comprises providing a porous catalyst layer (11) on a heater by electrodepositing material from a mixture containing the catalyst and a structure-directing agent in an amount sufficient to form an homogenous lyotropic liquid crystalline phase in the mixture.

Abstract: This invention provides methods for denaturing nucleic acids. The methods involve contacting a solution comprising double stranded nucleic acid with a surface having denaturation activity sufficient to produce denaturation within a period of not more than one hour.

Abstract: A method for indicating the concentration of a substance in solution includes passing an alternating voltage between a first electrode structure having coated thereon a polymer and a second separate counter electrode in the solution. The polymer is in one of an oxidized and a reduced state, between which states its conductivity varies. Changes in the conductivity of the polymer coating are measured, the measurement being representative of the state of the polymer and thereby of the concentration of the substance in the solution. Electrodes for use in this method are also described.